Skip to main content
Log in

Growth and Characteristics of n-VO2/p-GaN based Heterojunctions

  • Advanced Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

n-VO2/p-GaN based oxide-nitride heterojunctions were realized by growing high quality VO2 films with precisely controlled thickness on p-GaN/sapphire substrates by oxide molecular beam epitaxy (O-MBE). The high crystalline quality of the n-VO2/p-GaN heterojunctions were confirmed by X-ray diffraction (XRD) and scanning electron microscope (SEM) analysis. The phase transition characteristics of the as-grown n-VO2/p-GaN heterojunctions were systematically investigated by temperature-dependent resistivity and infrared transmittance measurements. The results indicated that an excellent reversible metal-to-insulator (MIT) transition is observed with an abrupt change in both resistivity and infrared transmittance (IR) at 330 K, which was lower than the 341 K for bulk single crystal VO2. Remarkably, the resistivity-temperature curve was well consistent with that obtained from the temperature dependent IR transmittance. Meanwhile, the current-voltage characteristics originated from the n-VO2/p-GaN interface were demonstrated both before and after MIT of VO2 overlayer, which were attributed to the p-n junction behavior and Schottky contact character, respectively. The design and modulation of the n-VO2/p-GaN based heterostructure devices will benefit significantly from these achievements.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Aetukri NB, Gray AX, Drouard M, et al. Control of the Metal-insulator Transition in Vanadium Dioxide by Modifying Orbital Occupancy[J]. Nature Physics, 2013, 9(10): 661–666

    Article  CAS  Google Scholar 

  2. Li M, Magdassi S, Gao YF, et al. Hydrothermal Synthesis of VO2 Polymorphs: Advantages, Challenges and Prospects for the Application of Energy Efficient Smart Windows[J]. Small, 2017, 13(36): UNSP 1701147

    Article  CAS  Google Scholar 

  3. Ran K, Huang WX, Shi QW, et al. Freeze-drying Induced Nano Crystallization of VO2 (M) with Improved Mid-infrared Switching Properties[J]. Journal of Alloys Compounds, 2017, 728: 1 076–1 082

    Article  CAS  Google Scholar 

  4. Slusar TV, Cho JC, Lee HR, et al. Mott Transition in Chain Structure of Strained VO2 Films Revealed by Coherent Phonons[J]. Scientific Reports, 2017, 7:16 038

    Article  CAS  Google Scholar 

  5. Zhang ZT, Gao YF, Chen ZH, et al. Thermochromics VO2 Thin Films: Solution-Based Processing, Improved Optical Properties, and Lowered Phase Transformation Temperature[J]. Langmuir, 2010, 26(13):10 738–10 744

    Article  CAS  Google Scholar 

  6. Ji CHH, Wu ZHM, Lu LL, et al. High Thermochromics Performance of Fe/Mg Co-doped VO2 Thin Films for Smart Window Applications[J]. Journal of Materials Chemistry C, 2018, 6(24): 6502–6509

    Article  CAS  Google Scholar 

  7. Ke YJ, Wang SC, Liu GW, et al. Vanadium Dioxide: The Multistimuli Responsive Material and Its Applications[J]. Small, 2018, 14(39): 1802025

    Article  CAS  Google Scholar 

  8. Minha K, Donguk K, Jin-hong P, et al. Structural and Optical Properties of VO2 Thin Film Grown by Reactive Sputtering from Mo-Doped V Metal Target[J]. Science of Advanced Materials, 2017, 9(8): 1 340–1 345

    Article  CAS  Google Scholar 

  9. Chen YL, Zhang XQ, Fang CQ, et al. Synthesis, Structure and Properties of Printable W-doped Thermochromics VO2 with a Low Phase Transition Temperature[J]. Ceramics Intermational, 2018, 44(16): 20 084–20 092

