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Synthesis of 3-glycidoxypropyltrimethoxysilane modified hydrotalcite bearing molybdate as corrosion inhibitor for waterborne epoxy coating

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Abstract

Zinc aluminum hydrotalcite intercalated with molybdate (HTM) and modified by 3-glycidoxypropyltrimethoxysilane (HTM-GS) was prepared and incorporated into a waterborne epoxy coating. The synthesized HTM-GS was characterized by FTIR, XRD, SEM, and TEM. The inhibitive action of HTM-GS on carbon steel was evaluated using electrochemical measurement and SEM/EDX analysis. The corrosion protection of the waterborne epoxy coating containing HTM-GS was evaluated and compared to that of the pure waterborne epoxy coating and the waterborne epoxy coating containing HTM by salt spray test and adhesion measurement. It was shown that the molybdate was intercalated in the hydrotalcite structure and the molybdate contents in HTM and HTM-GS were 16.0 and 13.2 wt%, respectively. The polarization curves obtained on the carbon steel electrode showed that HTM and HTM-GS are anodic corrosion inhibitors, and their inhibition efficiencies at concentration of 3 g/l were 92.0 and 94.7%, respectively. Additionally, HTM and HTM-GS at concentration of 0.5 wt% improved corrosion resistance and adhesion of waterborne epoxy coatings. Surface modification by 3-glycidoxypropyltrimethoxysilane ameliorated the dispersion of HTM in epoxy matrix and the effect of HTM on protection properties of waterborne epoxy coating.

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Acknowledgments

This research was funded by the Vietnam National Foundation for Science and Technology Development (NAFOSTED) under Grant Number 104.01-2012.15. The authors gratefully acknowledge the support of Thai-French Innovation Institute.

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Authors and Affiliations

  1. Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam

    To Thi Xuan Hang, Nguyen Tuan Anh, Trinh Anh Truc, Bui Van Truoc, Thai Hoang & Dinh Thi Mai Thanh

  2. Thai-French Innovation Institute, King Mongkut’s University of Technology North Bangkok, 1518, Pracharat 1 Rd., Bangsue, Bangkok, 10800, Thailand

    Siriporn Daopiset

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  1. To Thi Xuan Hang
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  2. Nguyen Tuan Anh
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  3. Trinh Anh Truc
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  4. Bui Van Truoc
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Correspondence to To Thi Xuan Hang.

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Hang, T.T.X., Anh, N.T., Truc, T.A. et al. Synthesis of 3-glycidoxypropyltrimethoxysilane modified hydrotalcite bearing molybdate as corrosion inhibitor for waterborne epoxy coating. J Coat Technol Res 13, 805–813 (2016). https://doi.org/10.1007/s11998-016-9791-7

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  • DOI: https://doi.org/10.1007/s11998-016-9791-7

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