Abstract
The catalytic removal of nitrogen oxides (NO x ) from diesel exhaust under oxygen-rich conditions remains a major challenge in the field of environmental catalysis, and the selective catalytic reduction of NO x with NH3 (NH3-SCR), especially over zeolite catalysts, is a well-proven technique for the catalytic deNO x process for diesel vehicles. The comprehensive understanding of the structure-activity relationship of zeolite catalysts in the NH3-SCR reaction and the elucidation of the detailed reaction mechanism are very important for the practical use of these catalytic materials. In this chapter, using the environmentally friendly Fe- and Cu-based zeolite catalysts (i.e. Fe-ZSM-5, Cu-ZSM-5, Cu-SSZ-13 and Cu-SAPO-34, etc.) as examples, the influence of preparation methods on NH3-SCR performance, the role of metal active sites/surface acid sites, the impact of NO2 and co-existing pollutants, the hydrothermal stability and also the possible SCR reaction pathways over these materials are discussed in detail, which can provide theoretical and empirical guidance for the redesign and activity improvement of these catalysts in their practical applications.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Granger P, Parvulescu VI (2011) Catalytic NO x abatement systems for mobile sources: from three-way to lean burn after-treatment technologies. Chem Rev 111:3155–3207
Liu Z, Woo SI (2006) Recent advances in catalytic deNO x science and technology. Catal Rev 48:43–89
Kwak JH, Tran D, Burton SD, Szanyi J, Lee JH, Peden CHF (2012) Effects of hydrothermal aging on NH3-SCR reaction over Cu/zeolites. J Catal 287:203–209
Grossale A, Nova I, Tronconi E (2008) Study of a Fe-zeolite-based system as NH3-SCR catalyst for diesel exhaust after treatment. Catal Today 136:18–27
Gabrielsson PLT (2004) Urea-SCR in automotive applications. Top Catal 28:177–184
Johnson TV (2009) Diesel emission control in review. SAE Int J Fuels Lubr 2:1–12
Brandenberger S, Kröcher O, Tissler A, Althoff R (2008) The state of the art in selective catalytic reduction of NOx by ammonia using metal-exchanged zeolite catalysts. Catal Rev 50:492–531
Feng X, Hall WK (1997) FeZSM-5: a durable SCR catalyst for NO x removal from combustion streams. J Catal 166:368–376
Ma A-Z, Grünert W (1999) Selective catalytic reduction of NO by ammonia over Fe-ZSM-5 catalysts. Chem Commun 1:71–72
Long RQ, Yang RT (1999) Superior Fe-ZSM-5 catalyst for selective catalytic reduction of nitric oxide by ammonia. J Am Chem Soc 121:5595–5596
Sjövall H, Olsson L, Fridell E, Blint RJ (2006) Selective catalytic reduction of NO x with NH3 over Cu-ZSM-5-the effect of changing the gas composition. Appl Catal B 64:180–188
Sjövall H, Blint RJ, Olsson L (2009) Detailed kinetic modeling of NH3 SCR over Cu-ZSM-5. Appl Catal B 92:138–153
Wilken N, Wijayanti K, Kamasamudram K, Currier NW, Vedaiyan R, Yezerets A, Olsson L (2012) Mechanistic investigation of hydrothermal aging of Cu-Beta for ammonia SCR. Appl Catal B 111–112:58–66
Park J, Park H, Baik J, Nam I, Shin C, Lee J, Cho B, Oh S (2006) Hydrothermal stability of CuZSM5 catalyst in reducing NO by NH3 for the urea selective catalytic reduction process. J Catal 240:47–57
Kwak JH, Tonkyn RG, Kim DH, Szanyi J, Peden CHF (2010) Excellent activity and selectivity of Cu-SSZ-13 in the selective catalytic reduction of NO x with NH3. J Catal 275:187–190
Moliner M, Franch C, Palomares E, Grill M, Corma A (2012) Cu-SSZ-39, an active and hydrothermally stable catalyst for the selective catalytic reduction of NO x . Chem Commun 48:8264–8266
