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Zinc Electrodeposition Morphology

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The Zinc/Bromine Flow Battery

Part of the book series: SpringerBriefs in Energy ((BRIEFSENERGY))

Abstract

The electrochemical performance of the zinc half-cell is strongly linked to the quality and morphology of zinc electrodeposits generated during the charging phase. The structure of the zinc plating also dictates performance characteristics such as efficiencies, charge densities and peak current values during the subsequent discharge phase. The previous chapter described and analyzed the considerations arising from chemical reactions occurring at the zinc-side electrode. Following from that point, this chapter describes the underlying reasons why different zinc plating morphologies are obtained under different conditions and how certain behavior such as dendritic growth can be detrimental to Zn/Br performance. Promising methods for solving such issues are then identified from a wide range of literature including studies directly related to redox flow batteries as well as from the highly established electroplating industry. The primary means of controlling zinc crystal structure involves the use of organic additives to achieve a specific growth template and rate. Additionally, the merits and drawbacks of alternative strategies such as controlling deposition rates are investigated in this chapter.

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  1. The University of Sydney, Sydney, NSW, Australia

    Gobinath Pillai Rajarathnam & Anthony Michael Vassallo

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  1. Gobinath Pillai Rajarathnam
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Rajarathnam, G.P., Vassallo, A.M. (2016). Zinc Electrodeposition Morphology. In: The Zinc/Bromine Flow Battery. SpringerBriefs in Energy. Springer, Singapore. https://doi.org/10.1007/978-981-287-646-1_4

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  • DOI: https://doi.org/10.1007/978-981-287-646-1_4

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