Abstract
Alternative lithographic techniques, in particular those based on scanning probe microscopy, have shown a great potential for fabricating nanostructures using various material and allowing high spatial resolution, alignment capabilities and high-resolution imaging during the different lithographic steps. More specifically, atomic force microscope (AFM) and scanning tunneling microscope (STM) have been in the recent past employed to image and modify at nanometer scale a new carbon material discovered in 2004 and called graphene, a single layer of carbon atoms arranged in a honeycomb crystal lattice. In this chapter a review of recent results obtained by scanning probe based nanofabrication on graphene nanostructures is presented. It is focused in particular on nanomanipulation, local anodic oxidation (LAO), electrochemical or thermal-stimulated desorption, static or dynamic ploughing as well as other AFM and STM based techniques on imaging, lithography and spectroscopy.
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Abbreviations
- AFM:
-
Atomic force microscope
- dI/dU, dI/dV:
-
Differential conductance
- FLG:
-
Few layer graphene
- GNR:
-
Graphene nano ribbons
- GO:
-
Graphene oxide
- GOepi :
-
Graphene oxide epitaxial
- I-V:
-
Current-Voltage
- KPM:
-
Kelvin probe microscopy
- LAO:
-
Local anodic oxidation
- LDOS:
-
Local density of states
- NEMS:
-
Nano electro mechanical systems
- SEM:
-
Scanning electron microscope
- SGM:
-
Scanning gate microscopy
- SLG:
-
Single layer graphene
- SPL:
-
Scanning probe lithography
- SPM:
-
Scanning probe microscopy
- SPN:
-
Scanning probe nanomanipulation
- SPS:
-
Scanning probe spectroscopy
- STM:
-
Scanning tunneling microscope
- TCNL:
-
Thermo chemical nano lithography
- TERS:
-
Tip enhanced Raman scattering
- UHV:
-
Ultra high vacuum
References
A. K. Geim and K. S. Novoselov, Nat. Mater. 6, 183 (2007).
K. S. Novoselov, D. Jiang, F. Schedin, T. J. Booth, V. V. Khotkevich, S. V. Morozov, and A. K. Geim, PNAS 102, 10451 (2005).
K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, Science 306, 666 (2004).
S. Roddaro, P. Pingue, V. Piazza, V. Pellegrini, and F. Beltram, Nano Lett. 7, 2707 (2007).
T. W. Ebbesen and H. Hiura, Adv. Mater. 7, 582 (1995).
X. K. Lu, M. F. Yu, H. Huang, and R. S. Ruoff, Nanotechnology 10, 269 (1999).
Y. Zhang, J. P. Small, M. E. S. Amori, and P. Kim, Appl. Phys. Lett. 86, 073104 (2005).
G. Binnig, H. Fuchs, Ch. Gerber, H. Rohrer, E. Stoll, and E. Tosatti, Europhys. Lett. 1, 31 (1986).
S. Park and C. F. Quate, Appl. Phys. Lett. 48, 112 (1986).
G. Binnig, H. Rohrer, C. Gerber, and E. Weibel, Phys. Rev. Lett. 49, 57 (1982).
G. Binnig, C. F. Quate, and Ch. Gerber, Phys. Rev. Lett. 56(9), 930 (1986).
B. Bhushan, Scanning Probe Microscopy in Nanoscience and Nanotechnology. Springer, Heidelberg (2010).
M. Bowker and P. R. Davies, Scanning Tunneling Microscopy in Surface Science. Wiley, Weinheim (2010).
A. A. Tseng, A. Notargiacomo, and T. P. Chen, J. Vac. Sci. Technol. B 23, 877 (2005).
P. Nemes-Incze, Z. Osvath, K. Kamaras, and L. P. Biró, Carbon 46, 1435, (2008).
A. Fasolino, J. H. Los, and M. Katsnelson, Nat. Mater. 6, 858 (2007).
C. H. Lui, L. Liu, K. F. Mak, G. W. Flynn, and T. Heinz, Nature 462, 339 (2009).
D. Teweldebrhan and A. A. Balandin, Appl. Phys. Lett. 94, 013101 (2009).
M. A. Meitl, Z.-T. Zhu, V. Kumar, K. J. Lee, X. Feng, Y. Y. Huang, I. Adesida, R. G. Nuzzo, and J. A. Rogers, Nat. Mater. 5, 33 (2006).