Sultana A, Nanba T, Sasaki M, Haneda M, Suzuki K, Hamada H (2011) Selective catalytic reduction of NO x with NH3 over different copper exchanged zeolites in the presence of decane. Catal Today 164:495–499
Ye Q, Wang L, Yang RT (2012) Activity, propene poisoning resistance and hydrothermal stability of copper exchanged chabazite-like zeolite catalysts for SCR of NO with ammonia in comparison to Cu/ZSM-5. Appl Catal A 427–428:24–34
Zones SI (1991) Conversion of faujasites to high-silica chabazite SSZ-13 in the presence of N, N, N-trimethyl-1-adamantammonium iodide. J Chem Soc Faraday Trans 87:3709–3716
Long RQ, Yang RT (1999) Catalytic performance of Fe-ZSM-5 catalysts for selective catalytic reduction of nitric oxide by ammonia. J Catal 188:332–339
Rahkamaa-Tolonen K, Maunula T, Lomma M, Huuhtanen M, Keiski RL (2005) The effect of NO2 on the activity of fresh and aged zeolite catalysts in the NH3-SCR reaction. Catal Today 100:217–222
Iwasaki M, Yamazaki K, Shinjoh H (2011) NO x reduction performance of fresh and aged Fe-zeolites prepared by CVD: effects of zeolite structure and Si/Al2 ratio. Appl Catal B 102:302–309
Long RQ, Yang RT (2001) Fe-ZSM-5 for selective catalytic reduction of NO with NH3: a comparative study of different preparation techniques. Catal Lett 74:201–205
Long RQ, Yang RT (2002) Reaction mechanism of selective catalytic reduction of NO with NH3 over Fe-ZSM-5 catalyst. J Catal 207:224–231
Rivallan M, Berlier G, Ricchiardi G, Zecchina A, Nechita M-T, Olsbye U (2008) Characterisation and catalytic activity in deNO x reactions of Fe-ZSM-5 zeolites prepared via ferric oxalate precursor. Appl Catal B 84:204–213
Brandenberger S, Kröcher O, Casapu M, Tissler A, Althoff R (2011) Hydrothermal deactivation of Fe-ZSM-5 catalysts for the selective catalytic reduction of NO with NH3. Appl Catal B 101:649–659
Chen H-Y, Sachtler WMH (1998) Activity and durability of Fe/ZSM-5 catalysts for lean burn NO x reduction in the presence of water vapor. Catal Today 42:73–83
Krishna K, Seijger GBF, van den Bleek CM, Makkee M, Mul G, Calis HPA (2003) Selective catalytic reduction of NO with NH3 over Fe-ZSM-5 catalysts prepared by sublimation of FeCl3 at different temperatures. Catal Lett 86:121–132
Qi G, Gatt JE, Yang RT (2004) Selective catalytic oxidation (SCO) of ammonia to nitrogen over Fe-exchanged zeolites prepared by sublimation of FeCl3. J Catal 226:120–128
Kumar MS, Schwidder M, Grünert W, Brückner A (2004) On the nature of different iron sites and their catalytic role in Fe-ZSM-5 deNO x catalysts: new insights by a combined EPR and UV/Vis spectroscopic approach. J Catal 227:384–397
Battiston AA, Bitter JH, de Groot FMF, Overweg AR, Stephan O, van Bokhoven JA, Kooyman PJ, van der Spek C, Vankó G, Koningsberger DC (2003) Evolution of Fe species during the synthesis of over-exchanged Fe/ZSM5 obtained by chemical vapor deposition of FeCl3. J Catal 213:251–271
Marturano P, Drozdova L, Pirngruber GD, Kogelbauer A, Prins R (2001) The mechanism of formation of the Fe species in Fe-ZSM-5 prepared by CVD. Phys Chem Chem Phys 3:5585–5595
Rauscher M, Kesore K, MoÈnnig R, Schwieger W, Tiûler A, Turek T (1999) Preparation of a highly active Fe-ZSM-5 catalyst through solid-state ion exchange for the catalytic decomposition of N2O. Appl Catal A 184:249–256
Devadas M, Kröcher O, Elsener M, Wokaun A, Mitrikas G, Söger N, Pfeifer M, Demel Y, Mussmann L (2007) Characterization and catalytic investigation of Fe-ZSM5 for urea-SCR. Catal Today 119:137–144
