Abstract
Assembly of submicron-sized microspheres has received much attention due to its high potential for wide variety of applications. We have developed a preparation method of polymer particles by simple mixing of a poor solvent into the polymer solution followed by evaporation of a good solvent. By using this technique, silica nanoparticles and polymer composite particles were prepared. Preparation of three-dimensional assemblies of silica particles in polymer particles and composite Janus particles are shown.
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Xia Y, Gates B, Yin Y, Lu Y (2000) Monodispersed colloidal spheres: old materials with new applications. Adv Mater 12(10):693–713
Kumacheva E, Golding RK, Allard M, Sargent EH (2002) Colloidal crystal growth on mesoscopically patterned surfaces: effect of confinement. Adv Mater 14(3):221–224
Míguez H, Yang SM, Tétreault N, Ozin GA (2002) Oriented free-standing three-dimensional silicon inversed colloidal photonic crystal microfibers. Adv Mater 14(24):1805–1808
Yabu H, Inoue K, Shimomura M (2006) Multiple-periodic of self-organized honeycomb-patterned films and polymer nanoparticles hybrids. Colloid Surface Physicochem Eng Aspect 284–285:301–304
Li F, Badel X, Linnros J, Wiley JB (2005) Fabrication of colloidal crystal with tubular-like packings. J Am Chem Soc 127:3268–3269
Caruso F (2004) Colloids and colloid assemblies. Wiley-VCH, New York
Hu J, Chen M, Wu L (2011) Organic–inorganic nanocomposites synthesized via miniemulsion polymerization. Polym Chem 2:760–772
Subramaniam AB, Abkrian M, Stone HA (2005) Controlled assembly of jammed colloidal shells on fluid droplets. Nat Mater 4:553–556
Stein A, Li F, Denny NR (2008) Morphological control in colloidal crystal templating of inverse opals, hierarchical structures, and shaped particles. Chem Mater 20:649–666
Hong SH, Moon JH, Lim JM, Kim SH, Yang SM (2005) Fabrication of spherical colloidal crystals using electrospray. Langmuir 21:10416–10421
Ohkubo M, Lu Y (1996) Production of core-shell composite polymer particles utilizing the stepwise heterocoagulation method. Colloids Surf A 109:49–53
Wagner CS, Shehata S, Henzler K, Yuan J, Wittemann A (2011) Towards nanoscale composite particles of dual complexity. J Colloid Interface Sci 355:115–123
Ito F, Uchida Y, Murakami Y (2010) Facile technique for preparing organic–inorganic composite particles: monodisperse poly(lactide-co-glycolide) (PLGA) particles having silica nanoparticles on the surface. Colloids Surf A 361:109–117
Yabu H, Higuchi T, Shimomura M (2005) Unique phase-separation structures of block-copolymer nanoparticles. Adv Mater 17(18):2062–2065
Motoyoshi K, Tajima A, Higuchi T, Tajima A, Yabu H, Shimomura M (2010) Static and dynamic control of phase separation structures in nanoparticles of polymer blends. Soft Matter 6(6):1253–1257
Yabu H, Koike K, Motoyoshi K, Higuchi T, Shimomura M (2010) A novel route for fabricating metal-polymer composite nanoparticles with phase-separated structures macromol. Rap Commun 31(14):1267–1271
Yabu H, Endo A, Koike K, Motoyoshi K, Higuchi T, Shimomura M (2011) Hierarchical assembly of CdS nanoparticles in polymer particles having phase separation structures. Polymer J 43(3):301–305
Acknowledgment
This work has been partially supported by Grant-in-Aid for Priority Area “Metamaterials” (no. 23109502), MEXT, Japan.
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Yabu, H., Sato, S. Controlled assembly of silica microspheres in spherically confined polymer particles by using self-organized precipitation (SORP) method. Colloid Polym Sci 291, 181–186 (2013). https://doi.org/10.1007/s00396-012-2643-9
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DOI: https://doi.org/10.1007/s00396-012-2643-9