Abstract
Background
A set of Makrofol DE 1-1 polymeric samples was irradiated to different gamma doses. The dielectric response of irradiated polymers was investigated at a wide range of frequencies at room temperature. The modification induced in optical properties include the optical band gap (Eoptical), number of carbon per cluster (M), number of carbon per length (N), and refractive index (n) for irradiated samples were studied as well.
Methods
The dielectric constant (έ), dielectric loss factor (ε˝), loss tangent (tanδ), the ac electrical conductivity (σac), and impedance (Z) were measured in the frequency range from (100) Hz to (100) MHz. The optical band gap energy and its corresponding parameters for the samples were evaluated using ineffective thickness method (ITM).
Results
Gamma-ray irradiation had a considerable effect on the optical band gap energy for Makrofol DE 1-1 polymer detector film, which decreases from 4.20 to 3.96 eV and 4.35 to 4.16 eV for indirect and direct allowed transitions in ITM method, respectively, while it decreases from 4.40 to 4.20 eV in DITM method as a result of γ-ray dose increases. (n) of all studied samples is considerably high. (N) and (M) for the direct transition are lower than that for the indirect transition and their values increase with increasing gamma dose.
Conclusion
The results reveal that Makrofol DE1-1 polymer can be used as gamma dosimeter. Furthermore, Makrofol DE1-1 has much greater resistance to radiation damage; the attained results suggested strongly the applicability of Makrofol DE1-1 polymer to be used in medical products applications and suitable for optoelectronic and photoelectric devices.
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- Makrofol DE1-1 polymeric detectors have been irradiated with γ-irradiation with different doses.
- Electrical parameters of the pristine and irradiated samples were calculated.
- UV–visible spectra have been studied and the optical energy band gap as well as refractive index of un-irradiated and irradiated samples have been calculated.
- Number of carbon atoms per conjugate length and cluster have been calculated.
Background
Polymeric materials were and still have an interesting point of study, because its structure could be significantly changed by radiation. Thus, polymer composites and structure have steadily gained growing importance in the last few decades. The structure of such materials has been accomplished through electrical conductivity measurements (Zahran et al. 1981; Kumar et al. 2006). Irradiated polymeric materials with ionizing radiation such as γ-rays, X-rays, accelerated electrons, and ion beams leads to the formation of very reactive intermediates products like excited states, ions, and free radicals, which result in rearrangements and/or formation of new bonds. The effects of these reactions lead to the formation of oxidized products, grafts, scission of main chain (degradation), or cross-linking beside its effects on the optical, thermal, and electrical behavior of such polymer (Zahran et al. 1981; Saad et al. 2014; Fares 2011; Tayel et al. 2015; Rammah 2015, 2017; Al-Amri et al. 2017; Alfaramawi et al. 2017; Alsalhi et al. 2017; Jaleh et al. 2017; Rammah and Abdalla 2017; Rammah and Awad 2018; Saad et al. 2018; Abdul-Kader et al. 2018). Degradation and cross-linking occur simultaneously, and the outcome of the process is determined by a competition between the reactions (Kumar et al. 2006; Sinha et al. 2004). Oxidation and degradation occur gradually with increasing irradiation dose. Polycarbonate (PC) is a well-known engineering thermoplastic with an excellent balance of optical, physical, mechanical, and processing characteristics (Chung 1997; Cheng 2003). Polycarbonate detectors are used as a particle track detector for neutrons and alpha particles (Nouh et al. 2004; Price 2005; Awad et al. 2007; Awad et al. 2008; Rammah et al. 2018). Moreover, radiation effects on dielectric properties are of particular interest to science and technology and they have many applications in modern engineering (Basha et al. 1996; Ahmed et al. 2001; Kecskemeti et al. 2006; Hanafy 2008), and the effect of ion irradiation on the dielectric properties of polymers has been also studied earlier (Yoshida et al. 1980; Chailan et al. 1997; Martinez-Pardoma et al. 1998; Phukan et al. 1999; Fares 2011).
