Skip to main content
Log in

Utilization of Cr(VI) solutions with steel shavings

  • Inorganic Synthesis and Industrial Inorganic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

New single-stage method was developed for chemical utilization of wastewater containing 0.25 to 400 g L–1 of chromium in terms of chromium anhydride with the us of sulfuric acid and steel cuttings. The method makes it possible to convert hexavalent chromium into easily used ferrochromium precipitates. It was found that there occur periodic synchronous concentration fluctuations of Cr(VI) and Cr(III) up to, respectively, 400 g L–1 and 150 mg L–1 in the course of reduction of hexavalent chromium with the use of steel cuttings in sulfuric acid solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Vinogradov, S.S., Ekologicheski bezopasnoe gal’vanicheskoe proizvodstvo (Ecologically Safe Electroplating Industry), Kudryavtsev, V.N., Ed., Moscow: Globus, 2002, 2nd ed. rev. suppl.

  2. Kuzubova, L.I. and Morozov, S.V., Ochistka neftesoderzhashchikh stochnykh vod: Analiticheskii obzor (Purification of Oil-containing Wastewater: Analytical Review), Novosibirsk: SORAN; GPNTB; NIOKh, 1992.

    Google Scholar 

  3. Kvasnikov, E.I. and Serpokrylov, N.S., Biologicheskaya ochistka khromsoderzhashchikh promyshlennykh stochnykh vod (Biological Purification of Chromium-containing Industrial Wastewater), Kiev: Naukova Dumka, 1990.

    Google Scholar 

  4. Chanturiya, V.A. and Solozhenkin, P.M., Gal’vanokhimicheskie metody ochistki tekhnogennykh vod (Galvanochemical Methods for Purification of Technological Wastewater), Moscow: IKTs Akademkniga, 2005.

    Google Scholar 

  5. Vinogradov, S.S. and Kruglikov, S.S., Gal’vanotekh. Obrab. Poverkh., 2008, vol. 16, no. 1, pp. 46–47.

    Google Scholar 

  6. Skrylev, L.D., Skryleva, T.L., and Koltykova, G.N., Khim. Tekhnol. Vody, 1997, vol. 19, no. 5, pp. 516–523.

    CAS  Google Scholar 

  7. Rogov, V.M. and Shvetsova, T.L., Khim. Tekhnol. Vody, 1986, vol. 8, no. 3, pp. 22–25.

    CAS  Google Scholar 

  8. Fazlutdinov, K.K., Markov, V.F., and Maskaeva, L.N., Butlerov Soobshch., 2014, vol. 37, no. 2, pp. 10–17.

    Google Scholar 

  9. Fazlutdinov, K.K., Markov, V.F., and Maskaeva, L.N., Butlerov Soobshch., 2014, vol. 39, no. 8, pp. 34–39.

    Google Scholar 

  10. Meites, L., An Introduction to Chemical Equilibrium and Kinetics, New York: Pergamon Press, 1981.

    Google Scholar 

  11. Nikandrova, L.I., Gerasimova, N.I., Ivanova, L.V., and Kondratovich, G.A., Analiz elektrolitov i rastvorov (Analysis of Electrolytes and Solutions), Moscow: Gos. Khim. Izdat, 1963.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to K. K. Fazlutdinov.

Additional information

Original Russian Text © K.K. Fazlutdinov, V.F. Markov, A.V. Gorokhov, L.N. Maskaeva, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 8, pp. 971−977.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fazlutdinov, K.K., Markov, V.F., Gorokhov, A.V. et al. Utilization of Cr(VI) solutions with steel shavings. Russ J Appl Chem 89, 1221–1227 (2016). https://doi.org/10.1134/S1070427216080024

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427216080024

Navigation