Abstract
Nanofluids are a new class of fluids engineered by dispersing nanometer-size structures (particles, fibers, tubes, droplets) in base fluids. The very essence of nanofluids research and development is to enhance fluid macroscale and megascale properties such as thermal conductivity through manipulating microscale physics (structures, properties and activities). Therefore, the success of nanofluid technology depends very much on how well we can address issues like effective means of microscale manipulation, interplays among physics at different scales, and optimization of microscale physics for the optimal megascale properties. In this chapter we review methodologies available to effectively tackle these central but difficult problems and identify the future research needs as well. The reviewed techniques include nanofluids synthesis through liquid-phase chemical reactions in continuous-flow microfluidic microreactors, scaling-up by the volume averaging, and constructal design with the constructal theory. The identified areas of future research contain microfluidic nanofluids, thermal waves, and constructal nanofluids. While our focus is on heat-conduction nanofluids, the methodologies are equally valid for the other types of nanofluids. The review could serve as a coherent, inspiring and realistic plan for future research and development of nanofluid technology.
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References
Choi, S.U.S., Zhang, Z.G., Keblinski, P.: Nanofluids. In: Nalwa, H.S. (ed.) Encyclopedia of Nanoscience and Nanotechnology, vol. 6, pp. 757–773. American Scientific Publishers (2004)
Peterson, G.P., Li, C.H.: Heat and mass transfer in fluids with nanoparticle suspensions. Adv. Heat Transfer 39, 257–376 (2006)
Das, S.K., Choi, S.U.S., Yu, W.H., Pradeep, T.: Nanofluids: Science and Technology. John Wiley & Sons, Chichester (2008)
Wen, D.S., Ding, Y.L., Williams, R.: Nanofluids turn up the heat. TCE 771, 32–34 (2005)
Pileni, M.P.: Magnetic fluids: fabrication, magnetic properties, and organization of nanocrystals. Adv. Funct. Mater. 11, 323–336 (2001)
Wasan, D.T., Nikolov, A.D.: Spreading of nanofluids on solids. Nature 423, 156–159 (2003)
Gorman, J.: Nanofluid flow: detergents may benefit from new insight. Sci. News 163, 292–293 (2003)
Chen, H.S., Ding, Y.L., He, Y.R., Tan, C.Q.: Rheological behaviour of ethylene glycol based titania nanofluids. Chemical Physics Letters 444, 333–337 (2007)
Zhang, L.L., Jiang, Y.H., Ding, Y.L., Povey, M., York, D.: Investigation into the antibacterial behaviour of suspensions of ZnO nanoparticles (ZnO nanofluids). Journal of Nanoparticle Research 9, 479–489 (2007)
Pomogailo, A.D., Kestelman, V.N.: Metallopolymer Nanocomposites. Springer, Heidelberg (2005)
Dice, G.D., Mujumdar, S., Elezzabi, A.Y.: Plasmonically enhanced diffusive and subdiffusive metal nanoparticle-dye random laser. Appl. Phys. Lett. 86, 131105 (2005)
Duan, X., Huang, Y., Cui, Y., Wang, J., Lieber, C.M.: Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices. Nature 409, 241–245 (2001)
Duan, X., Huang, Y., Agarwal, R., Lieber, C.M.: Single-nanowire electrically driven lasers. Nature 421, 66–69 (2003)
