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The oxidation of single-crystal nickel-based superalloys

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Abstract

A phase transformation occurs in nickel-based single-crystal superalloys as a result of the oxidation that creates the external NiO scale. This transformation, which is the precursor to internal oxidation, creates the β phase (NiAl) first followed by the δ phase (Ni2Al3) prior to the formation of the spinel Ni (Cr, Al)2O4 and Al2O3 in succession. The implications of this effect on the rate of oxidation are discussed in this article.

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References

  1. M.A. Smith, W.A. Frazier, and B.A. Pregger, Materials Science and Engineering, A203 (1995), pp. 388–398.

    Article  Google Scholar 

  2. M.S. Hook (Ph.D. thesis, University of Cambridge, U.K., 2004).

  3. A. Akhtar, M.S. Hook, and R.C. Reed, “On the Oxidation of the Third Generation Single Crystal Superalloy CMSX-10”, Metall. Mat. Trans. A36A (2005) pp. 3001–3017.

    Article  CAS  Google Scholar 

  4. M. Göbel, A. Rahmel, and M. Schütze, Oxid. Met., 39 (1993), pp. 231–261.

    Article  Google Scholar 

  5. M. Göbel, A. Rahmel, and M. Schütze, Oxid. Met., 41 (1994), pp. 271–300.

    Article  Google Scholar 

  6. R. Janakiraman, G.H. Meier, and F.S. Pettit, Metall. Mat. Trans. A, 30A (1999), pp. 2905–2911.

    Article  CAS  Google Scholar 

  7. M.C. Maris-Sida, G.H. Meier, and F.S. Pettit, Metall. Mat. Trans. A, 34A (2003), pp. 2609–2619.

    Article  CAS  Google Scholar 

  8. M.H. Li et al., Oxid. Met., 59 (2003), pp. 591–605.

    Article  CAS  Google Scholar 

  9. M.H. Li et al., Oxid. Med., 60 (2003), pp. 195–210.

    Article  CAS  Google Scholar 

  10. F.H. Yuan et al., Oxid. Met., 60 (2003), pp. 211–224.

    Article  CAS  Google Scholar 

  11. V.K. Tolpygo, D.R. Clarke, and K.S. Murphy, Metall. Mat. Trans. A, 32A (2001), pp. 1467–1478.

    Article  CAS  Google Scholar 

  12. J. Angenete, K. Stiller, and V. Langer, Oxid. Met., 60 (2003), pp. 47–82.

    Article  CAS  Google Scholar 

  13. J. Angenete, and K. Stiller, Oxid. Met., 60 (2003), pp. 83–101.

    Article  CAS  Google Scholar 

  14. J. Angenete, K. Stiller, and E. Bakchinova, Surface and Coatings Technology, 176 (2004), pp. 272–283.

    Article  CAS  Google Scholar 

  15. V.K. Tolpygo and D.R. Clarke, Acta Mat., 48 (2000), pp. 3283–3293.

    Article  CAS  Google Scholar 

  16. C.S. Giggins and F.S. Pettit, J. Electrochem. Soc., 118 (1971), pp. 1782–1790.

    Article  CAS  Google Scholar 

  17. M. Moniruzzaman et al., ISIJ International, 43 (2003), pp. 386–393.

    CAS  Google Scholar 

  18. J. Pan et al., Phil. Mag. Letters, 84 (2004), pp. 781–789.

    Article  CAS  Google Scholar 

  19. C.L. Briant, and K.L. Luthra, Metall. Trans. A, 19A (1988), pp. 2099–2108.

    CAS  Google Scholar 

  20. A. Ul-Hamid, Oxid. Met., 58 (2002), pp. 41–56.

    Article  CAS  Google Scholar 

  21. T.J. Nijdam, L.P.H. Juergens, and W.G. Sloof, Acta Mat., 51 (2003), pp. 5295–5307.

    Article  CAS  Google Scholar 

  22. M. Bobeth et al., Corrosion Science, 37 (1995), pp. 657–670.

    Article  CAS  Google Scholar 

  23. P. Nash, M.F. Singleton, and J.I. Murray, Phase Diagrams of Binary Nickel Alloys, ed. P. Nash, (Materials Park, OH: ASM International, 1991).

    Google Scholar 

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Akhtar, A., Hegde, S. & Reed, R.C. The oxidation of single-crystal nickel-based superalloys. JOM 58, 37–42 (2006). https://doi.org/10.1007/s11837-006-0066-0

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  • DOI: https://doi.org/10.1007/s11837-006-0066-0

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