K. S. Kim, Y. Zhao, H. Jang, S. Y. Lee, J. M. Kim, K. S. Kim, J.-H. Ahn, P. Kim, J.-Y. Choi, and B. H. Hong, Nature 457, 706 (2009).
G. F. Schneider, V. E. Calado, H. Zandbergen, L. M. K. Vandersypen, and C. Dekker, Nano Lett. 10, 1912 (2010).
Z. Li, Z. Cheng, R. Wang, Q. Li, and Y. Fang, Nano Lett. 9(10), 3599 (2009).
T. Hertel, R. Martel, and P. Avouris, J. Phys. Chem. B 102, 910 (1998).
A. Wienssa and G. Persch-Schuy, Appl. Phys. Lett. 75, 1077 (1999).
T. Banno, M. Tachiki, H. Seo, H. Umezawa, and H. Kawarada, Diam. Relat. Mater. 11, 387 (2002).
I. W. Frank, D. M. Tanenbaum, A. M. van der Zande, and P. L. McEuen, J. Vac. Sci. Technol. B 25(6), 2558 (2007).
M. Poot and H. S. J. van der Zant, Appl. Phys. Lett. 92, 063111 (2008).
C. Lee, X. Wei, J. W. Kysar, and J. Hone, Science 321, 385 (2008).
J. S. Bunch, A. M. van der Zande, S. S. Verbridge, I. W. Frank, D. M. Tanenbaum, J. M. Parpia, H. G. Craighead, and P. L. McEuen, Science 315, 490 (2007).
S. Shivaraman, R. A. Barton, X. Yu, J. Alden, L. Herman, M. V. S. Chandrashekhar, J. Park, P. L. McEuen, J. M. Parpia, H. G. Craighead, and M. G. Spencer, Nano Lett. 9, 3100 (2009).
V. Singh, S. Sengupta, H. S. Solanki, R. Dhall, A. Allain, S. Dhara, P. Pant, and M. M. Deshmukh, Nanotechnology 21, 165204 (2010).
F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, Nat. Mater. 6, 652 (2007).
J. S. Bunch, S. S. Verbridge, J. S. Alden, A. M. van der Zande, J. M. Parpia, H. G. Craighead, and P. L. McEuen, Nano Lett. 8(8), 2458 (2008).
S. Stankovich, D. A. Dikin, R. D. Piner, K. A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S. T. Nguyen, and R. S. Ruoff, Carbon 45, 1558 (2007).
G. Eda, G. Fanchini, and M. Chhowalla, Nat. Nanotechnol. 3, 270 (2008).
S. S. Hong, W. Kundhikanjana, J. J. Cha, K. Lai, D. Kong, S. Meister, M. A. Kelly, Z.-X. Shen, and Y. Cui, Nano Lett. 10(8), 3118 (2010).
A. J. M. Giesbers, U. Zeitler, S. Neubeck, F. Freitag, K. S. Novoselov, and J. C. Maan, Solid State Commun. 147, 366 (2008).