Singh, A.K.: Thermal conductivity of nanofluids. Defence Science Journal 58, 600–607 (2008)
Li, C.H., Williams, W., Buongiorno, J., Hu, L.W., Peterson, G.P.: Transient and Steady-State Experimental Comparison Study of Effective Thermal Conductivity of Al2O3/Water Nanofluids. J. Heat Transfer 130, 040301/1–044503/4 (2008)
Wang, L.Q., Wei, X.H.: Nanofluids: Synthesis, Heat Conduction, and Extension. J. Heat Transfer 131, 033102/1–033102/7 (2009)
Jang, S.P., Choi, S.U.S.: Effects of Various Parameters on Nanofluid Thermal Conductivity. J. Heat Transfer 129, 617–623 (2007)
Vadasz, P.: Heat Conduction in Nanofluid Suspensions. J. Heat Transfer 128, 465–477 (2006)
Lee, S., Choi, S.U.S., Li, S., Eastman, J.A.: Measuring Thermal Conductivity of Fluids Containing Oxide Nanoparticles. J. Heat Transfer 121, 280–289 (1999)
Wei, X.H., Zhu, H.T., Wang, L.Q.: CePO4 Nanofluids: Synthesis and Thermal Conductivity. J. Thermophysics Heat Transfer 23, 219–222 (2009)
Das, S.K., Putra, N., Thiesen, P., Roetzel, W.: Temperature Dependence of Thermal Conductivity Enhancement for Nanofluids. J. Heat Transfer 125, 567–574 (2003)
He, Y.R., Men, Y.B., Liu, X., Lu, H.L., Chen, H.S., Ding, Y.L.: Study on forced convective heat transfer of non-Newtonian nanofluids. J. Thermal Sci. 18, 20–26 (2009)
Tzou, D.Y.: Thermal Instability of Nanofluids in Natural Convection. Int. J. Heat Mass Transfer 51, 2967–2979 (2008)
Buongiorno, J.: Convection Transport in Nanofluids. J. Heat Transfer 128, 240–250 (2006)
Xuan, Y.M., Li, Q.: Investigation on Convective Heat Transfer and Flow Features of Nanofluids. J. Heat Transfer 125, 151–155 (2003)
Milanova, D., Kumar, R.: Heat Transfer Behavior of Silica Nanoparticles Experiment in Pool Boiling. J. Heat Transfer 130, 042401/–042401/6 (2009)
Kim, S.J., McKrell, T., Buongiorno, J., Hu, L.W.: Alumina Nanoparticles Enhance the Flow Boiling Critical Heat Flux of Water at Low Pressure. J. Heat Transfer 130, 044501/1–044501/3 (2008)
Kim, S.J., McKrell, T., Buongiorno, J., Hu, L.W.: Experimental Study of Flow Critical Heat Flux in Alumina-Water, Zinc-Oxide-Water, and Diamond-Water Nanofluids. J. Heat Transfer 131, 043204/1–043204/7 (2009)
Kedzierski, M.A.: Effect of CuO Nanoparticle Concentration on R134a/Lubricant Pool-Boiling Heat Transfer. J. Heat Transfer 131, 043205/1–043205/7 (2009)
Wu, D.X., Zhu, H.T., Wang, L.Q., Liu, L.M.: Critical Issues in Nanofluids Preparation, Characterization and Thermal Conductivity. Current Nanoscience 5, 103–112 (2009)
Choi, S.U.S.: Nanofluids: From Vision to Reality Through Research. J. Heat Transfer 131, 033106/1–033106/9 (2009)
Eastman, J.A., Phillpot, S.R., Choi, S.U.S., Keblinski, P.: Thermal transport in nanofluids. Annu. Rev. Mater. Res. 34, 219–246 (2004)
Phelan, P.E., Bhattacharya, P., Prasher, R.S.: Nanofluids for heat transfer applications. Annu. Rev. Heat Transfer 14, 255–275 (2005)
Sobhan, C.B., Peterson, G.P.: Microscale and Nanoscale Heat Transfer: Fundamentals and Engineering Applications. CRC Press, Boca Raton (2008)
Wang, L.Q., Xu, M.T., Wei, X.H.: Multiscale theorems. Adv. Chemical Engineering 34, 175–468 (2008)
Wang, L.Q.: Flows through porous media: a theoretical development at macroscale. Transport in Porous Media 39, 1–24 (2000)
