Abstract
Stereochemically inert, positively charged chiral octahedral complexes of CoIII and CrIII were used as catalysts for asymmetric oxidative coupling of 2-naphthol. The reaction product 1,1´-bi-2-naphthol was produced with a yield of up to 74% and enantiomeric excess of up to 22%. The reduction and oxidation potentials of a series of CoIII and CrIII cationic complexes were measured.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0685—0688, March, 2016.
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Larionov, V.A., Peregudova, S.M., Maleev, V.I. et al. A novel type of catalysts for asymmetric oxidative coupling of 2-naphthol. Russ Chem Bull 65, 685–688 (2016). https://doi.org/10.1007/s11172-016-1356-5
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DOI: https://doi.org/10.1007/s11172-016-1356-5