S. Eilers and J. P. Rabe, Phys. Status Solidi B 246(11–12), 2527 (2009).
G. Prakash, M. L. Bolen, R. Colby, E. A. Stach, M. A. Capano, and R. Reifenberger, New J. Phys. 12, 125009 (2010).
G. Lu, X. Zhou, H. Li, Z. Yin, B. Li, L. Huang, F. Boey, and H. Zhang, Langmuir 26(9), 6164 (2010).
J. Dagata, J. Schneir, H. H. Harary, C. J. Evans, M. T. Postek, and J. Bennett, Appl. Phys. Lett. 56, 2001 (1990).
H. C. Day and D. R. Allee, Appl. Phys. Lett. 62, 2691 (1993).
R. Garcia, R. V. Martinez, and J. Martinez, Chem. Soc. Rev. 35, 29 (2006).
A. A. Tseng, A. Notargiacomo, and T. P. Chen, J. Vac. Sci. Technol. B 23, 877 (2005).
L. Weng, L. Zhang, Y. P. Chen, and L. P. Rokhinson, Appl. Phys. Lett. 93, 093107 (2008).
S. Masubuchi, M. Ono, K. Yoshida, K. Hirakawa, and T. Machida, Appl. Phys. Lett. 94, 082107 (2009).
K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, M. I. Katsnelson, I. V. Grigorieva, S. V. Dubonos, and A. A. Firsov, Nature 438, 197 (2005).
Y. Zhang, J. W. Tan, H. L. Stormer, and P. Kim, Nature 438, 201 (2005).
G. Rius, N. Camara, P. Godignon, and F. Pérez-Murano, J. Vac. Sci. Technol. B 27(6), 3149 (2009).
J. H. Ye, F. Pérez-Murano, N. Barniol, G. Abadal, and X. Aymerich, J. Vac. Sci. Technol. B 13, 1423 (1995).
G. Abadal, F. Pérez-Murano, N. Barniol, and X. Aymerich, Appl. Phys. A: Mater. Sci. Process. 66, S791 (1998).
V. Tozzini and V. Pellegrini, Phys. Rev. B 81, 113404 (2010).
M. H. F. Sluiter and Y. Kawazoe, Phys. Rev. B 68, 085410 (2003).
J. O. Sofo, A. S. Chaudhari, and G. D. Barber, Phys. Rev. B 75, 153401 (2007).
D. C. Elias, R. R. Nair, T. M. G. Mohiuddin, S. V. Morozov, P. Blake, M. P. Halsall, A. C. Ferrari, D. W. Boukhvalov, M. I. Katsnelson, A. K. Geim, and K. S. Novoselov, Science 323, 610 (2009).
Z. Wei, D. Wang, S. Kim, S. Y. Kim, Y. Hu, M. K. Yakes, A. R. Laracuente, Z. Dai, S. R. Marder, C. Berger, W. P. King, W. A. de Heer, P. E. Sheehan, and E. Riedo, Science 328, 1373 (2010).
J. M. Mativetsky, E.Treossi, E. Orgiu, M. Melucci, G. P. Veronese, P. Samorì, and V. Palermo, J. Am. Chem. Soc. 132, 14130 (2010).
M. Zhou, Y. L. Wang, Y. M. Zhai, J. F. Zhai, W. Ren, F. A. Wang, S. J. Dong, Chem. Eur. J. 15, 6116 (2009).
P. Vettiger, M. Despont, U. Drechsler, U. Durig, W. Haberle, M. I. Lutwyche, H. E. Rothuizen, R. Stutz, R. Widmer, and G. K. Binnig, IBM J. Res. Develop. 44(3), 323 (2000).
E. Stolyarova, K. T. Rim, S. Ryu, J. Maultzsch, P. Kim, L. E. Brus, T. F. Heinz, M. S. Hybertsen, and G. W. Flynn, PNAS 104(22), 9209 (2007).