Choi, S.U.S., Eastman, J.A.: Enhanced heat transfer using nanofluids. United States Patent, US 6221275 B1 (2001)
Eastman, J.A., Choi, S.U.S., Li, S., Yu, W., Thompson, L.J.: Anomalously increased effective thermal conductivities of ethylene glycol-based nanofluids containing copper nanoparticles. Appl. Phys. Lett. 78, 718–720 (2001)
Chang, H., Tsung, T.T., Chen, L.C., Yang, Y.C., Lin, H.M., Lin, C.K., Jwo, C.S.: Nanoparticle suspension preparation using the arc spray nanoparticle synthesis system combined with ultrasonic vibration and rotating electrode. Int. J. Adv. Manufacturing Tech. 26, 552–558 (2005)
Lo, C.H., Tsung, T.T., Chen, L.C., Su, C.H., Lin, H.M.: Fabrication of copper oxide nanofluid using submerged arc nanoparticle synthesis system (SANSS). J. Nanoparticle Research 7, 313–320 (2005)
Lo, C.H., Tsung, T.T., Chen, L.C.: Shaped-controlled synthesis of Cu-based nanofluid using submerged arc nanoparticle synthesis system (SANSS). J. Crystal Growth 277, 636–642 (2005)
Romano, J.M., Parker, J.C., Ford, Q.B.: Application opportunities for nanoparticles made from condensation of physical vapors. Adv. Powder Metallurgy Particulate Materials 2, 12–13 (1997)
Zhu, H.T., Lin, Y.S., Yin, Y.S.: A novel one-step chemical method for preparation of copper nanofluids. J. Colloid Interface Sci. 277, 100–103 (2004)
Zhu, H.T., Zhang, C.Y., Liu, S.Q., Tang, Y.M., Yin, Y.S.: Effects of nanoparticle clustering and alignment on thermal conductivities of Fe3O4 aqueous nanofluids. Appl. Phys. Lett. 89, 023123 (2006)
Zhu, H.T., Zhang, C.Y., Tang, Y.M.: Novel synthesis and thermal conductivity of CuO nanofluids. J. Phys. Chem. C 111, 1646–1650 (2007)
Wei, X.H., Kong, T.T., Zhu, H.T., Wang, L.Q.: CuS/Cu2S nanofluids: synthesis and thermal conductivity. Int. J. Heat Mass Transfer (in press, 2009)
Wei, X.H., Zhu, H.T., Kong, T.T., Wang, L.Q.: Synthesis and Thermal Conductivity of Cu2O Nanofluids. Int. J. Heat Mass Transfer 52, 4371–4374 (2009)
Wang, L.Q., Liu, F.: Forced convection in slightly curved microchannels. Int. J. Heat Mass Transfer 50, 881–896 (2007)
Wang, L.Q., Yang, T.L.: Multiplicity and stability of convection in curved ducts: review and progress. Adv. Heat Transfer 38, 203–255 (2004)
Wang, L.Q., Cheng, K.C.: Flow transitions and combined free and forced convective heat transfer in rotating curved channels: the case of positive rotation. Phys. Fluids 8, 1553–1573 (1996)
Sudarsan, A.P., Ugaz, V.M.: Fluid mixing in planar spiral microchannels. Lab on a Chip 6, 74–82 (2006)
Hong, C.C., Choi, J.W., Ahn, C.H.: A novel in-plane passive microfluidic mixer with modified Tesla structures. Lab on a Chip 4, 109–113 (2004)
Sudarsan, A.P., Ugaz, V.M.: Multivortex micromixing. Proceedings of the National Academy of Sciences of the United States of America 103, 7228–7233 (2006)
Alleborn, N., Nandakumar, K., Raszillier, H., Durst, F.: Further contributions on the two-dimensional flow in a sudden expansion. J. Fluid Mech. 330, 169–188 (1997)
Nguyen, N.T.: Micromixers: Fundamentals, Design and Fabrication. William-Andrew (2008)
Tice, J.D., Song, H., Lyon, A.D., Ismagilov, R.F.: Formation of droplets and mixing in multiphase microfluidics at low values of the reynolds and the capillary numbers. Langmuir 19, 9127–9133 (2003)
