Skip to main content

Introduction

  • Chapter
  • First Online:
Chromium -VI Reagents: Synthetic Applications

Part of the book series: SpringerBriefs in Molecular Science ((BRIEFSMOLECULAR))

  • 576 Accesses

Abstract

Oxidation is an important process in many natural events, including our life cycle. Oxidation is defined as the addition of oxygen, loss of hydrogen or loss of electrons. Thus the molecular oxygen itself or a substance which can release oxygen on decomposition, such as peroxides, can act as oxidizing agents. On the other hand, metals being highly electropositive, they tend to lose electrons easily and thus any metal atom which can exist in more than one valency can function as an oxidant under suitable conditions. Consequently oxidants may be classified as metal oxidants and non-metal oxidants.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 16.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. Westheimer FH (1949) Chem Rev 45:419

    Article  CAS  Google Scholar 

  2. Venkatasubramanian N (1963) J Sci Ind Res 22:397

    Google Scholar 

  3. Waters WA (1964) Mechanism of oxidation of organic compounds. Methun and Co Ltd, London

    Google Scholar 

  4. Stewart R (1964) Oxidation mechanisms. Benjamin Inc, New York

    Google Scholar 

  5. Wiberg KB (1964) Oxidation in organic chemistry. Academic Press Inc, New York

    Google Scholar 

  6. Sundaram S, Venkatasubramanian N, Ananatakrishnan SV (1967) J Sci Ind Res 35:518

    Google Scholar 

  7. Cainelli G, Cardillo G (1984) Reactivity and structure: concepts in organic chemistry, vol 19. Springer, New York

    Google Scholar 

  8. Freeman F (1973) Reviews on the active species in chemical reaction. In: Dayagi S (ed) Chromylchloride oxidations of organic compounds. Freund Publishing Ltd, Israel, pp 39–66

    Google Scholar 

  9. Freeman F (1986) Oxidation by oxochromium(VI) compounds; In: Mij’s WJ, De Jonge, Cornelis RHI (eds) Organic Syntheses Oxidation by Metallic Compounds, Plenum Press, NY, p 41–118

    Google Scholar 

  10. Rocek J (1966) Chemistry of carbonyl compounds. In: Patai S (ed). Interscience, London

    Google Scholar 

  11. Bamford CH, Tipper CFH (1971) Comprehensive chemical kinetics, vol 7. Elsevier, New York

    Google Scholar 

  12. Corey EJ, Suggs JW (1975) Tetrahedron Lett 2647

    Google Scholar 

  13. De Asish (1982) J Sci Ind Res 41:484

    CAS  Google Scholar 

  14. Piancatelli G, Scettri A, D’Auria M. (1982) Synthesis 245

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Raghavan Seshan .

Rights and permissions

Reprints and permissions

Copyright information

© 2011 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Srinivasan, S., Seshan, R. (2011). Introduction. In: Chromium -VI Reagents: Synthetic Applications. SpringerBriefs in Molecular Science(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-20817-1_1

Download citation

Publish with us

Policies and ethics