Abstract
The surface properties of metals and alloys become important when these materials are used especially for tribological applications. Some basic concepts involved during wear of metals and alloys are briefly discussed in this chapter. Delamination theory of adhesive wear which is dominating wear mechanism for most metals and alloys is discussed. Most of the tribological joints are exposed to environmental oxygen when used in atmospheric conditions. Oxidation becomes problematic for such and high-temperature sliding applications when oxygen source is readily available at the interface. The debris formation mechanism and oxidation during sliding are included in this chapter. Information on oxidation and tribological behavior of 60NiTi is reviewed as it is a potential alloy for tribo-element applications. A brief description on phase transformation and high-temperature tribology of metallic materials is also included. The wear of materials at the interface depends on the interfacial strength of the sliding materials. In high-temperature oxidative wear, wear performance can be determined by the type of oxides formed on the sliding surfaces.
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References
In The American Heritage® Dictionary of the English Language, Houghton Mifflin Company
In Merriam-Webster Medical Dictionary© 2002, Merriam-Webster, Inc
In WordNet® 2.0 © 2003, Princeton University
Binnig G et al (1982) Surface studies by scanning tunneling microscopy. Phys Rev Lett 49(1):57–61
Binnig G, Quate CF, Gerber C (1986) Atomic force microscope. Phys Rev Lett 56(9):930–933
Israelachvili JN (1989) Techniques for direct measurements of forces between surfaces in liquids at the atomic scale. Chemtracts Anal Phys Chem 1:1–12
Krim J, Widom A (1988) Damping of a crystal oscillator by an adsorbed monolayer and its relation to interfacial viscosity. Phys Rev B 38(17):12184–12189
Krim J, Solina DH, Chiarello R (1991) Nanotribology of a Kr monolayer: a quartz-crystal microbalance study of atomic-scale friction. Phys Rev Lett 66(2):181–184
Rabinowicz E (1995) Friction and lubrication of materials. Wiley, New York
Bowden FP, Tabor D (1964) The friction and lubrication of solids, vol I and II. Clarendon Press, Oxford
Suh NP (1973) The delamination theory of wear. Wear 25(1):111–124
Suh NP (1986) Tribophysics. Printice-Hall, Englewood Cliffs, NJ
Holm R (1946) Electric contacts. Almquist and Wiksells, Stockholm
Archard J (1953) Contact and rubbing of flat surfaces. J Appl Phys 24(8):981–988
Stott FH (1998) The role of oxidation in the wear of alloys. Tribol Int 31(1–3):61–71
Fehlner FP (1986) Low temperature oxidation, the role of vitreous oxides. OSTI ID: 5328041. Retrieved from http://www.osti.gov/scitech/servlets/purl/5328041
Jeurgens L et al (2000) Thermodynamic stability of amorphous oxide films on metals: application to aluminum oxide films on aluminum substrates. Phys Rev B 62(7):4707
Doherty P, Davis R (1963) Direct observation of the oxidation of Aluminum single crystal surfaces. J Appl Phys 34(3):619–628
Eldridge J et al (1988) Thermal oxidation of single-crystal aluminum at 550 °C. Oxidation Metals 30(5):301–328
Snijders P, Jeurgens L, Sloof W (2002) Structure of thin aluminium-oxide films determined from valence band spectra measured using XPS. Surf Sci 496(1):97–109
Francis E (1999) Standard oxidation potentials. ©1998 [cited 2012 Oct 30, 2012]; Accessed http://dl.clackamas.cc.or.us/ch105-09/standard.htm
Ingole SP (2005) Nanotribological characterization of dynamic surfaces. University of Alaska Fairbanks, Fairbanks, AK, USA
Ingole S (2013) 60NiTi alloy for tribological and biomedical surface engineering applications. JOM 65(6):792–798. doi:10.1007/s11837-013-0610-7
Industry updates (2011) J Fail Anal Prev 11(6):645–653. doi:10.1007/s11668-011-9515-3
Chan CM, Trigwell S, Duerig T (2004) Oxidation of an NiTi alloy. Surf Interface Anal 15(6):349–354
Firstov G et al (2002) Surface oxidation of NiTi shape memory alloy. Biomaterials 23(24):4863–4871
DellaCorte C et al (2009) Intermetallic Nickel–Titanium alloys for oil-lubricated bearing applications. NASA, Cleveland, OH
DellaCorte C, Glennon GN (2012) Ball bearings comprising nickel-titanium and methods of manufacture thereof, in Google Patents, The United States of America as represented by the National Aeronautics and Space Administration, Abbott Ball Company, USA
DellaCorte C et al (2011) Resilient and corrosion-proof rolling element bearings made from superelastic Ni-Ti alloys for aerospace mechanism applications. August 2011, NASA/TM—2011-217105, http://www.ntrs.nasa.gov/archive/nasa/casi.ntrs.nasa.gov/20110016524_2011017534.pdf
Pepper SV et al (2009) NITINOL 60 as a material for spacecraft triboelements. 2009. Proc. ‘13th European Space Mechanisms and Tribology Symposium – ESMATS 2009’, Vienna, Austria, 23–25 September 2009 (ESA SP-670, July 2009), http://www.esmats.eu/esmatspapers/pastpapers/pdfs/2009/pepper.pdf
Pepper SV, DellaCorte C, Glennon G (2010) Lubrication of Nitinol 60, June 2010, NASA/TM-2010: 215331-1-8, http://www.grc.nasa.gov/WWW/StructuresMaterials/TribMech/highlights/documents/additional/TM-2010-216331.pdf