Günther, A., Jhunjhunwala, M., Thalmann, M., Schmidt, M.A., Jensen, K.F.: Micromixing of miscible liquids in segmented gas−liquid flow. Langmuir 21, 1547–1555 (2005)
Hosokawa, K., Fujii, T., Endo, I.: Handling of picoliter liquid samples in a poly (dimethylsiloxane)-based microfluidic device. Anal. Chem. 71, 4781–4785 (1999)
Handique, K., Burns, M.A.: Mathematical modeling of drop mixing in a slit-type microchannel. J. Micromech. Microeng. 11, 548–554 (2001)
Kashid, M.N., Gerlach, I., Goetz, S., Franzke, J., Acker, J.F., Platte, F., Agar, D.W., Turek, S.: Internal circulation within the liquid slugs of a liquid-liquid slug-flow capillary microreactor. Ind. Eng. Chem. Res. 44, 5003–5010 (2005)
Grigoriev, R.O.: Chaotic mixing in thermocapillary-driven microdroplets. Phys. Fluids 17, 033601 (2005)
Muradoglu, M., Stone, H.A.: Mixing in a drop moving through a serpentine channel: A computational study. Phys. Fluids 17, 073305 (2005)
Garstecki, P., Fischbach, M.A., Whitesides, G.M.: Design for mixing using bubbles in branched microfluidic channels. Appl. Phys. Lett. 86, 244108 (2005)
Salman, W., Angeli, P., Gavriilidis, A.: Sample pulse broadening in Taylor flow microchannels for screening applications. Chem. Eng. Technol. 28, 509–514 (2005)
Garstecki, P., Fuerstman, M.J., Fischbach, M.A., Sia, S.K., Whitesides, G.M.: Mixing with bubbles: a practical technology for use with portable microfluidic devices. Lab Chip 6, 207–212 (2006)
Fan, J., Zhang, Y.X., Wang, L.Q.: Bubble formation in microfluidic T-junctions (submitted, 2009)
Tan, Y.C., Lee, A.: Micro/naodroplets in microfluidic devices. In: Bhushan, B. (ed.) Springer Handbook of Nanotechnology, pp. 571–587. Springer, Heidelberg (2007)
Wang, L.Q., Zhang, Y.X., Cheng, L.: Magic microfluidic T-junctions: valving and bubbling. Chaos, Solitons & Fractals 39, 1530–1537 (2009)
Shah, R.K., Shum, H.C., Rowat, A.C., Lee, D.Y., Agresti, J.J., Utada, A.S., Chu, L.Y., Kim, J.W., Fernandez-Nieves, A., Martinez, C.J., Weitz, D.A.: Designer emulsions using microfluidics. Materials Today 11, 18–27 (2008)
Wei, X.H., Wang, L.Q.: Microfluidic Cu2O nanofluids (submitted, 2009)
Xuan, Y.M., Li, Q., Zhang, X., Hu, W.: Aggregation structure and thermal conductivity of nanofluids. AICHE Journal 49, 1038–1043 (2003)
Koo, J., Kleinstreuer, C.: A new thermal conductivity model for nanofluids. J. Nanoparticle Research 6, 577–588 (2004)
Jang, S.P., Choi, S.U.S.: Role of Brownian motion in the enhanced thermal conductivity of nanofluids. Appl. Phys. Lett. 84, 4316–4318 (2004)
Bhattacharya, P., Saha, S.K., Yadav, A., Phelan, P.E., Prasher, R.S.: Brownian dynamics simulation to determine the effect thermal conductivity of nanofluids. J. Appl. Phys. 95, 6492–6494 (2004)
Prasher, R., Bhattacharya, P., Phelan, P.E.: Thermal conductivity of nanoscale colloidal solutions (nanofluids). Phys. Rev. Lett. 94, 025901 (2005)
Prasher, R., Bhattacharya, P., Phelan, P.E.: Brownian-motion-based convective-conductive model for the effective thermal conductivity of nanofluids. J. Heat Transfer 128, 588–595 (2006)
Yu, W., Choi, S.U.S.: The role of interfacial layers in the enhanced thermal conductivity of nanofluids: a renovated Maxwell model. J. Nanoparticle Research 5, 167–171 (2003)
