Abstract
Mono, co- and tri-doped TiO2 thin films with the transition metals (vanadium and/or chrominium) and a nonmetal (nitrogen) have been fabricated by sol-gel method. X-ray diffraction results clearly reveal anatase crystal structure for all obtained samples and doping with any dopants doesn’t change the anatase phase of TiO2. Compared to TiO2, three types of doped TiO2 thin films exhibit a red-shift in the absorption edge and have much better photocatalytic properties for methylene blue degradation in visible light region. The maximum visible-photocatalytic performance was achieved for tri-doped TiO2 sample. The mechanism for enhancing visible-photocatalytic activity of co-doped and tri-doped TiO2 thin films was also examined.
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M. A. Shannon, P. W. Bohn, M. Elimelech, J. G. Georgiadis, B. J. Mariñas and A.M. Mayes, Nature 452, 301 (2008).
S. Malato, P. Fernández-Ibáñez, M.I. Maldonado, J. Blanco, and W. Gernjak, Catalysis Today 147, 1 (2009).
M. N. Chong, B. Jin, C. W. K. Chow, C. Saint, Water research 44, 2997 (2010).
W. Choi, A. Termin and M. R. Hoffmann, J. Phys. Chem. 98, 13669 (1994).
Y-H. Peng, G-F Huang and W-Q. Huang, Advanced Powder Technology 23, 8 (2012).
A. Hajjaji, A. Atyaoui, K. Trabelsi, M. Amlouk, L. Bousselmi, B. Bessais, M. A. E. Khakani and M. Gaidi, American Journal of Analytical Chemistry 5, 473 (2014).
J. C-S. Wu, C-H. Chen, Journal of Photochemistry and Photobiology A: Chemistry 163, 509 (2004).
J. M. Herrmann, J. Disdier and P. Pichat, Chem. Phys. Lett. 108, 618 (1984).
D. Lu, M. Zhang, Z. Zhang, Q. Li, X. Wang and J. Yang, Nanoscale Research Letters 9, 272 (2014).
M. E. Kurtoglu, T. Longenbach, K. Sohlberg and Y. Gogotsi, J. Phys. Chem. C 115, 17392 (2011).
R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki and Y. Taga, Science 293, 269 (2001).
B. Viswanathan and K. R. Krishanmurthy, Int. J. of Photoenergy, Article ID 269654, 10 pages (2012).
D. Morris, R. Dixon, F. H. Jones, Y. Dou et al., Phys. Rev. B 55, 16083 (1997).
H. Zhao, S. Bennici, J. Shen and A. Auroux, Appl. Catal. A 356, 121 (2009).
G. Silversmit and D. Depla, J. of Electron Spectroscopy and Related Phenomena 135, 167 (2004).
Z. Jiao, T. Chen, J. Xiong, T. Wang, G. Lu, J. Ye and Y. Bi, Scientific Reports 3, 2720 (2013).
X. B. Chen and C. Burda, J. Phys. Chem. B 108, 15446 (2004).
J. Xu, Y. Ao, M. Chen and D. Fu, Applied Surface Science 256, 4397 (2010).
Q. Meng, T. Wang, E. Liu, X. Ma, Q. Ge and J. Gong, Phys. Chem. Chem. Physics 15, 9549 (2013).
T. Umebayashi, T. Yanaki, H. Itoh and K. Asai, J. Phys. and Chem. of solids 63, 1909 (2002).
F. Strobel and D. P. Ridge, Inorg. Chem. 27, 891 (1988).
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Phung, H.N.T., Tran, V.N.K., Duong, P.A. et al. Effect of co-doping and tri-doping with transition metals and a nonmetal on photocatalytic activity in visible light of TiO2 thin film. Journal of the Korean Physical Society 70, 995–1000 (2017). https://doi.org/10.3938/jkps.70.995
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DOI: https://doi.org/10.3938/jkps.70.995