Therefore, the goal of the present work is to study the effect of gamma irradiation on electrical and optical properties of Makrofol DE 1-1 polymer detector. The dielectric constant (ε′), dielectric loss (ε′′), ac conductivity (σac) were measured and discussed. The optical energy band (Eoptical), number of carbon atoms per cluster (M), number of carbon atoms per length (N), and refractive index (n) were calculated using ineffective thickness method (ITM) and derivation of ineffective thickness method (DITM) methods.
Methods and theoretical considerations
Dielectric properties
The parameters of dielectric studies like the dielectric constant, ε′, dielectric loss, ε′′, and ac conductivity, σac reveals the electro-optic coefficient of the material (Ignatius et al. 2014). These parameters have been calculated by means of the following relations:
where
C, d, A, and εo are the capacitance, the thickness, the cross-sectional area of the sample, and the absolute permittivity of vacuum (8.854 × 10−9 F/cm), respectively. tanδ is the dissipation factor and Z is the impedance of the sample.
Optical properties
The optical properties for amorphous and crystalline materials like the optical energy band gap, Eoptical, and refractive index, n were studied by investigating the samples absorption spectra in the UV region. The electrons in the valence bands interact with electromagnetic waves and are raised to the conduction band. The optical transitions occur by two different ways; one is the indirect (forbidden or allowed) transition, whereas the other is the direct (forbidden or allowed) transition. In this study, the optical band gap energy for the samples were evaluated using ineffective thickness method (ITM). In this method, the optical band gap can be determined using data of the film absorbance spectra and independent on the samples thickness (Ghobadi 2016). Tauc’s formula (Tauc 1974) which modified by Mott and Davis (Mott and Davies 1979) as follows:
where (G) is a constant, (E = hv) is the incident photons energy, and (Eoptical) is optical energy band. (m) is the power characterizes electronic transition, and equal 0.5 and 2 for direct and indirect allowed transition, respectively. α(ν) is optical absorption coefficient defined by Beer–Lambert’s law as follows:
where A(λ) and t are the film absorbance and thickness, respectively. Substitute Eq. (5) into Eq. (4), one can get:
Eq. (6) can be rearranged as follows:
Let the constant \( {\left(\frac{2.303}{t}\right)}^{1/m} \) equals K, then Eq. (7) writes as follows:
Substitute the ratio \( \frac{G}{K} \) by new constant C, then
Equation (9) shows that optical band gap (Eoptical) determination depends only on absorbance (A(λ)) spectra instead of the absorption coefficient and avoiding any needs to film thickness. Then the values of optical energy band gap for the studied samples can be determined directly from extrapolating the linear region of (A(λ)E)1/m - E curve at (A(λ)E)1/m = 0.
The exact optical energy band gap of the studied samples can be evaluated by another method called derivation of ineffective thickness method (DITM), which is proposed to estimate of the exact optical band gap (Ghobadi 2016). In this method, the measure absorbance spectrum of the sample is needed only as well. Starting from ineffective thickness method (ITM), Eq. (9) can be rewritten as follows:
Taking ln of both sides of Eq. (10)
Then
Taking derivation of Eq. (12) with respect to E gives:
Plotting \( \frac{d\left\{\ln \left[A\left(\lambda \right)E\right]\right\}}{dE} \) versus E, a discontinuity at (E = Eoptical) will be found and the optical band gap can be estimated directly at this point.
