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Ultra-Trace Analysis of Palladium: State-of-the-Art and Future Challenges

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Urban Airborne Particulate Matter

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Abstract

Due to the introduction of the three-way catalytic converter (TWC) in Europe in the mid-eighties, determination of platinum group elements (PGE) in environmental compartments has received elevated interest over the past two decades. While improving air quality by converting hydrocarbons, carbon monoxide, and nitrogen oxides into the less harmful substances carbon dioxide, nitrogen, and water, the use of these devices constitutes a new source for the widespread emission of PGE into the environment.

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References

  • Amosse J (1998) Determination of platinum-group elements and gold in geological matrixes by inductively coupled plasma-mass spectrometry (ICP-MS) after separation with selenium and tellurium carriers. Geostand Newslett 22:93–102

    Article  CAS  Google Scholar 

  • Balcerzak M (2002) Sample digestion methods for the determination of traces of precious metals by spectrometric techniques. Anal Sci 18:737–750

    Article  CAS  Google Scholar 

  • Barbante C, Veysseyre A, Ferrari C, Van de Velde K, Morel C, Capodaglio G, Cescon P, Scarponi G, Boutron C (2001) Greenland snow evidence of large scale atmospheric contamination for platinum, palladium, and rhodium. Env Sci Technol 35:835–839

    Article  CAS  Google Scholar 

  • Barefoot RR (1999) Distribution and speciation of platinum group elements in environmental matrices. Trends Anal Chem 18:702–711

    Article  CAS  Google Scholar 

  • Begerow J, Turfeld M, Dunemann L (1997) Determination of physiological palladium, platinum, iridium and gold levels in human blood using double focusing magnetic sector field inductively coupled plasma mass spectrometry. J Anal At Spectrom 12:1095–1098

    Article  CAS  Google Scholar 

  • Bencs L, Ravindra K, Van Grieken R (2003) Methods for the determination of platinum group elements originating from the abrasion of automotive catalytic converters. Spectrochim Acta B 58:1723–1755

    Article  Google Scholar 

  • Boch K, Schuster M, Risse G, Schwarzer M (2002) Microwave-assisted digestion procedure for the determination of palladium in road dust. Anal Chim Acta 459:257–265

    Article  CAS  Google Scholar 

  • Brzezicka M, Szmyd E (1999) Investigation of the influence of interfering elements on the determination of palladium in copper ores by graphite furnace atomic absorption spectrometry. Spectrochim Acta B 54:883–889

    Article  Google Scholar 

  • Caroli S, Alimonti A, Petrucci F, Bocca B, Krachler M, Forastiere F, Sacerdote MT, Mallone S (2001) Assessment of exposure to platinum group metals in urban children. Spectrochim Acta B 56:1241–1248

    Article  Google Scholar 

  • Colombo C, Monhemius AJ, Plant JA (2008) Platinum, palladium and rhodium release from vehicle exhaust catalysts and road dust exposed to simulated lung fluids. Ecotoxicol Env Saf 71:722–730

    Article  CAS  Google Scholar 

  • da Silva MAM, Frescura VLA, Curtius AJ (2001) Determination of noble metals in biological samples by electrothermal vaporization inductively coupled plasma mass spectrometry, following cloud point extraction. Spectrochim Acta B 56:1941–1949

    Article  Google Scholar 

  • da Silva LID, de Souza Sarkis JE, Zotin FMZ, Carneiro MC, Neto AA, da Silva ASAG, Cardoso MJB, Monteiro MIC (2008) Traffic and catalytic converter-related atmospheric contamination in the metropolitan region of the city of Rio de Janeiro, Brazil. Chemosphere 71:677–684

    Article  Google Scholar 

  • de Vos E, Edwards SJ, McDonald I, Wray DS, Carey PJ (2002) A baseline survey of the distribution and origin of platinum group elements in contemporary fluvial sediments of the Kentish Stour, England. Appl Geochem 17:1115–1121

    Article  Google Scholar 

  • Ek KH, Morrison GM, Rauch S (2004) Environmental routes for platinum group elements to biological materials—a review. Sci Total Env 334–335:21–38

    Article  Google Scholar 

  • Ely JC, Neal CR, O’Neill J, Jain JC (1999) Quantifying the platinum group elements (PGE) and gold in geological samples using cation exchange pretreatment and ultrasonic nebulization inductively coupled plasma-mass spectrometry (USN-ICP-MS). Chem Geol 157:219–234