Qi G, Yang RT (2005) Ultra-active Fe/ZSM-5 catalyst for selective catalytic reduction of nitric oxide with ammonia. Appl Catal B 60:13–22
Qi G, Yang RT (2005) Selective catalytic oxidation (SCO) of ammonia to nitrogen over Fe/ZSM-5 catalysts. Appl Catal A 287:25–33
Delahay G, Valade D, Guzmanvargas A, Coq B (2005) Selective catalytic reduction of nitric oxide with ammonia on Fe-ZSM-5 catalysts prepared by different methods. Appl Catal B 55:149–155
Iwasaki M, Yamazaki K, Banno K, Shinjoh H (2008) Characterization of Fe/ZSM-5 deNO x catalysts prepared by different methods: relationships between active Fe sites and NH3-SCR performance. J Catal 260:205–216
Shi X, Liu F, Shan W, He H (2012) Hydrothermal deactivation of Fe-ZSM-5 prepared by different methods for the selective catalytic reduction of NO x with NH3. Chin J Catal 33:454–464
Schwidder M, Heikens S, Detoni A, Geisler S, Berndt M, Bruckner A, Grunert W (2008) The role of NO2 in the selective catalytic reduction of nitrogen oxides over Fe-ZSM-5 catalysts: active sites for the conversion of NO and of NO/NO2 mixtures. J Catal 259:96–103
Schwidder M, Kumar M, Klementiev K, Pohl M, Bruckner A, Grunert W (2005) Selective reduction of NO with Fe-ZSM-5 catalysts of low Fe content I. Relations between active site structure and catalytic performance. J Catal 231:314–330
Brandenberger S, Kröcher O, Tissler A, Althoff R (2010) The determination of the activities of different iron species in Fe-ZSM-5 for SCR of NO by NH3. Appl Catal B 95:348–357
Høj M, Beier MJ, Grunwaldt J-D, Dahl S (2009) The role of monomeric iron during the selective catalytic reduction of NO x by NH3 over Fe-BEA zeolite catalysts. Appl Catal B 93:166–176
Schwidder M, Santhosh Kumar M, Bruckner A, Grunert W (2005) Active sites for NO reduction over Fe-ZSM-5 catalysts. Chem Commun 6:805–807
Brandenberger S, Kröcher O, Tissler A, Althoff R (2011) Effect of structural and preparation parameters on the activity and hydrothermal stability of metal-exchanged ZSM-5 in the selective catalytic reduction of NO by NH3. Ind Eng Chem Res 50:4308–4319
Schwidder M, Santhosh Kumar M, Bentrup U, Pérez-Ramírez J, Brückner A, Grünert W (2008) The role of Brønsted acidity in the SCR of NO over Fe-MFI catalysts. Microporous Mesoporous Mater 111:124–133
Qi G, Wang Y, Yang RT (2008) Selective catalytic reduction of nitric oxide with ammonia over ZSM-5 based catalysts for diesel engine applications. Catal Lett 121:111–117
Li M, Yeom Y, Weitz E, Sachtler WMH (2006) An acid catalyzed step in the catalytic reduction of NO x to N2. Catal Lett 112:129–132
Savara A, Li M-J, Sachtler WMH, Weitz E (2008) Catalytic reduction of NH4NO3 by NO: effects of solid acids and implications for low temperature deNO x processes. Appl Catal B 81:251–257
Brandenberger S, Kröcher O, Wokaun A, Tissler A, Althoff R (2009) The role of Brønsted acidity in the selective catalytic reduction of NO with ammonia over Fe-ZSM-5. J Catal 268:297–306
Klukowski D, Balle P, Geiger B, Wagloehner S, Kureti S, Kimmerle B, Baiker A, Grunwaldt JD (2009) On the mechanism of the SCR reaction on Fe/HBEA zeolite. Appl Catal B 93:185–193
Kröcher O, Devadas M, Elsener M, Wokaun A, Söger N, Pfeifer M, Demel Y, Mussmann L (2006) Investigation of the selective catalytic reduction of NO by NH3 on Fe-ZSM5 monolith catalysts. Appl Catal B 66:208–216
He C, Wang Y, Cheng Y, Lambert CK, Yang RT (2009) Activity, stability and hydrocarbon deactivation of Fe/Beta catalyst for SCR of NO with ammonia. Appl Catal A 368:121–126