Once the optical energy band gap of the studied samples were determined, their refractive index can be estimated (Dimitrov and Sakka 1996; Ali et al. 2017):
For a linear structure, the number of carbon atoms per conjugation length, (N) is given by (Fink and Hnatowicz 2007):
Where the value of β is taken to be − 2.9 eV as it is associated with π–π* optical transitions in –C=C– structure and 2β gives the band structure energy of a pair of adjacent π sites. Finally, the number of carbon atoms per cluster (M) is given by (Fink and Hnatowicz 2007):
Experimental procedures
Makrofol DE 1-1 (bisphenol-A polycarbonate) nuclear track detectors (NTDs) of chemical composition [C16 H14 O3] with thickness of 175 μm and density 1.2 g/m3 were used. Chemical structure (repeating unit) of Makrofol DE 1-1 polycarbonate detector is shown in Fig. 1. The samples were supplied by Bayer AG Leverkusen, Germany. The polymeric detector samples were cut to a size of 2 × 2 cm2 and irradiated with different γ-ray doses, viz. 1, 10, and 100 kGy using 1.25 MeV60Co gamma cell irradiation facility of type MC-20 with dose rate 4 kGy/h fabricated by the Russian Atomic Energy at Egyptian Atomic Energy Authority (EAEA). The detector samples were positioned at the center of the driving belt and the irradiation process was achieved automatically. The samples were irradiated for different times to maintain the desired doses.
Pristine and γ-irradiated samples were subjected to optical measurements using UV-visible spectrometer (UVS-2700) in the wavelength range from 190 to 1100 nm.
The electrical measurements of all samples were carried out at room temperature using an LCR (Hioki 3520 HiTester Meter Bridge) over the frequency range of 100 Hz–100 kHz. The good electrical contact during measurements was made by applying an air-drying type silver paint on the opposite sides of the bulk samples. By using the measured values of capacitance C, dielectric loss factor tanδ, and dimensions of the samples, the dielectric constant, ε′, dielectric loss, ε′′, and ac conductivity, σac have been calculated using Eqs. (1)–(3).
Results
The dielectric constant ε′ and dielectric loss ε′′ of un-irradiated and irradiated samples were found high at low-frequency region (nearly below 20 kHz), and their values increase with increasing γ-irradiation dose. The ac conductivity of the studied polymer increases with increasing the frequency γ-irradiation dose as well. Gamma-ray irradiation had a considerable effect on the optical band gap energy for Makrofol DE 1-1 polymer detector film, which decreases from 4.20 to 3.96 eV and 4.35 to 4.16 eV for indirect and direct allowed transitions in ITM method, respectively, while it decreases from 4.40 to 4.20 eV in DITM method as a result of the increase in γ-ray dose. The refractive index of all studied samples is considerably high, its values for the direct transition is less than that for the indirect transition and increases with increasing of γ-dose. The number of carbon atoms per conjugate length, N and the number of carbon atoms per cluster M for the direct band gap was found lower than that for the indirect energy band gap, and their values increase with increasing gamma dose.
Discussion
Electrical properties
Figures 2 and 3 depict the dielectric constant ε′ and dielectric loss ε′′ as a function of frequency for Makrofol DE 1-1 polymer irradiated to γ-ray with doses 0, 1, 10, and 100 kGy at room temperature. One can observe that the dielectric constant ε′ and dielectric loss ε′′ of all samples are high in the lower frequency region (nearly below 20 kHz). However, the region below 1 kHz shows sharper increase. At higher frequencies, the value ε′ and ε′′ were slowly decreased and nearly constant at frequency of 10 kHz. It can be attributed to the fact that as the frequency increases, the dipolar molecules in the polymer cannot be able to response further to the increase in the rates of the applied field. The observed increase in dielectric constant ε′ and dielectric loss ε′′ toward the low-frequency region is attributed to the interfacial polarization (Rajendran et al. 2004). Both pristine polymer and irradiated samples show similar trend. Results of Figs. 2 and 3 reveal that an increase in ε′ and ε′′ values with γ-ray doses. This can be attributed to the formation of some defects sites in the band gaps of polymer because of occurrence of chain scission. Generally, these defects may indicate sign of the existence of charge carriers traps in the band gap of the polymer (Velitchkova et al. 2000; El-Sayed et al. 2004). Therefore, the irradiation increases the ability of the polymer to store charge, i.e., the increase of its dielectric constant (Abdul-Kader et al. 2014).
Figure 4 shows the variation of the Makrofol DE 1-1 samples impedance with frequency for different gamma irradiation doses. It can be noticed that the impedance rapidly decreases by increasing the frequency and the impedance increased by increasing the dose.