    Article  CAS  Google Scholar 

  • Falta T, Limbeck A, Stingeder G, Hann S (2007) Ultra-trace determination of palladium in human urine samples via flow injection coupled with ICP-MS. At Spectr 28:81–89

    CAS  Google Scholar 

  • Fraser MP, Cass GR, Simoneit BRT (1999) Particulate organic compounds emitted from motor vehicle exhaust in the atmosphere. Atmos Env 33:2715–2724

    Article  CAS  Google Scholar 

  • Fritz JS (1999) Analytical solid-phase extraction. Wiley-VCH, New York

    Google Scholar 

  • Georgieva M, Pihlar B (1997) Determination of palladium by adsorptive stripping voltammetry. Fresenius J Anal Chem 357:847–880

    Article  Google Scholar 

  • Godlewska-Zylkiewicz B, Lesniewska BA, Gasiewska U, Hulanicki A (2000) Ion-exchange preconcentration and separation of trace amounts of platinum and palladium. Anal Lett 33:2805–2820

    Article  CAS  Google Scholar 

  • Gomez B, Gomez M, Sanchez JL, Fernandez R, Palacios MA (2001) Platinum and rhodium distribution in airborne particulate matter and road dust. Science Total Env 269:131–144

    Article  CAS  Google Scholar 

  • Gomez MB, Gomez MM, Palacios MA (2003) ICP-MS determination of Pt, Pd and Rh in airborne and road dust after tellurium coprecipitation. J Anal At Spectrom 18:80–83

    Article  CAS  Google Scholar 

  • Hann S, Köllensperger G, Kanitsar K, Stingeder G (2001) ICP-SFMS determination of palladium using IDMS in combination with on-line and off-line matrix separation. J Anal At Spectrom 16:1057–1063

    Article  CAS  Google Scholar 

  • Heumann KG (2004) Isotope-dilution ICP-MS for trace element determination and speciation: from a reference method to a routine method? Anal Bioanal Chem 378:318–329

    Article  CAS  Google Scholar 

  • Hossain KZ, Honjo T (2000) Separation of trace amounts of palladium(II) with crown ether from hydrochloric acid and potassium thiocyanate media. Fresenius J Anal Chem 367:141–145

    Article  CAS  Google Scholar 

  • Jarvis I, Totland MM, Jarvis KE (1997) Determination of the platinum-group elements in geological materials by ICP-MS using microwave digestion, alkali fusion and cation-exchange chromatography. Chem Geol 143:27–42

    Article  CAS  Google Scholar 

  • Jarvis KE, Parry SJ, Piper JM (2001) Temporal and spatial studies of autocatalyst-derived platinum, rhodium, and palladium and selected vehicle-derived trace elements in the environment. Env Sci Technol 35:1031–1036

    Article  CAS  Google Scholar 

  • Johnson Matthey Precious Metal Marketing, Johnson Matthey Plc, London, UK, 2009. http://www.platinum.matthey.com/publications/12108520516719.html

  • Kanitsar K, Köllensperger G, Hann S, Limbeck A, Puxbaum H, Stingeder G (2003) Determination of Pt, Pd and Rh by inductively coupled plasma sector field mass spectrometry (ICP-SFMS) in size-classified urban aerosol samples. J Anal At Spectrom 18:239–246

    Article  CAS  Google Scholar 

  • Kántor T (2001) Electrothermal vaporization and laser ablation sample introduction for flame and plasma spectrometric analysis of solid and solution samples. Spectrochim Acta B 56:1523–1563

    Article  Google Scholar 

  • Köllensberger G, Hann S, Stingeder G (2000) Determination of Rh, Pd and Pt in environmental silica containing matrices: capabilities and limitations of ICP-MS. J Anal At Spectrom 15:1553–1557

    Article  Google Scholar 

  • Kovacheva P, Djingova R (2002) Ion-exchange method for separation and concentration of platinum and palladium for analysis of environmental samples by inductively coupled plasma atomic emission spectrometry. Anal Chim Acta 464:7–13