Ma L, Li J, Arandiyan H, Shi W, Liu C, Fu L (2012) Influence of calcination temperature on Fe/HBEA catalyst for the selective catalytic reduction of NO x with NH3. Catal Today 184:145–152
Pieterse JAZ, Pirngruber GD, van Bokhoven JA, Booneveld S (2007) Hydrothermal stability of Fe-ZSM-5 and Fe-BEA prepared by wet ion-exchange for N2O decomposition. Appl Catal B 71:16–22
Lee H-T, Rhee H-K (1999) Stability of Fe/ZSM-5 de-NO x catalyst: effects of iron loading and remaining Brønsted acid sites. Catal Lett 61:71–76
Iwasaki M, Shinjoh H (2011) Hydrothermal stability enhancement by sequential ion-exchange of rare earth metals on Fe/BEA zeolites used as NO reduction catalysts. Chem Commun 47:3966–3968
Long R, Yang RT (2000) Characterization of Fe-ZSM-5 catalyst for selective catalytic reduction of nitric oxide by ammonia. J Catal 194:80–90
Carja G, Delahay G, Signorile C, Coq B (2004) Fe-Ce-ZSM-5 a new catalyst of outstanding properties in the selective catalytic reduction of NO with NH3. Chem Commun 12:1404–1405
Heo I, Lee Y, Nam I-S, Choung JW, Lee J-H, Kim H-J (2011) Effect of hydrocarbon slip on NO removal activity of CuZSM5, FeZSM5 and V2O5/TiO2 catalysts by NH3. Microporous Mesoporous Mater 141:8–15
Li J, Zhu R, Cheng Y, Lambert CK, Yang RT (2010) Mechanism of propene poisoning on Fe-ZSM-5 for selective catalytic reduction of NO x with ammonia. Environ Sci Technol 44:1799–1805
Ma L, Li J, Cheng Y, Lambert CK, Fu L (2012) Propene poisoning on three typical Fe-zeolites for SCR of NO x with NH3: from mechanism study to coating modified architecture. Environ Sci Technol 46:1747–1754
Malpartida I, Marie O, Bazin P, Daturi M, Jeandel X (2011) An operando IR study of the unburnt HC effect on the activity of a commercial automotive catalyst for NH3-SCR. Appl Catal B 102:190–200
Kern P, Klimczak M, Heinzelmann T, Lucas M, Claus P (2010) High-throughput study of the effects of inorganic additives and poisons on NH3-SCR catalysts. Part II: Fe-zeolite catalysts. Appl Catal B 95:48–56
Silver RG, Stefanick MO, Todd BI (2008) A study of chemical aging effects on HDD Fe-zeolite SCR catalyst. Catal Today 136:28–33
Shwan S, Jansson J, Olsson L, Skoglundh M (2014) Chemical deactivation of Fe-BEA as NH3-SCR catalyst-effect of phosphorous. Appl Catal B 147:111–123
Ren L, Zhu L, Yang C, Chen Y, Sun Q, Zhang H, Li C, Nawaz F, Meng X, Xiao FS (2011) Designed copper-amine complex as an efficient template for one-pot synthesis of Cu-SSZ-13 zeolite with excellent activity for selective catalytic reduction of NO x by NH3. Chem Commun 47:9789–9791
Qi G, Yang RT (2005) Low-temperature SCR of NO with NH3 over noble metal promoted Fe-ZSM-5 catalysts. Catal Lett 100:243–246
Kim YJ, Kwon HJ, Heo I, Nam I-S, Cho BK, Choung JW, Cha M-S, Yeo GK (2012) Mn-Fe/ZSM5 as a low-temperature SCR catalyst to remove NO x from diesel engine exhaust. Appl Catal B 126:9–21
Sultana A, Sasaki M, Suzuki K, Hamada H (2013) Tuning the NO x conversion of Cu-Fe/ZSM-5 catalyst in NH3-SCR. Catal Commun 41:21–25
Koebel M, Elsener M, Kleemann M (2000) Urea-SCR: a promising technique to reduce NO x emissions from automotive diesel engines. Catal Today 59:335–345
Devadas M, Krocher O, Elsener M, Wokaun A, Soger N, Pfeifer M, Demel Y, Mussmann L (2006) Influence of NO2 on the selective catalytic reduction of NO with ammonia over Fe-ZSM5. Appl Catal B 67:187–196
Sun Q, Gao Z-X, Chen H-Y, Sachtler WMH (2001) Reduction of NO x with ammonia over Fe/MFI: reaction mechanism based on isotopic labeling. J Catal 201:88–99
Iwasaki M, Shinjoh H (2010) A comparative study of “standard”, “fast” and “NO2” SCR reactions over Fe/zeolite catalyst. Appl Catal A 390:71–77