Figure 5 illustrates the frequency dependence of ac conductivity, σac, for irradiated Makrofol DE 1-1 polymer at room temperature. From this figure, one can notice that ac conductivity of samples increases with increasing frequency, which is the common characteristic of disordered materials and increases with increasing gamma irradiation doses. Figures 4 and 5 show consistent data that at high frequency the impedance decreases and the ac conductivity increases.
The variation of the ac conductivity of Makrofol DE 1-1 samples with different gamma doses at different frequencies is presented in Fig. 6. It was found that as the dose increases as the σac increases up to 10 kGy and the detector ac conductivity is almost saturated from 10 kGy up to 100 kGy. Polymer exposure to gamma irradiation will lead to increase the conductivity of the detector as explained in literature (Singh et al. 2005; Czvikovszky and Hargitai 1999). Interaction of gamma photons with the polymer components will produce a flood of δ-rays, which in turn produce huge number of free radicals leading to scission of polymer chains. With increasing the absorbed doses, the energy deposited in polymer material increases and therefore the number of the conjugated double bonds increases (Hussain et al. 2005). Increasing the conjugated double bonds increases the delocalization of charge carriers, and hence their motion in an applied external electric field. This net polarization produces higher ac conductivity at higher frequency (Jonscher 1977).
Optical properties
Figure 7 illustrates the experimental UV spectra at 280–400 nm for pristine and γ-irradiated Makrofol DE 1-1 samples. Pristine and 1 kGy irradiated samples show the same absorption behavior. Higher γ-doses (greater than 1 kGy) lead to formation of color centers appeared as a shoulder superimposed on the UV spectra in the range 310–320 nm. This may be the reason for the color change of plastic from transparent to faint yellowish after γ-irradiation. The optical energy band gap for the studied samples were determined using ineffective thickness method (ITM) (Ghobadi 2016) by putting the power m in Eq. (9) equals to 0.5 and 2 for direct and indirect allowed transition, respectively. Plotting (A(λ)E)2 and (A(λ)E)1/2 against E for direct and indirect allowed transition are shown in Figs. 8a–d and 9a–d, respectively. The values of optical energy band gap for pristine and γ-irradiated Makrofol DE 1-1 samples were determined directly from extrapolating the linear region of (A(λ)E)1/m - E curve at (A(λ)E)1/m = 0 and the values are tabulated in Table 1.
The optical energy band gap of the studied samples is also evaluated using the derivation of ineffective thickness method (DITM) (Ghobadi 2016) using Eq. (13) (Fig. 9). Figure 10 depicts the variation of dln[(A(λ)E)]/dE with E for pristine and γ-irradiated Makrofol DE 1-1 samples. Values of the optical energy band gaps are determined and summarized in Table 1. Results show that there is a good agreement between energy gap values which are obtained from ITM and DITM methods. One can notice that the values of energy gap of indirect and direct band gap in Makrofol DE 1-1 polymer detector decreasing with increasing gamma dose. Furthermore, the values of indirect band gap have been found to be lower than the corresponding values for the direct band gap. These decreases are attributed to the fact that irradiation induced defects and/or increase the number of conjugated bonds (–C=C–). This means that the conductivity of the irradiated polymer with gamma radiation is greater than that of the bulk. Moreover, such a decrease in Eoptical may be attributed to the formation of new photo-chemicals, which form the trap levels between the HOMO and LUMO energy states, making the lower energy transitions feasible and results in the reduction of the optical band gap (Durrani and Bull 1987). In this study, the energy band gap for Makrofol DE 1-1 polymer decreases from 4.20 to 3.96 eV and from 4.35 to 4.16 eV for indirect and direct allowed transitions in ITM method, respectively. While the band gap decreases from 4.40 to 4.20 eV in DITM method as a result of γ-ray dose increases. Thus, the present study proves that the optical energy band gap of Makrofol DE 1-1 polymer detector is rather dependent on the γ-dose. These results are somewhat consistent with the published data for the effect of γ-dose on different types of polymeric detectors like Sinha et al. (2001), Nouh et al. (2004), and Rammah and Abdalla (2017).