    Article  CAS  Google Scholar 

  • Krachler M, Alimonti A, Pertrucci F, Irgolic KJ, Forastiere F, Caroli S (1998) Analytical problems in the determination of platinum-group metals in urine by quadrupole and magnetic sector field inductively coupled plasma mass spectrometry. Anal Chim Acta 363:1–10

    Article  CAS  Google Scholar 

  • Lesniewska BA, Godlewska-Zylkiewicz B, Ruszczynska A, Bulska E, Hulanicki A (2006) Elimination of interferences in determination of platinum and palladium in environmental samples by inductively coupled plasma mass spectrometry. Anal Chim Acta 564:236–242

    Article  CAS  Google Scholar 

  • Limbeck A (2005) Short-term variation of palladium in airborne particulate matter. In: Zereini F, Alt F (eds) Palladium emissions in the environment: analytical methods, environmental assessment and health effects. Springer, Berlin, pp 381–396

    Google Scholar 

  • Limbeck A (2006) Microwave-assisted UV-digestion procedure for the accurate determination of Pd in natural waters. Anal Chim Acta 575:114–119

    Article  CAS  Google Scholar 

  • Limbeck A, Rendl J, Puxbaum H (2003) ETAAS determination of palladium in environmental samples with on-line preconcentration and matrix separation. J Anal At Spectrom 18:161–165

    Article  CAS  Google Scholar 

  • Limbeck A, Rendl J, Heimburger G, Kranabetter A, Puxbaum H (2004) Seasonal variation of palladium, elemental carbon and aerosol mass concentrations in airborne particulate matter. Atmos Env 38:1979–1987

    Article  CAS  Google Scholar 

  • Limbeck A, Puls C, Handler M (2007) Platinum and palladium emissions from on-road vehicles in the Kaisermühlen tunnel (Vienna, Austria). Env Sci Technol 41:4938–4945

    Article  CAS  Google Scholar 

  • Liu P, Su Z, Wu X, Pu Q (2002) Application of isodiphenylthiourea immobilized silica gel to flow injection on-line microcolumn preconcentration and separation coupled with flame atomic absorption spectrometry for interference-free determination of trace silver, gold, palladium and platinum in geological and metallurgical samples. J Anal At Spectrom 17:125–130

    Article  CAS  Google Scholar 

  • Lough GC, Schauer JJ, Park J, Shafer MM, DeMinter JT, Weinstein JP (2005) Emissions of metals associated with motor vehicle roadways. Env Sci Technol 39:826–836

    Article  CAS  Google Scholar 

  • Matsubara I, Takeda Y, Ishida K (2000) Improved recovery of trace amounts of gold (III), palladium (II) and platinum (IV) from large amounts of associated base metals using anion-exchange resins. Fresenius J Anal Chem 366:213–217

    Article  CAS  Google Scholar 

  • Meisel T, Fellner N, Moser J (2003) A simple procedure for the determination of platinum group elements and rhenium (Ru, Rh, Pd, Re, Os, Ir and Pt) using ID-ICP-MS with an inexpensive on-line matrix separation in geological and environmental materials. J Anal At Spectrom 18:720–726

    Article  CAS  Google Scholar 

  • Messerschmidt J, von Bohlen A, Alt F, Klockenkamper R (2000) Separation and enrichment of palladium and gold in biological and environmental samples, adapted to the determination by total reflection X-ray fluorescence. Analyst 125:397–399

    Article  CAS  Google Scholar 

  • Moldovan M, Gomez MM, Palacios MA (1999) Determination of platinum, rhodium and palladium in car exhaust fumes. J Anal At Spectrom 14:1163–1169

    Article  CAS  Google Scholar 

  • Moldovan M, Rauch S, Gomez M, Palacios MA, Morrison GM (2001) Bioaccumulation of palladium, platinum and rhodium from urban particulates and sediments by the freshwater isopod Asellus aquaticus. Water Res 35:4175–4183

    Article  CAS  Google Scholar 

  • Moldovan M, Palacios MA, Gomez MM, Morrison GM, Rauch S, McLeod C, Ma R, Caroli S, Alimonti A, Petrucci F, Bocca B, Schramel P, Zischka M, Pettersson C, Wass U, Luna M, Saenz JC, Santamarıa J (2002) Environmental risk of particulate and soluble platinum group elements released from gasoline and diesel engine catalytic converters. Sci Total Env 296:199–208