Grossale A, Nova I, Tronconi E, Chatterjee D, Weibel M (2008) The chemistry of the NO/NO2-NH3 “fast” SCR reaction over Fe-ZSM5 investigated by transient reaction analysis. J Catal 256:312–322
Grossale A, Nova I, Tronconi E, Chatterjee D, Weibel M (2009) NH3-NO/NO2 SCR for diesel exhausts after treatment: reactivity, mechanism and kinetic modelling of commercial Fe- and Cu-promoted zeolite catalysts. Top Catal 52:1837–1841
Grossale A, Nova I, Tronconi E (2009) Ammonia blocking of the “Fast SCR” reactivity over a commercial Fe-zeolite catalyst for diesel exhaust after treatment. J Catal 265:141–147
Forzatti P, Nova I, Tronconi E (2009) Enhanced NH3 selective catalytic reduction for NO x abatement. Angew Chem Int Ed 48:8366–8368
Shi X, Liu F, Xie L, Shan W, He H (2013) NH3-SCR performance of fresh and hydrothermally aged Fe-ZSM-5 in standard and fast selective catalytic reduction reactions. Environ Sci Technol 47:3293–3298
PaÃrvulescua VI, Grange P, Delmon B (1998) Catalytic removal of NO. Catal Today 46:233–316
Baik JH, Yim SD, Nam I-S, Mok YS, Lee J-H, Cho BK, Oh SH (2004) Control of NO x emissions from diesel engine by selective catalytic reduction (SCR) with urea. Top Catal 30–31:37–41
Komatsu T, Nunokawa M, Moon IS, Takahara T, Namba S, Yashima T (1994) Kinetic studies of reduction of nitric oxide with ammonia on Cu2+-exchanged zeolites. J Catal 148:427–437
Sultana A, Nanba T, Haneda M, Hamada H (2009) SCR of NO x with NH3 over Cu/NaZSM-5 and Cu/HZSM-5 in the presence of decane. Catal Commun 10:1859–1863
Richter M, Eckelt R, Parlitz B, Fricke R (1998) Low-temperature conversion of NO, to N2 by zeolite-fixed ammonium ions. Appl Catal B 15:129–146
Moden B, Donohue JM, Cormier WE, Li H-X (2008) Effect of Cu-loading and structure on the activity of Cu-exchanged zeolites for NH3-SCR. In: Stud Surf Sci Catal, edn. Elsevier, Paris: France, pp 1219–1222
Blakeman PG, Burkholder EM, Chen H-Y, Collier JE, Fedeyko JM, Jobson H, Rajaram RR (2014) The role of pore size on the thermal stability of zeolite supported Cu SCR catalysts. Catal Today 231:56–63
Fickel DW, D’Addio E, Lauterbach JA, Lobo RF (2011) The ammonia selective catalytic reduction activity of copper-exchanged small-pore zeolites. Appl Catal B 102:441–448
Luo J-Y, Oh H, Henry C, Epling W (2012) Effect of C3H6 on selective catalytic reduction of NO x by NH3 over a Cu/zeolite catalyst: a mechanistic study. Appl Catal B 123–124:296–305
Aoki K, Kusakabe K, Morooka S (2000) Separation of gases with an A-Type zeolite membrane. Ind Eng Chem Res 39:2245–2251
Gao F, Walter ED, Karp EM, Luo J, Tonkyn RG, Kwak JH, Szanyi J, Peden CHF (2013) Structure-activity relationships in NH3-SCR over Cu-SSZ-13 as probed by reaction kinetics and EPR studies. J Catal 300:20–29
Schmieg SJ, Oh SH, Kim CH, Brown DB, Lee JH, Peden CHF, Kim DH (2012) Thermal durability of Cu-CHA NH3-SCR catalysts for diesel NO x reduction. Catal Today 184:252–261
Ma L, Cheng Y, Cavataio G, McCabe RW, Fu L, Li J (2013) Characterization of commercial Cu-SSZ-13 and Cu-SAPO-34 catalysts with hydrothermal treatment for NH3-SCR of NO x in diesel exhaust. Chem Eng J 225:323–330
Bordiga S, Regli L, Cocina D, Lamberti C, Bjørgen M, Lillerud KP (2005) Assessing the acidity of high silica chabazite H-SSZ-13 by FTIR using CO as molecular probe comparison with H-SAPO-34. J Phys Chem C 109:2779–2784
Wang J, Yu T, Wang X, Qi G, Xue J, Shen M, Li W (2012) The influence of silicon on the catalytic properties of Cu/SAPO-34 for NO x reduction by ammonia-SCR. Appl Catal B 127:137–147