Yu, W., Choi, S.U.S.: The role of interfacial layers in the enhanced thermal conductivity of nanofluids: a renovated Hamilton-Crosser model. J. Nanoparticle Research 6, 355–361 (2004)
Xue, L., Keblinski, P., Phillpot, S.R., Choi, S.U.S., Eastman, J.A.: Effect of liquid layering at the liquid-solid interface on thermal transport. Int. J. Heat Mass Transfer 47, 4277–4284 (2004)
Xie, H., Fujii, M., Zhang, X.: Effect of interfacial nanolayer on the effective thermal conductivity of nanoparticle-fluid mixture. Int. J. Heat Mass Transfer 48, 2926–2932 (2005)
Ren, Y., Xie, H., Cai, A.: Effective thermal conductivity of nanofluids containing spherical nanoparticles. J. Phys. D 38, 3958–3961 (2005)
Leong, K.C., Yang, C., Murshed, S.M.S.: A model for the thermal conductivity of nanofluids: the effect of interfacial layer. J. Nanopart. Res. 8, 245–254 (2006)
Wang, B.X., Zhou, L.P., Peng, X.F.: A fractal model for predicting the effective thermal conductivity of liquid with suspension of nanoparticles. Int. J. Heat Mass Transfer 46, 2665–2672 (2003)
Prasher, R., Phelan, P.E., Bhattacharya, P.: Effect of aggregation kinetics on the thermal conductivity of nanoscale colloidal solutions (nanofluid). Nano Letters 6, 1529–1534 (2006)
Rusconi, R., Rodari, E., Piazza, R.: Optical measurements of the thermal properties of nanofluids. Appl. Phys. Lett. 89, 261916 (2006)
Putnam, S.A., Cahill, D.G., Braun, P.V., Ge, Z.B., Shimmin, R.G.: Thermal conductivity of nanoparticle suspensions. J. Appl. Phys. 99, 084308
Eapen, J., Williams, W.C., Buongiorno, J., Hu, L.W., Yip, S.: Mean-field versus microconvection effects in nanofluid thermal conduction. Phys. Rev. Lett. 99, 095901 (2007)
Das, S.K., Choi, S.U.S., Patel, H.E.: Heat transfer in nanofluids: a review. Heat Transfer Engng. 27, 3–19 (2006)
Keblinski, P., Prasher, R., Eapen, J.: Thermal conductance of nanofluids: is the controversy over? J. Nanopart. Res. 10, 1089–1097 (2008)
Murshed, S.M.S.: Correction and comment on thermal conductance of nanofluids: is the controversy over? J. Nanopart. Res. 11, 511–512 (2009)
Wang, L.Q., Zhou, X.S., Wei, X.H.: Heat Conduction: Mathematical Models and Analytical Solutions. Springer, Heidelberg (2008)
Whitaker, S.: The Method of Volume Averaging. Kluwer Academic, Dordrecht (1999)
Wang, L.Q.: Generalized Fourier law. Int. J. Heat Mass Transfer 37, 2627–2634 (1994)
Auriault, J.L.: Heterogeneous medium: is an equivalent macroscopic description possible? Int. J. Engng. Sci. 29, 785–795 (1991)
Quintard, M., Whitaker, S.: One- and two-equation models for transient diffusion processes in two-phase systems. Adv. in Heat Transfer 23, 369–464 (1993)
Ochoa-Tapia, J.A., Whitaker, S.: Heat transfer at the boundary between a porous medium and a homogeneous fluid. Int. J. Heat Mass Transfer 40, 2691–27076 (1997)
Ochoa-Tapia, J.A., Whitaker, S.: Heat transfer at the boundary between a porous medium and a homogeneous fluid: The one-equation model. J. Porous Media 1, 31–46 (1998)
Howes, F.A., Whitaker, S.: The spatial averaging theorem revisited. Chem. Eng. Sci. 40, 1387–1392 (1985)
