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All-Solid-State Lithium Batteries with Sulfide Electrolytes and Oxide Cathodes

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Abstract

All-solid-state lithium batteries (ASSLBs) have attracted increasing attention due to their high safety and energy density. Among all corresponding solid electrolytes, sulfide electrolytes are considered to be the most promising ion conductors due to high ionic conductivities. Despite this, many challenges remain in the application of ASSLBs, including the stability of sulfide electrolytes, complex interfacial issues between sulfide electrolytes and oxide electrodes as well as unstable anodic interfaces. Although oxide cathodes remain the most viable electrode materials due to high stability and industrialization degrees, the matching of sulfide electrolytes with oxide cathodes is challenging for commercial use in ASSLBs. Based on this, this review will present an overview of emerging ASSLBs based on sulfide electrolytes and oxide cathodes and highlight critical properties such as compatible electrolyte/electrode interfaces. And by considering the current challenges and opportunities of sulfide electrolyte-based ASSLBs, possible research directions and perspectives are discussed.

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Acknowledgements

This work was supported by the National Key R&D Program of China (Grant No. 2018YFB0905400), the National Natural Science Foundation of China (Grant Nos. 51872303, U1964205, 51902321), the Zhejiang Provincial Natural Science Foundation of China (Grant No. LD18E020004, LY18E020018), the Ningbo S&T Innovation 2025 Major Special Programme (Grant Nos. 2018B10061, 2018B10087, 2019B10044), the Natural Science Foundation of Ningbo (Grant Nos. 2018A610010, 2019A610007), the Jiangxi Provincial Key R&D Program of China (Grant No. 20182ABC28007) and the Youth Innovation Promotion Association CAS (2017342).

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Authors and Affiliations

  1. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, Zhejiang, China

    Jinghua Wu, Lin Shen, Zhihua Zhang, Gaozhan Liu, Zhiyan Wang, Dong Zhou, Hongli Wan & Xiayin Yao

  2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China

    Jinghua Wu, Lin Shen, Gaozhan Liu, Zhiyan Wang, Hongli Wan & Xiayin Yao

  3. Zhejiang Funlithium New Energy Technology Co., Ltd., Ningbo, 315201, Zhejiang, China

    Xiaoxiong Xu

  4. Ganfeng Lithium Co., Ltd., Xinyu, 338015, Jiangxi, China

    Xiaoxiong Xu

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  1. Jinghua Wu
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Correspondence to Xiaoxiong Xu or Xiayin Yao.

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Wu, J., Shen, L., Zhang, Z. et al. All-Solid-State Lithium Batteries with Sulfide Electrolytes and Oxide Cathodes. Electrochem. Energ. Rev. 4, 101–135 (2021). https://doi.org/10.1007/s41918-020-00081-4

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  • DOI: https://doi.org/10.1007/s41918-020-00081-4

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