Yu T, Wang J, Shen M, Li W (2013) NH3-SCR over Cu/SAPO-34 catalysts with various acid contents and low Cu loading. Catal Sci Technol 3:3234–3241
Wang L, Gaudet JR, Li W, Weng D (2013) Migration of Cu species in Cu/SAPO-34 during hydrothermal aging. J Catal 306:68–77
Fan S, Xue J, Yu T, Fan D, Hao T, Shen M, Li W (2013) The effect of synthesis methods on Cu species and active sites over Cu/SAPO-34 for NH3-SCR reaction. Catal Sci Technol 3:2357–2364
Deka U, Lezcano-Gonzalez I, Warrender SJ, Lorena Picone A, Wright PA, Weckhuysen BM, Beale AM (2013) Changing active sites in Cu-CHA catalysts: deNO x selectivity as a function of the preparation method. Microporous Mesoporous Mater 166:144–152
Wang L, Li W, Qi G, Weng D (2012) Location and nature of Cu species in Cu/SAPO-34 for selective catalytic reduction of NO with NH3. J Catal 289:21–29
Gao F, Walter ED, Washton NM, Szanyi J, Peden CHF (2013) Synthesis and evaluation of Cu-SAPO-34 catalysts for ammonia selective catalytic reduction. 1. Aqueous solution ion exchange. ACS Catal 3:2083–2093
Dĕdeček J, Wichterlová B, Kubát P (1999) Siting of the Cu+ ions in dehydrated ion exchanged synthetic and natural chabasites: a Cu+ photoluminescence study. Microporous Mesoporous Mater 32:63–74
Zamadies M, Chen X, Kevan L (1992) Study of Cu(II) location and adsorbate interaction in CuH-SAPO-34 molecular sieve by electron Sp4 resoname and electron spin echo modulath spectroscopies. J Phys Chem 96:2652–2657
Fickel DW, Lobo RF (2010) Copper coordination in Cu-SSZ-13 and Cu-SSZ-16 investigated by Variable-Temperature XRD. J Phys Chem C 114:1633–1640
Korhonen ST, Fickel DW, Lobo RF, Weckhuysen BM, Beale AM (2011) Isolated Cu2+ ions: active sites for selective catalytic reduction of NO. Chem Commun 47:800–802
Deka U, Juhin A, Eilertsen EA, Emerich H, Green MA, Korhonen ST, Weckhuysen BM, Beale AM (2012) Confirmation of isolated Cu2+ ions in SSZ-13 Zeolite as active sites in NH3-selective catalytic reduction. J Phys Chem C 116:4809–4818
Kispersky VF, Kropf AJ, Ribeiro FH, Miller JT (2012) Low absorption vitreous carbon reactors for operando XAS: a case study on Cu/Zeolites for selective catalytic reduction of NO x by NH3. Phys Chem Chem Phys 14:2229–2238
McEwen JS, Anggara T, Schneider WF, Kispersky VF, Miller JT, Delgass WN, Ribeiro FH (2012) Integrated operando X-ray absorption and DFT characterization of Cu-SSZ-13 exchange sites during the selective catalytic reduction of NO x with NH3. Catal Today 184:129–144
Kwak JH, Zhu H, Lee JH, Peden CH, Szanyi J (2012) Two different cationic positions in Cu-SSZ-13? Chem Commun 48:4758–4760
Xue J, Wang X, Qi G, Wang J, Shen M, Li W (2013) Characterization of copper species over Cu/SAPO-34 in selective catalytic reduction of NO x with ammonia: relationships between active Cu sites and de-NO x performance at low temperature. J Catal 297:56–64
Aguayo AT, Gayubo AG, Vivanco R, Olazar M, Bilbao J (2005) Role of acidity and microporous structure in alternative catalysts for the transformation of methanol into olefins. Appl Catal A 283:197–207
Colombo M, Nova I, Tronconi E (2012) Detailed kinetic modeling of the NH3-NO/NO2 SCR reactions over a commercial Cu-zeolite catalyst for Diesel exhausts after treatment. Catal Today 197:243–255
Kwak JH, Tran D, Szanyi J, Peden CHF, Lee JH (2012) The Effect of copper loading on the selective catalytic reduction of Nitric Oxide by ammonia over Cu-SSZ-13. Catal Lett 142:295–301
Zhu H, Kwak JH, Peden CHF, Szanyi J (2013) In situ DRIFTS-MS studies on the oxidation of adsorbed NH3 by NO x over a Cu-SSZ-13 zeolite. Catal Today 205:16–23