Refractive index of pristine and γ-irradiated Makrofol DE 1-1 samples was calculated using Eq. (14) (Dimitrov and Sakka 1996; ali et al. 2017). Table 1 collected the calculated refractive index by both ITM and DITM methods. Results showed that the refractive index of all samples is considerably high. The refractive index of the present samples for the direct transition is less than that for the indirect transition, and its value increases with increasing of γ-dose. This sheds light on usage γ-irradiated Makrofol DE 1-1 detectors in optoelectronic devices, since the wave propagation is strongly influenced by the distribution of the refractive index.
Makrofol DE 1-1 is an aromatic polymer characterized by a linear chain structure, thus the optical gap band Eoptical is correlated with the number of carbon bonds per molecule (Dimitrov and Sakka 1996). The shift in the absorption edges toward the visible from the ultraviolet (see Fig. 7) could be attributed to an increase in the conjugation length and a condensation of the aromatic rings into a compact carbonaceous cluster. The linear structure of the polymer and the number of carbon atoms per conjugation length N was calculated using Eq. (15) in direct and indirect transitions for pristine and γ-irradiated Makrofol DE 1-1 samples in ITM and DITM methods and listed in Table 2.
To enhance the optical properties of the polymeric material, the carbonaceous cluster is one of the important parameters. This cluster is rich with charge carrier, which enhances the surface conductivity of the polymers. The number of carbon atoms per cluster M was calculated by Eq. (16) in direct and indirect transitions for pristine and γ-irradiated Makrofol DE 1-1 samples in ITM and DITM methods and listed in Table 2. The number of carbon atoms per conjugate length N and the number of carbon atoms per cluster M for the direct band gap was lower than that for the indirect energy band gap, and their values increase with increasing gamma dose. This increase is attributed to cleavages of C–H bonds during the irradiation and, consequently, to the release of hydrogen.
Conclusions
The data analysis of the electrical parameters and the UV–visible spectra of the pristine and γ-irradiated Makrofol DE 1-1 polymeric detector led to the following conclusions:
-
1-
The dielectric constant ε′ and dielectric loss ε′′ of pristine and irradiated samples are high at low-frequency region nearly below 20 kHz, and their values increase with increasing γ-irradiation dose.
-
2-
The ac conductivity of the studied polymer increases with increasing frequency and increases with increasing γ-dose.
-
3-
UV-vis spectra of pristine and γ-irradiated Makrofol DE 1-1 detector reveal a shift toward the longer wavelength with increasing of the dose.
-
4-
Gamma-ray irradiation had a considerable effect on the optical band gap energy for Makrofol DE 1-1 detector that it decreases from 4.20 to 3.96 eV and from 4.35 to 4.16 eV for indirect and direct allowed transitions in ITM method, respectively. While it decreases from 4.40 to 4.20 eV in DITM method as a result of γ-ray dose increases.
-
5-
The refractive index of all studied samples is considerably high, its values for the direct transition is less than that for the indirect transition and increases with increasing of γ-dose.
-
6-
The number of carbon atoms per conjugate length N and the number of carbon atoms per cluster M for the direct band gap are lower than that for the indirect energy band gap, and their values are increasing with increasing gamma dose.
-
7-
Electrical and optical observations in this study suggested that the Makrofol DE 1-1 detector is suitable for optoelectronic and photoelectric devices.
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Acknowledgements
The authors would like to thank Prof. A. Hussein, Physics Department, Faculty of Science, Menoufia University, Egypt for his fruitful help, valuable comments, and his efforts to achievement this work. Special thanks to Prof. M. El Ghazaly, Physics Department, Faculty of Science, Zagazig University, Egypt, who provides us with the samples.
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Rammah, Y.S., Ibrahim, S.E. & Awad, E.M. Electrical and optical properties of Makrofol DE 1-1 polymeric films induced by gamma irradiation. Bull Natl Res Cent 43, 32 (2019). https://doi.org/10.1186/s42269-019-0071-4
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DOI: https://doi.org/10.1186/s42269-019-0071-4