    Article  CAS  Google Scholar 

  • Moldovan M, Gomez M, Palacios MA (2003) On-line preconcentration of palladium on alumina microcolumns and determination in urban waters by inductively coupled plasma mass spectrometry. Anal Chim Acta 478:209–217

    Article  CAS  Google Scholar 

  • Müller M, Heumann KG (2000) Isotope dilution inductively coupled plasma quadrupole mass spectrometry in connection with a chromatographic separation for ultra trace determinations of platinum group elements (Pt, Pd, Ru, Ir) in environmental samples. Fresenius J Anal Chem 368:109–115

    Article  Google Scholar 

  • Muzikar M, Fontas C, Hidalgo M, Havel J, Salvado V (2006) A preconcentration system using polyamine Metalfix-Chelamine resin for the on-line determination of palladium(II) and platinum(IV) by inductively coupled plasma optical emission spectrometry. Talanta 70:1081–1086

    Article  CAS  Google Scholar 

  • Palacios MA, Gomez MM, Moldovan M, Morrison G, Rauch S, McLeod C, Ma R, Laserna J, Lucena P, Caroli S, Alimonti A, Petrucci F, Bocca B, Schramel P, Lustig S, Zischka M, Wass U, Stenbom B, Luna M, Saenz JC, Santamaria J, Torrents JM (2000) Platinum-group elements: quantification in collected exhaust fumes and studies of catalytist surfaces. Sci Total Env 257:1–15

    Article  CAS  Google Scholar 

  • Patel KS, Sharma PC, Hoffmann P (2000) Graphite furnace-atomic absorption spectrophotometric determination of palladium in soil. Fresenius J Anal Chem 367:738–741

    Article  CAS  Google Scholar 

  • Petrucci F, Bocca B, Alimonti A, Caroli S (2000) Determination of Pd, Pt and Rh in airborne particulate and road dust by high-resolution ICP-MS: a preliminary investigation of the emission from automotive catalysts in the urban area of Rome. J Anal At Spectrom 15:525–528

    Article  CAS  Google Scholar 

  • Radziuk B, Rödel G, Stenz H, Becker-Ross H, Florek S (1995) Spectrometer system for simultaneous multielement electrothermal atomic absorption spectrometry using line sources and Zeeman-effect background correction. J Anal At Spectrom 10:127–136

    Article  CAS  Google Scholar 

  • Rao CRM, Reddi GS (2000) Platinum group metals (PGM); occurrence, use and recent trends in their determination. Trends Anal Chem 19:565–586

    Article  CAS  Google Scholar 

  • Rauch S, Lu M, Morrison GM (2001) Heterogeneity of platinum group metals in airborne particles. Env Sci Technol 35:595–599

    Article  CAS  Google Scholar 

  • Rauch S, Hemond HF, Peuker-Ehrenbrink B, Ek KH, Morrison GM (2005) Platinum group element concentrations and osmium isotopic composition in urban airborne particles from Boston, Massachusetts. Env Sci Technol 39:9464–9470

    Article  CAS  Google Scholar 

  • Ravindra K, Bencs L, Van Grieken R (2004) Platinum group elements in the environment and their health risk. Sci Total Env 318:1–43

    Article  CAS  Google Scholar 

  • Rudolph E, Limbeck A, Hann S (2006) Novel matrix separation-on-line pre-concentration procedure for accurate quantification of palladium in environmental samples by isotope dilution inductively coupled plasma sector field mass spectrometry. J Anal At Spectrom 21:1287–1293

    Article  CAS  Google Scholar 

  • Schäfer J, Hannker D, Eckhardt JD, Stüben D (1998) Uptake of traffic-related heavy metals and platinum group elements (PGM) by plants. Sci Total Env 215:59–67

    Article  Google Scholar 

  • Schäfer J, Eckhardt JD, Berner ZA, Stüben D (1999) Time-dependent increase of traffic-emitted platinum-group elements (PGE) in different environmental compartments. Env Sci Technol 33:3166–3170

    Article  Google Scholar 

  • Schuster M, Schwarzer M (1996) Selective determination of palladium by online column preconcentration and graphite furnace atomic absorption spectrometry. Anal Chim Acta 328:1–11