Ingole S, Liang H, Mohanty P (2005) Tribology characteristics of thermal sprayed NiTi coatings. In presented at 4th ASM international surface engineering congress and 19th international conference on surface modification technologies. ASM International, Saint Paul
Stanford MK, Thomas F, DellaCorte C (2012) Processing issues for preliminary melts of the intermetallic compound 60-NITINOL. Nov 01, 2012, NASA/TM-2012-216044; E-18479; GRC-E-DAA-TN4035, Doc ID: 20130000580, http://ntrs.nasa.gov/archive/nasa/casi.ntrs.nasa.gov/20130000580_2012018813.pdf
Jaeger J (1942) Moving sources of heat and the temperature of sliding contacts. in. J Proc Roy Soc NSW 76:203–224
Cook N, Bhushan B (1973) Sliding surface interface temperatures(solid–solid interface temperature rise during sliding from model with surface topography statistics, frictional conditions, surface hardness and thermal parameters). ASME Trans Ser F J Lubr Technol 95:59–64
Rigney D et al (1986) Low energy dislocation structures caused by sliding and by particle impact. Mater Sci Eng 81:409–425
Don J, Sun TC, Rigney DA (1983) Friction and wear of Cu–Be and dispersion-hardened copper systems. Wear 91(2):191–199
Hume-Rothery W (1931) The metallic state. Oxford University Press, London
Davies H, Luborsky F (1983) Amorphous metallic alloys. Butterworths, London, pp 8–25
Giessen BC (1982) In: Proceedings of 4th international conference on rapidly quenched metals, Japan Institute of Metals, Sendai
Xia S et al (1999) Formation of disordered structures in Cr–Fe alloy by mechanical milling. J Phys Condens Matter 5(17):2729
Gaffet E et al (1988) Ball milling amorphization mechanism of Ni⋅Zr alloys. J Less Common Metals 145:251–260
Hellstern E, Schultz L (1988) Formation and properties of mechanically alloyed amorphous Fe⋅Zr. Mater Sci Eng 97:39–42
Koch C et al (1983) Preparation of “amorphous” Ni 6 0 Nb 4 0 by mechanical alloying. Appl Phys Lett 43(11):1017–1019
Thompson J, Politis C (1987) Formation of amorphous Ti–Pd alloys by mechanical alloying methods. EPL (Europhys Lett) 3(2):199
Dolgin B et al (1986) Mechanical alloying of Ni, CO, and Fe with Ti. Formation of an amorphous phase. J Non-Crystalline Solids 87(3):281–289
Politis C, Johnson W (1986) Preparation of amorphous Ti 1−x Cu x (0.10≪x ≤ 0.87) by mechanical alloying. J Appl Phys 60(3):1147–1151
Schwarz RB, Koch CC (1986) Formation of amorphous alloys by the mechanical alloying of crystalline powders of pure metals and powders of intermetallics. Appl Phys Lett 49(3):146–148
Atzmon M et al (1984) Formation and growth of amorphous phases by solid-state reaction in elemental composites prepared by cold working. Appl Phys Lett 45(10):1052–1053
Schwarz R, Johnson W (1983) Formation of an amorphous alloy by solid-state reaction of the pure polycrystalline metals. Phys Rev Lett 51(5):415–418
Johnson WL (1986) Thermodynamic and kinetic aspects of the crystal to glass transformation in metallic materials. Prog Mater Sci 30(2):81–134
Ahlström J, Karlsson B (2002) Modelling of heat conduction and phase transformations during sliding of railway wheels. Wear 253(1–2):291–300
Beilby SG (1921) Aggregation and flow of solids. Macmillon, London
Bowden F, Hughes T (1937) Physical properties of surfaces. IV. Polishing, surface flow and the formation of the Beilby layer. Proc Roy Soc Lon Ser A Math Phys Sci 160(903):575–587
Rigney D, Hammerberg J (1999) Mechanical mixing and the development of nanocrystalline material during the sliding of metals. Proc TMS Fall Meet 465–474
Ganapathi S et al (1990) A comparative study of the nanocrystalline material produced by sliding wear and inert gas condensation. In MRS proceedings. Cambridge University Press, Cambridge
Rigney D et al (2003) Examples of structural evolution during sliding and shear of ductile materials. Scripta Materialia 49(10):977–983
Kim HJ, Karthikeyan S, Rigney D (2009) A simulation study of the mixing, atomic flow and velocity profiles of crystalline materials during sliding. Wear 267(5–8):1130–1136
Fu XY, Rigney D, Falk M (2003) Sliding and deformation of metallic glass: experiments and MD simulations. J Non-Crystalline Solids 317(1):206–214
Heilmann P et al (1983) Sliding wear and transfer. Wear 91(2):171–190
Weast R, Selby S, Hodgman C (1965/1966) Handbook of chemistry and physics, 46th edn. The Chemical Rubber Co, Cleveland, OH
Xia SK, Saitovitch EB (1994) Formation of an amorphous phase in Cr(1−x)FeX films obtained by thermal evaporation. Phys Rev B 49(5):927
Birol Y (2010) High temperature sliding wear behaviour of Inconel 617 and Stellite 6 alloys. Wear 269(9–10):664–671
Blau PJ (2010) Elevated-temperature tribology of metallic materials. Tribol Int 43(7):1203–1208
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Ingole, S.P. (2013). Tribology of Metals and Alloys. In: Menezes, P., Nosonovsky, M., Ingole, S., Kailas, S., Lovell, M. (eds) Tribology for Scientists and Engineers. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-1945-7_6
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