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Fluorescent Dissolved Organic Matter in Natural Waters

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Photobiogeochemistry of Organic Matter

Abstract

Dissolved organic matter (DOM), of allochthonous and autochthonous origin, is a heterogeneous mixture of organic compounds, with molecular weights ranging from less than 100 to over 300,000 Da in natural waters. The DOM components are involved into key biogeochemical processes such as global carbon cycle, nutrient dynamics, photosynthesis, biological activity and finally as energy sources in the aquatic environments. Among the DOM components, only a limited fraction of organic compounds show fluorescence properties. These compounds are termed the fluorescent DOM (FDOM). In the pioneering works conducted by Kalle and Duursma, the fluorescence of terrestrial humic substances served as a tracer of soil organic matter in freshwater and seawater environments. The fluorescence of humic substances has then been used to distinguish the mixing of river water with seawater as well as their sources.

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Acknowledgments

We thank Dr. Kazuhide Hayakawa of Lake Biwa Environmental Research Institute, Japan for his valuable comments; Dr. Jie Yuan and Dr. Ling Li of Institute of Geochemistry, Chinese Academy of Sciences for their generous help. This work was financially supported by the Institute of Geochemistry, the Chinese Academy of Sciences, Guiyang, China. This work was partly supported by Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, China; Kyoto University, Japan; University Turin, Italy; and Hiroshima University, Japan. This chapter acknowledges the reprinted from Senesi (1990a), Copyright (1990), with permission from Elsevier; reprinted from Zhang et al. (2010), Copyright (2010), with permission from Elsevier; Copyright (2005, 2007) by The Geochemical Society of Japan; reprinted from Stedmon et al. (2003), Copyright (2003), with permission from Elsevier; reprinted from Bro (1997), Copyright (1997), with permission from Elsevier; copyright (2005, 2010) by the Japanese Society of Limnology; Copyright (2009) CSIRO; reprinted from Patel-Sorrentino et al. (2002), Copyright (2002), with permission from Elsevier; and reprinted (adapted) with permission from Clarke et al. (1976), Copyright (1976) American Chemical Society.

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Mostofa, K.M.G., Liu, Cq., Yoshioka, T., Vione, D., Zhang, Y., Sakugawa, H. (2013). Fluorescent Dissolved Organic Matter in Natural Waters. In: Mostofa, K., Yoshioka, T., Mottaleb, A., Vione, D. (eds) Photobiogeochemistry of Organic Matter. Environmental Science and Engineering(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-32223-5_6

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