    Article  CAS  Google Scholar 

  • Shazali I, Van’t Dack L, Gijbels R (1987) Determination of precious metals in ores and rocks by thermal neutron activation/γ-spectrometry after preconcentration by nickel sulfide fire assay and coprecipitation with tellurium. Anal Chim Acta 196:49–58

    Article  CAS  Google Scholar 

  • Sternbeck J, Sjodin A, Andreasson K (2002) Metal emissions from road traffic and the influence of resuspension—results from two tunnel studies. Atmos Env 36:4735–4744

    Article  CAS  Google Scholar 

  • Sun Y, Guan X, Du A (1998) Determination of platinum group elements by inductively coupled plasma-mass spectrometry combined with nickel sulfide fire assay and tellurium coprecipitation. Spectrochim Acta B 53:1463–1467

    Article  Google Scholar 

  • Sures B, Zimmermann S, Messerschmidt J, von Bohlen A, Alt F (2001) First report on the uptake of automobile catalyst emitted palladium by European eels (Anguilla anguilla) following experimental exposure to road dust. Env Pollut 113:341–345

    Article  CAS  Google Scholar 

  • Sures B, Zimmermann S, Messerschmidt J, von Bohlen A (2002) Relevance and analysis of traffic related platinum group metals (Pt, Pd, Rh) in the aquatic biosphere, with emphasis on palladium. Ecotoxicology 11:385–392

    Article  CAS  Google Scholar 

  • Tilch J, Schuster M, Schwarzer M (2000) Determination of palladium in airborne particulate matter in a German city. Fresenius J Anal Chem 367:450–453

    Article  CAS  Google Scholar 

  • Turner A, Crussel M, Millward GE, Cobelo-Garcia A, Fisher AS (2006) Adsorption kinetics of platinum group elements in river water. Env Sci Technol 40:1524–1531

    Article  CAS  Google Scholar 

  • Vlasankova R, Otruba V, Bendl J, Fisera M, Kanicky V (1999) Preconcentration of platinum group metals on modified silica gel and their determination by inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry in airborne particulates. Talanta 48:839–846

    Article  CAS  Google Scholar 

  • Wang J, Varughese K (1987) Determination of traces of palladium by adsorptive stripping voltammetry of the dimethylglyoxime complex. Anal Chim Acta 199:185–189

    Article  CAS  Google Scholar 

  • Zereini F, Alt F (2000) Anthropogenic platinum-group element emissions. Their impact on man and environment. Springer, Berlin

    Book  Google Scholar 

  • Zereini F, Wiseman C, Alt F, Messerschmidt J, Müller J, Urban H (2001) Platinum and rhodium concentrations in airborne particulate matter in Germany from 1988 to 1998. Env Sci Technol 35:1996–2000

    Article  CAS  Google Scholar 

  • Zereini F, Alt F, Messerschmidt J, von Bohlen A, Liebl K, Püttmann W (2004) Concentration and distribution of platinum group elements (Pt, Pd, Rh) in airborne particulate matter in Frankfurt am Main, Germany. Env Sci Technol 38:1686–1692

    Article  CAS  Google Scholar 

  • Zereini F, Alt F, Messerschmidt J, Wiseman C, Feldmann I, von Bohlen A, Müller J, Liebl K, Püttmann W (2005) Concentration and particle size distribution of road-specific heavy metals in urban airborne particulate matter. Env Sci Technol 39:2983–2989

    Article  CAS  Google Scholar 

  • Zhao Z, Freiser H (1986) Differential pulse polarographic determination of trace levels of platinum. Anal Chem 58:1498–1501

    Article  CAS  Google Scholar 

  • Zischka M, Wegscheider W (2000) Reliability of and measurement uncertainty for the determination of Au, Pd, Pt and Rh for ICP-MS in environmentally relevant samples. In: Zereini F, Alt F (eds) Anthropogenic platinum-group element emissions: their impact on man and environment. Springer, Berlin, pp 201–214

    Chapter  Google Scholar 

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Acknowledgments

The authors gratefully acknowledge the financial support from the Austrian Science Fund-FWF (Project Nr.: P20838-N17).

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Correspondence to C. Puls .

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Puls, C., Limbeck, A., Hann, S. (2010). Ultra-Trace Analysis of Palladium: State-of-the-Art and Future Challenges. In: Zereini, F., Wiseman, C. (eds) Urban Airborne Particulate Matter. Environmental Science and Engineering(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-12278-1_10

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