Kwak JH, Lee JH, Burton SD, Lipton AS, Peden CH, Szanyi J (2013) A common intermediate for N2 formation in enzymes and zeolites: side-on Cu-nitrosyl complexes. Angew Chem Int Ed 52:9985–9989
Metkar PS, Balakotaiah V, Harold MP (2012) Experimental and kinetic modeling study of NO oxidation: comparison of Fe and Cu-zeolite catalysts. Catal Today 184:115–128
Wang D, Zhang L, Kamasamudram K, Epling WS (2013) In Situ-DRIFTS study of selective catalytic reduction of NO x by NH3 over Cu-exchanged SAPO-34. ACS Catal 3:871–881
Trukhan N, Mueller U, Bull I (2011) US Patent 2011/0076229, 31 Mar 2011
Xie L, Liu F, Ren L, Shi X, Xiao FS, He H (2014) Excellent performance of one-pot synthesized Cu-SSZ-13 catalyst for the selective catalytic reduction of NO with NH3. Environ Sci Technol 48:566–572
Xie L, Liu F, Xiao FS, He H. Effects of post-treatment method and Na co-cation on the hydrothermal stability of Cu-SSZ-13 catalyst for the selective catalytic reduction of NO x with NH3. To be published
Xie L, Liu F, Shi X, He H (2013) Influence of calcination procedure on NH3-SCR performance of Cu-SSZ-13 catalysts prepared by one-pot synthesis method. Paper presented at the 6th Asia-Pacific Congress on Catalysis, Taipei, Taiwan, 13–17 October, 2013
Xie L (2014) Selective catalytic reduction of NO x with NH3 over highly efficient Cu-SSZ-13 catalyst. PhD thesis in the University of Chinese Academy of Sciences
Verma AA, Anggara T, Bates SA, Parekh AA, Paolucci C, Schneider WF, Yezerets A, Kamasamudram K, Miller JT, Delgass WN, Ribeiro FH (2013) NO oxidation: a probe reaction on Cu-SSZ13. Paper presented at the 23rd North American catalysis society meeting, Galt House Hotel, Kentucky, Louisville, 2–7 June 2013
Xie L, Liu F, Liu K, Shi X, He H (2014) Inhibitory effect of NO2 on the selective catalytic reduction of NO x with NH3 over one-pot-synthesized Cu-SSZ-13 catalyst. Catal Sci Technol 4:1104–1110
Ciardelli C, Nova I, Tronconi E, Chatterjee D, Bandl-Konrad B (2004) A “Nitrate Route” for the low temperature “Fast SCR” reaction over a V2O5–WO3/TiO2 commercial catalyst. Chem Commun 23:2718–2719
Martínez-Franco R, Moliner M, Thogersen JR, Corma A (2013) Efficient One-Pot preparation of Cu-SSZ-13 materials using cooperative OSDAs for their catalytic application in the SCR of NO x . ChemCatChem 5:3316–3323
Martínez-Franco R, Moliner M, Franch C, Kustov A, Corma A (2012) Rational direct synthesis methodology of very active and hydrothermally stable Cu-SAPO-34 molecular sieves for the SCR of NO x . Appl Catal B 127:273–280
Lorena PA, Warrender SJ, Slawin AMZ, Dawson DM, Ashbrook SE, Wright PA, Thompson SP, Gaberova L, Llewellyn PL, Moulin B, Vimont A, Daturi M, Park MB, Sung SK, Nam I-S, Hong SB (2011) A co-templating route to the synthesis of Cu SAPO STA-7, giving an active catalyst for the selective catalytic reduction of NO. Microporous Mesoporous Mater 146:36–47
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Liu, F., Xie, L., Shi, X., He, H. (2016). Emerging Applications of Environmentally Friendly Zeolites in the Selective Catalytic Reduction of Nitrogen Oxides. In: Xiao, FS., Meng, X. (eds) Zeolites in Sustainable Chemistry. Green Chemistry and Sustainable Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-47395-5_12
Download citation
DOI: https://doi.org/10.1007/978-3-662-47395-5_12
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-47394-8
Online ISBN: 978-3-662-47395-5
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)