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A New Multi-Copper-Substituted Tetramer Tungstoantimonate: Synthesis, Photocatalytic and Electrochemical Properties

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Abstract

Under hydrothermal conditions, a new “S”-shaped Cu-substituted tetramer tungstoantimonate, HKNa2(H2en)6[Cu(en)(H2O)]2[KNaCu3(H2O)7(B-a-SbW9O33)2]2⋅16H2O (1, en = 1,2-ethylenediamine) was synthesized in reactions of the Na9[SbW9O33]·19.5H2O precursor with CuCl2⋅2H2O and potassium acetate in the presence of en and characterized by IR spectrum, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction, respectively. Polyoxoanion 1 consists of two asymmetric sandwich-type polyanions {KNaCu3(H2O)7(B-a-SbW9O33)2} linked by two structurally equivalent [Cu4(en)(H2O)]2+ bridges. The electrochemical properties and photocatalytic activities have been investigated, displaying outstanding photocatalytic and electrocatalytic activities for the photodegradation of MB and H2O2/NO2−/BrO3− reduction.

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Acknowledgements

This work was supported by the NSFC (No. 21901018), the China Postdoctoral Science Foundation funded project (No. 2019M650498) and the Doctoral Scientific Research Foundation of Bohai University (No. 0520bs027).

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Authors and Affiliations

  1. Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, College of Chemistry and Materials Engineering, Bohai University, Jinzhou, 121013, China

    Zhong Zhang, Lin Yang, Na Xu & Xiao-Hui Li

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  1. Zhong Zhang
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  2. Lin Yang
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  3. Na Xu
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  4. Xiao-Hui Li
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Correspondence to Zhong Zhang.

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Zhang, Z., Yang, L., Xu, N. et al. A New Multi-Copper-Substituted Tetramer Tungstoantimonate: Synthesis, Photocatalytic and Electrochemical Properties. J Clust Sci 33, 1249–1255 (2022). https://doi.org/10.1007/s10876-021-02059-8

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