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Synthesis, transport, and ionophore properties of α,ω-biphosphorylated azapodands: VIII. Solvent extraction of the metal ions with N,N′-bis(dioctylphosphorylmethyl)-1,8-diamino-3,6-dioxaoctane

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Abstract

Liquid extraction from the aqueous solutions of perchloric acid with neutral azapodand extractant N,N′-bis(dioctylphosphorylmethyl)-1,8-diamino-3,6-dioxaoctane has been highly efficient in the cases of uranyl ions and some metals of groups II and III. To estimate the synergic effect of organophosphorus extractants, the neutral extractant was applied in the mixture with an acidic component, bis(pentadecyl)phosphoric acid. The synergic effect has exclusively been observed in the extraction of zinc and cadmium ions.

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References

  1. Garifzyanov, A.R., Davletshin, R.R., Davletshina, N.V., and Cherkasov, R.A., Russ. J. Gen. Chem., 2013, vol. 83, no. 2, p. 398.

    Article  CAS  Google Scholar 

  2. Cherkasov, R.A., Vasil’ev, R.I., Garifzyanov, A.R., and Talan, A.S., Russ. J. Gen. Chem., 2008, vol. 78, no. 6, p. 1167.

    Article  CAS  Google Scholar 

  3. Garifzyanov, A.R., Davletshin, R.R., Davletshina, N.V., and Cherkasov, R.A., Russ. J. Gen. Chem., 2012, vol. 82, no. 10, p. 1646.

    Article  CAS  Google Scholar 

  4. Bansal, B., Chen, X., and Hossain, M., Chem. Eng. Proc., 2005, vol. 44, no. 5, p. 1327.

    Article  CAS  Google Scholar 

  5. Zhao, J.M., Shen, X.Y., Deng, F.L., Wang, F.C., Wu, Y. and Liu, H.Z., Sep. Purific. Technol., 2011, vol. 78, no. 2, p. 345.

    CAS  Google Scholar 

  6. Ramakul, P., Supajaroon, T., Prapasawat, T., Pancharoen, U., and Lothongkum, A., J. Indust. Engin. Chem., 2009, vol. 15, no. 2, p. 224.

    Article  CAS  Google Scholar 

  7. Gaikwad, A.G., Chem. Biochem. Eng., 2003, vol. 17, no. 4, p. 327.

    CAS  Google Scholar 

  8. Gaikwad, A.G., Talanta, 2004, vol. 63, no. 4, p. 917.

    Article  CAS  Google Scholar 

  9. Cherkasov, R.A., Garifzyanov, A.R., Leont’eva, S.V., Davletshin, R.R., and Koshkin, S.A., Russ. J. Gen. Chem., 2009, vol. 79, no. 12, p. 2599.

    Article  CAS  Google Scholar 

  10. Wang, C. and Li, D.Q., Solvent Extr. Ion Exch., 1994, vol. 12, no. 3, p. 615.

    Article  CAS  Google Scholar 

  11. Wang, W. and Cheng, C.Y., J. Chem. Technol. Biotechnol., 2011, vol. 86, no. 5, p. 1237.

    Article  CAS  Google Scholar 

  12. Martynov, B.V., Spravochnik po ekstraktsii. Ekstraktsiya organicheskimi kislotami i ikh solyami (Guide to Extraction. Extraction with Organic Acids and Its Salts), Moscow: Atomizdat, 1978, vol. 3.

  13. Wang, C. and Li, D.Q., Solvent Extr. Ion Exch., 1994, vol. 12, no. 3, p. 615.

    Article  CAS  Google Scholar 

  14. Wang, W., Pranolo, Y., and Cheng, C.Y., Hydrometallurgy, 2011, vol. 108, no. 1, p. 100.

    Article  CAS  Google Scholar 

  15. Garifzyanov, A.R., Vasil’ev, R.I., and Cherkasov, R.A., Russ. J. Gen. Chem., 2005, vol. 75, no. 2, p. 217.

    Article  CAS  Google Scholar 

  16. Busev, A.I., Sintez novykh organicheskikh reagentov dlya neorganicheskogo analiza (The Synthesis of New Organic Reagents for Inorganic Analysis), Moscow: Mosk. Univ., 1972.

    Google Scholar 

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Authors and Affiliations

  1. Kazan Federal University, ul. Kremlyevskaya 18, Kazan, Tatarstan, 420008, Russia

    A. R. Garifzyanov, S. V. Leont’ev, N. V. Davletshina, A. V. Voloshin & R. A. Cherkasov

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  1. A. R. Garifzyanov
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  2. S. V. Leont’ev
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  3. N. V. Davletshina
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  4. A. V. Voloshin
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  5. R. A. Cherkasov
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Correspondence to R. A. Cherkasov.

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Original Russian Text © A.R. Garifzyanov, S.V. Leont’ev, N.V. Davletshina, A.V. Voloshin, R.A. Cherkasov, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 11, pp. 1796–1804.

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Garifzyanov, A.R., Leont’ev, S.V., Davletshina, N.V. et al. Synthesis, transport, and ionophore properties of α,ω-biphosphorylated azapodands: VIII. Solvent extraction of the metal ions with N,N′-bis(dioctylphosphorylmethyl)-1,8-diamino-3,6-dioxaoctane. Russ J Gen Chem 83, 1997–2004 (2013). https://doi.org/10.1134/S1070363213110054

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  • DOI: https://doi.org/10.1134/S1070363213110054

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