M. Ishigami, J. H. Chen, W. G. Cullen, M. S. Fuhrer, and E. D. Williams, Nano Lett. 7(6), 1644 (2007).
G. Li, A. Luican, and E. Y. Andrei, Phys. Rev. Lett. 102, 176804 (2009).
H. A. Mizes, S. Park, and W. A. Harrison, Phys. Rev. B 36, 4491 (1987).
G. M. Rutter, J. N. Crain, N. P. Guisinger, T. Li, P. N. First, and J. A. Stroscio, Science 317, 219 (2007).
F. Varchon, P. Mallet, L. Magaud, and J.-Y. Veuillen, Phys. Rev. B 77, 165415 (2008).
J. Wintterlin and M.-L. Bocquet, Surf. Sci. 603, 1841 (2009).
Y. Pan, H. Zhang, D. Shi, J. Sun, S. Du, F. Liu, and H. Gao, Adv. Mater. 21(27), 2777 (2009).
J. Coraux, A. T. N’Diaye, C. Busse, and T. Michely, Nano Lett. 8(2), 565 (2008).
A. L. Vázquez de Parga, F. Calleja, B. Borca, M. C. G. Passeggi, Jr., J. J. Hinarejos, F. Guinea, and R. Miranda, Phys. Rev. Lett. 100, 056807 (2008).
N. Levy, S. A. Burke, K. L. Meaker, M. Panlasigui, A. Zett, F. Guinea, A. H. Castro Neto, and M. F. Crommie, Science 329, 544 (2010).
M. L. Teague, A. P. Lai, J. Velasco, C. R. Hughes, A. D. Beyer, M. W. Bockrath, C. N. Lau, and N. C. Yeh, Nano Lett. 9(7), 2543 (2009).
L. Tapasztó, G. Dobrik, P. Lambin, and L. P. Biró, Nature Nanotech. 3, 397 (2008).
D. H. Kim, J. Y. Koo, and J. J. Kim, Phys. Rev. B 68, 113406 (2003).
P. Sessi, J. R. Guest, M. Bode, and N. P. Guisinger, Nano Lett. 9(12), 4343 (2009).
C. Casiraghi, A. Hartschuh, E. Lidorikis, H. Qian, H. Harutyunyan, T. Gokus, K. S. Novoselov, and A. C. Ferrari, Nano Lett. 7(9), 2711 (2007).
A. C. Ferrari, J. C. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K. S. Novoselov, S. Roth, and A. K. Geim, Phys. Rev. Lett. 97, 187401 (2006).
D. Graf, F. Molitor, K. Ensslin, C. Stampfer, A. Jungen, C. Hierold, and L. Wirtz, Nano Lett. 7(2), 238 (2007).
R. M. Stöckle, Y. D. Suh, V. Deckert, and R. Zenobi, Chem. Phys. Lett. 318, 131 (2000).
Y. Saito, P. Verma, K. Masui, Y. Inouye, and S. Kawata, J. Raman Spectrosc. 40, 1434 (2009).
Y.-J. Yu, Y. Zhao, S. Ryu, L. E. Brus, K. S. Kim, and P. Kim, Nano Lett. 9(10), 3431 (2009).
A. Verdaguer, M. Cardellach, J. J. Segura, G. M. Sacha, J. Moser, M. Zdrojek, A. Bachtold, and J. Fraxedas, Appl. Phys. Lett. 94, 233105 (2009).
J. Martin, N. Akerman, G. Ulbricht, T. Lohmann, J. H. Smet, K. Von Klitzing, and A. Yacoby, Nat. Phys. 4, 144 (2008).
M. R. Connolly, K. L. Chiou, C. G. Smith, D. Anderson, G. A. C. Jones, A. Lombardo, A. Fasoli, and A. C. Ferrari, Appl. Phys. Lett. 96, 113501 (2010).
K. Xu, P. Cao, and J. R. Heath, Science 329, 1188 (2010).
J. Cai, P. Ruffieux, R. Jaafar, M. Bieri, T. Braun, S. Blankenburg, M. Muoth, A. P. Seitsonen, M. Saleh, X. Feng, K. Muellen, and R. Fasel, Nature 466, 472 (2010).
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Pingue, P. (2011). Scanning Probe Based Nanolithography and Nanomanipulation on Graphene. In: Tseng, A. (eds) Tip-Based Nanofabrication. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-9899-6_10
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