Skip to main content
Log in

Mechanochemical preparation of polymeric composites consisting of polyamide and clay materials

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The mechanism of mechanochemical formation of composites consisting of PA-6 polyamide and clay minerals (pyrophyllite, kaolinite) was studied by IR spectroscopy and X-ray diffraction analysis. Composites with chemical bonding between the components are formed by activation of polyamide-pyrophyllite mixtures at polymer content c ≤ 10% and of polyamide-kaolinite mixtures at c ≤ 5%. Increased polymer content of the starting mixture “inhibits” the disordering of the silicate structure in the course of activation. Modification of polymers with mechanochemically formed polyamide/clay mineral composites improves the physicomechanical characteristics of the composite materials obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Okhlopkova, A.A., Vinogradova, A.V., and Pinchuk, L.S., Plastiki, napolnennye ul’tradispersnymi neorganicheskimi soedineniyami (Plastics Filled with Ultradispersed Inorganic Compounds), Gomel: NANB Inst. Mekhaniki Metallopolimernykh Sistem, 1999.

    Google Scholar 

  2. Vinogradova, N.E., Protivoiznosnye prisadki k maslam (Antiwear Additives to Oils), Moscow: Khimiya, 1972.

    Google Scholar 

  3. Vorob’eva, S.A., Trenie Iznos, 1996, vol. 17, no. 6, pp. 827–831.

    Google Scholar 

  4. Cherdyntseva, S.V., Belousov, S.I., Krasheninnikov, S.V., et al., Plast. Massy, 2013, no. 2, pp. 11–14.

    Google Scholar 

  5. Osipchik, V.S., Sukhinina, A.V., and Gureev, Yu.A., Plast. Massy, 2008, no. 6, pp. 11–14.

    Google Scholar 

  6. Handbook of Fillers and Reinforcements for Plastics, Katz, H.S. and Milewski, J.V., Eds., New York: Van Nostrand Reinhold, 1978.

    Google Scholar 

  7. Ikekawa, A. and Hayakawa, S., Sib. Khim. Zh., 1991, no. 5, pp. 19–24.

    Google Scholar 

  8. Smith, A.L., Applied Infrared Spectroscopy, New York: Wiley-Interscience, 1979.

    Google Scholar 

  9. Tarasevich, Yu.I., Stroenie i khimiya poverkhnosti sloistykh silikatov (Structure and Chemistry of the Surface of Layered Silicates), Kiev: Naukova Dumka, 1988.

    Google Scholar 

  10. Dechant, J., Ultrarotspektroskopische Untersuchungen an Polymeren, Berlin: Akademie, 1972.

    Google Scholar 

  11. Vorsina, I.A., Grigor’eva, T.F., Udalova, T.A., et al., J. Appl. Spectrosc., 2014, vol. 81, no. 2, pp. 244–249.

    Article  CAS  Google Scholar 

  12. Vorsina, I.A., Barinova, A.P., and Lyakhov, N.Z., Khim. Inter. Ustoich. Razv., 2004, vol. 12, no. 2, pp. 303–311.

    CAS  Google Scholar 

  13. Vorsina, I.A., Grigor’eva, T.F., Barinova, A.P., and Lyakhov, N.Z., Khim. Inter. Ustoich. Razv., 2011, vol. 19, no. 1, pp. 1–10.

    Google Scholar 

  14. Avvakumov, E.G., Mekhanicheskie metody aktivatsii khimicheskikh protsessov (Mechanical Methods for Activation of Chemical Processes), Novosibirsk: Nauka, 1986.

    Google Scholar 

  15. Heller-Kallai, L., Yariv, S., and Fridman, I., J. Therm. Anal., 1986, vol. 31, pp. 95–106.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. A. Udalova.

Additional information

Original Russian Text © I.A. Vorsina, T.F. Grigor’eva, T.A. Udalova, S.V. Vosmerikov, N.Z. Lyakhov, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 3, pp. 484–489.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vorsina, I.A., Grigor’eva, T.F., Udalova, T.A. et al. Mechanochemical preparation of polymeric composites consisting of polyamide and clay materials. Russ J Appl Chem 88, 488–493 (2015). https://doi.org/10.1134/S1070427215030192

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427215030192

Keywords

Navigation