Abstract
Carbon nanofibers supported copper nanoparticles (CuNPs/CNFs) catalyst was synthesized by electrospinning in the high-pressure hydrogenation method, and the high-temperature calcination. The catalyst was characterized by scanning electron microscope, transmission electron microscope, energy dispersive spectrometer, and X-ray photoelectron spectroscopy. The CuNPs/CNFs catalyst was used for Ullmann-type couplings under ligand-free conditions, and the results showed that the CuNPs/CNFs catalyst had a good catalytic activity for Ullmann O-arylation of aryl halides with various phenols.
Graphical Abstract
The schematic illustration: Preparation process of CuNPs/CNFs catalyst.
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This work is financially support by the National Natural Science Foundation of China (21166016), and the Scientific Research Program of Higher Education Institutions of Inner Mongolia Autonomous Region (NJZZ12050).
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Zhang, C., Li, C., Bai, J. et al. A Cu Nanoparticle Embedded in Electrospundoped Carbon Nanofibers as Efficient Catalysts for Ullmann O-Arylation of Aryl Halides with Various Phenols. Catal Lett 145, 1764–1770 (2015). https://doi.org/10.1007/s10562-015-1566-8
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DOI: https://doi.org/10.1007/s10562-015-1566-8