    Article  CAS  Google Scholar 

  10. Hyun J, Min-woo K, and Woong-ki H. Voltage Sweep Direction-dependent Metal-insulator Transition in a Single-crystalline VO2 Nano Beam Embedded in an Insulating Layer[J]. Journal of Alloys and Compounds, 2017, 720: 445–450

    Article  CAS  Google Scholar 

  11. Zhang C, Kang CHY, Zong HT, et al. Stress Induced Modulation of the Structure and Photoelectric Property of Vanadium Oxide Films on Sapphire Substrate[J]. Journal of Inorganic Materials, 2018, 33(11):1 225–1 231

    Article  Google Scholar 

  12. S WM, Soo KI, Guo PJ, et al. Oxidation State Discrimination in the Atomic Layer Deposition of Vanadium Oxides[J]. Chemistry of Materials, 2017, 29(15): 6 238–6 244

    Article  CAS  Google Scholar 

  13. Salinporn K, Jude L, Jr ND, et al. Transport Behavior and Electronic Structure of Phase Pure VO2 Thin Films Grown on C-plane Sapphire under Different O2 Partial Pressure[J]. Journal of Applied Physics, 2013, 114(5): 053703

    Article  CAS  Google Scholar 

  14. Heungsoo K, S NB, A CN, et al. Strain Effect in Epitaxial VO2 Thin Films Grown on Sapphire Substrates using SnO2 Buffer Layers[J]. Aip Advances, 2017, 7(10): 105116

    Article  CAS  Google Scholar 

  15. Roccaforte F, Fiorenza P, Greco G, et al. Emerging Trends in Wide Band Gap Semiconductors (SiC and GaN) Technology for Power Devices[J]. Microelectronic Engineering, 2018, 187: 66–77

    Article  CAS  Google Scholar 

  16. Wang MH, Bian JM, Sun HJ, et al. n-VO2/p-GaN Based Nitrideoxide Heterostructure with Various Thickness of VO2 Layer Grown by MBE[J]. Applied Surface Science, 2016, 389: 199

    Article  CAS  Google Scholar 

  17. Bian JM, Wang MH, Sun HJ, et al. Thickness-modulated Metal-insulator Transition of VO2 Film Grown on Sapphire Substrate by MBE[J]. Journal of Materials Science, 2016, 51(13): 6 149–6 155

    Article  CAS  Google Scholar 

  18. Fan LL, Chen S, Wu YF, et al. Growth and Phase Transition Characteristics of Pure M-phase VO2 Epitaxial Film Prepared by Oxide Molecular Beam Epitaxy[J]. Applied Physics Letters, 2013, 103(13): 131 914

    Article  CAS  Google Scholar 

  19. Wu CHZH and Xie Y. Promising Vanadium Oxide and Hydroxide Nanostructures: From Energy Storage to Energy Saving[J]. Energy & Environmental Science, 2010, 3(9): 1 191–1 206

    Article  CAS  Google Scholar 

  20. Bian JM, Wang MH, Miao LH, et al. Growth and Characterization of VO2/p-GaN/sapphire Heterostructure with Phase Transition Properties[J]. Applied Surface Science, 2015, 357: 282–286

    Article  CAS  Google Scholar 

  21. Li XX, Bian JM, Wang MH, et al. Realization of Nitride-oxide Based p-n Heterojunctions with the n-VO2/p-GaN/sapphire Structure[J]. Materials Research Bulletin, 2016, 77: 199–204

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jiming Bian  (边继明).

Additional information

Funded by the National Natural Science Foundation of China (No. 51872036), the Dalian Science and Technology innovation fund (No. 2018J12GX033), and the Fundamental Research Funds for the Central Universities (No. DUT19LAB07)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, Y., Zhang, B., Wang, M. et al. Growth and Characteristics of n-VO2/p-GaN based Heterojunctions. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 35, 342–347 (2020). https://doi.org/10.1007/s11595-020-2262-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-020-2262-0

Key words

Navigation