Gray, W.G., Leijnse, A., Kolar, R.L., Blain, C.A.: Mathematical Tolls for Changing Spatial Scales in the Analysis of Physical Systems. CRC Press, Boca Raton (1993)
Carbonell, R.G., Whitaker, S.: Heat and mass transfer in porous media. In: Bear, J., Corapcioglu, M.Y. (eds.) Fundamentals of Transport Phenomena in Porous Media, pp. 123–198. Martinus Nijhoff (1984)
Quintard, M., Kaviany, M., Whitaker, S.: Two-medium treatment of heat transfer in porous media: numerical results for effective parameters. Adv. Water Resour. 20, 77–94 (1997)
Quintard, M., Whitaker, S.: Theoretical Analysis of Transport in Porous Media. In: Vafai, K. (ed.) Handbook of Heat Transfer in Porous Media, pp. 1–52. Marcel Dekker, New York (2000)
Quintard, M., Whitaker, S.: Local thermal equilibrium for transient heat conduction: Theory and comparison with numerical experiments. Int. J. Heat Mass Transfer 38, 2779–2796 (1995)
Tzou, D.Y.: Macro-to Microscale Heat Transfer: The Lagging Behavior. Taylor & Francis, Abington (1997)
Wang, L.Q., Wei, X.H.: Equivalence between dual-phase-lagging and two-phase-system heat conduction processes. Int. J. Heat Mass Transfer 51, 1751–1756 (2008)
Wang, L.Q., Zhou, X.S.: Dual-phase-lagging Heat-Conduction Equations. Shandong University Press (2000)
Wang, L.Q., Zhou, X.S.: Dual-phase-lagging Heat-Conduction Equations: Problems and Solutions. Shandong University Press (2001)
Wang, L.Q., Xu, M.T., Zhou, X.S.: Well-posedness and solution structure of dual-phase-lagging heat conduction. Int. J. Heat Mass Transfer 44, 1659–1669 (2001)
Xu, M.T., Wang, L.Q.: Thermal oscillation and resonance in dual-phase-lagging heat conduction. Int. J. Heat Mass Transfer 45, 1055–1061 (2002)
Wang, L.Q., Xu, M.T., Wei, X.H.: Dual-phase-lagging and porous-medium heat conduction processes. In: Vadasz, P. (ed.) Emerging Topics in Heat and Mass Transfer in Porous Media - from Bioengineering and Microelectronics to Nanotechnology, pp. 1–37. Springer, Heidelberg (2008)
Fan, J., Wang, L.Q.: Microstructural effects on macroscale thermal properties in nanofluids (submitted, 2009)
Bejan, A., Lorente, S.: Design with Constructal Theory. Wiley, Chichester (2008)
Reis, A.H.: Constructal theory: from engineering to physics, and how flow systems develop shape and structure. App. Mech. Rev. 59, 269–282 (2006)
Bejan, A., Lorente, S.: Constructal theory of configuration generation in nature and engineering. J. App. Phys. 100, 041301/1–041301/27 (2006)
Bai, C., Wang, L.Q.: Constructal design of particle volume fraction in nanofluids. J. Heat Transfer 131, 112402/1–112402/7 (2009)
Wang, L.Q.: An approach for thermodynamic reasoning. Int. J. Modern Phys. B 10, 2531–2551 (1996)
Rocha, L.A., Lorente, S., Bejan, A.: Constructal design for cooling a disc-shaped area by conduction. Int. J. Heat Mass Transfer 45, 1643–1652 (2002)
Bejan, A.: Constructal-theory network of conducting paths for cooling a heat generating volume. Int. J. Heat Mass Transfer 40, 799–816 (1997)
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Wang, L., Quintard, M. (2009). Nanofluids of the Future. In: Wang, L. (eds) Advances in Transport Phenomena. Advances in Transport Phenomena, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-02690-4_4
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