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Microwave synthesis and photoluminescent properties of Sr2CeO4/Ln3+ (Ln = Er, Ho, Tm)

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Frontiers of Chemistry in China

Abstract

Sr2CeO4/Ln3+ (Ln = Er, Ho, Tm) phosphors were synthesized with the microwave radiation method for the first time. The luminescent properties of the samples were investigated and the up-conversion luminescence of Er3+, Ho3+ and Tm3+ doped Sr2CeO4 phosphors was observed. The spectra indicate that the energy transfer takes place from the triplet excited state of MLCT (metal-to-ligand charge transfer) state for Sr2CeO4 (sensitizer) to the rare earth ions (activator).

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References

  1. Tan H, Song F, Su J, Shang M R, Fu B, Zhang G Y, Cheng Z X, Chen H C. Upconversion luminescence and spectra characteristics of Er3+, Tm3+ co-doped NaY(WO4)2 crystal. Acta Physica Sinica, 2004, 53(2): 631–635 (in Chinese)

    CAS  Google Scholar 

  2. Danielson E, Devenney M, Giaquinta D M, Golden J H, Haushalter R C, Mcfarland E W, Poojary D M, Reaves C M, Weinberg W H, Wu X D. A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods. Science, 1998, 279(6): 837–839

    Article  CAS  Google Scholar 

  3. Hirai T, Kawamura Y. Preparation of Sr2CeO4: Eu3+, Dy3+ white luminescence phosphor particles and thin films by using an emulsion liquid membrane system. J Phys Chem B, 2005, 109(12): 5,569–5,573

    Article  CAS  Google Scholar 

  4. Sankar R, Subba Rao G V. Eu3+ luminescence, Ce4+-Eu3+ energy transfer, and white-red light generation in Sr2CeO4. Journal of the Electrochemical Society, 2000, 147(7): 2,773–2,779

    CAS  Google Scholar 

  5. Nag A, Narayanan T R. Photoluminescence of Sr2−xLnxCeO4+x/2 (Ln = Eu, Sm or Yb) prepared by a wet chemical method. Journal of Materials Chemistry, 2003, 13: 370–376

    Article  CAS  Google Scholar 

  6. Shi S K, Li J M, Zhou J. Luminescence spectra of Sm3+ doped Sr2CeO4 synthesized through co-precipitation process. Spectroscopy and Spectral Analysis, 2005, 25(10): 1,739–1,741 (in Chinese)

    CAS  Google Scholar 

  7. Chuai X H, Zhang H J, Li F S, Zhou G Z. Synthesis of Sr2CeO4: Eu3+ by citrate gel method and its luminescence properties. Chinese Journal of Inorganic Chemistry, 2003, 19(5): 462–466 (in Chinese)

    CAS  Google Scholar 

  8. Shi S K, Wang J Y, Li J M, Zhou J. Combustion synthesis and properties of Eu3+ doped Sr2CeO4 phosphor. Journal of the Chinese Rare Earth Society, 2004, 22(6): 859–862 (in Chinese)

    CAS  Google Scholar 

  9. Herai T, Kawamura Y. Preparation of Sr2CeO4 blue phosphor particles and rare earth (Eu, Ho, Tm, or Er)-doped Sr2CeO4 phosphor particles, using an emulsion liquid membrane system. J Phys Chem B, 2004, 108(34): 12,763–12,769

    Google Scholar 

  10. Zhang Z T, Hang J Y. Inorganic Photolumenscence Materials and Application. Beijing: Chemical Industry Press, 2005, 267–268 (in Chinese)

    Google Scholar 

  11. Chen X B, Song Z F, Saw A N. Up-conversion luminescence and volumetric display research on Er (0.5): FOG material excited by 1520 nm laser. Spectroscopy and Spectral Analysis, 2005, 25(1): 13–18 (in Chinese)

    Google Scholar 

  12. Liu Y L, Song C Y, Zhang J X, Yuan D S, Huang L H, Rong J H, Zhang J W. Afterglow emission of Er3+, Ho3+ and Tm3+ in gadolinium oxysulfide. Chinese Journal of Inorganic Chemistry, 2005, 21(6): 905–909 (in Chinese)

    CAS  Google Scholar 

  13. Song C Y, Liu Y L, Zhang J X, Huang L H, Yuan D S, Rong J H, Shi C S, Lei B F. Synthesis of the orange-red long afterglow phosphor: Gd2O2S: Sm3+ by the microwave radiation method. Journal of Jinan University (Natural Science & Medicine Edition), 2003, 24(5): 93–96 (in Chinese)

    CAS  Google Scholar 

  14. Pei X J, Hou Y B, Xu Z, Zhao S L, Teng F. Upconversion luminescence properties of YLiF4: Er, Tm and Yb synthesized by hydrothermal method. Spectroscopy and Spectral Analysis, 2005, 25(6): 819–823 (in Chinese)

    CAS  Google Scholar 

  15. Xiao S G, Yang X H, Liu Z W. Upconversion luminescence in Ho3+ doped fluoride thin film with excitation red laser. Spectroscopy and Spectral Analysis, 2003, 23(2): 221–222 (in Chinese)

    CAS  Google Scholar 

  16. Shen Y R, Zhang H. Spectral properties of ZnS: Ho3+. Chinese Journal of Luminescence, 1987, 8(3): 174–181 (in Chinese)

    Google Scholar 

  17. Qi C H, Liu C X, Lin F Y, Hu H F. Upconversion luminescence of Ho3+ in Yb3+, Ho3+ doped ZBLAN glasses. Chinese Journal of Lasers, 1998, 25(6): 561–564 (in Chinese)

    Google Scholar 

  18. Zhang X, Liu X R. Study of the upconversion mechanisms of Ho3+ in LaF3 crystal. Chinese Journal of Luminescence, 1997, 18(4): 295–297 (in Chinese)

    Google Scholar 

  19. Zang J C, Shan B R, Song Y R, Yao S Z, Zheng D W, Ye J P. Spectroscopy and upconversion process in Ho3+: ZnWO4 crystal. Journal of the Chinese Ceramic Society, 2005, 33(5): 538–546 (in Chinese)

    CAS  Google Scholar 

  20. Qi C H, Zhang X R, Hu H F. Spectral properties of Ho3+ in ZBLAN glass. Acta Optica Sinica, 1994, 14(6): 583–588 (in Chinese)

    CAS  Google Scholar 

  21. Yang L M, Song H W, Yu L X, Liu Z X, Lu S Z, Ma L Q. Upconversion luminescence in nanocrystalline Y2O3: Ho/Yb. Chinese Journal of Luminescence, 2004, 25(6): 710–714 (in Chinese)

    CAS  Google Scholar 

  22. Yan L, Liu Z W, Yang X L. Study on red up-conversion luminescence of fluoride glasses doped with Er3+, Yb3+ and Tm3+. Spectroscopy and Spectral Analysis, 2005, 25(6): 824–827 (in Chinese)

    CAS  Google Scholar 

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Correspondence to Song Huihua.

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Translated from Journal of Hebei Normal University (Natural Science Edition), 2007, 31(2): 212–216 [译自: 河北师范大学学报 (自然科学版)]

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Kang, H., Song, H., Wang, J. et al. Microwave synthesis and photoluminescent properties of Sr2CeO4/Ln3+ (Ln = Er, Ho, Tm). Front. Chem. China 2, 393–397 (2007). https://doi.org/10.1007/s11458-007-0074-9

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  • DOI: https://doi.org/10.1007/s11458-007-0074-9

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