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Synthesis and crystal structure of the nickel(II) complex with 2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone

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Abstract

2-Diphenylphosphinobenzaldehyde 2-quinolinylhydrazone (HL) and its nickel(II) complex [Ni(L)(CH3COO)] were synthesized. The structure of the complex was determined by X-ray diffraction. The nickel ion in the molecule of the complex has a square PNN’O donor environment. Owing to C-H...O intermolecular hydrogen bonds, centrosymmetric dimers are formed in the crystal.

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Correspondence to S. I. Levchenkov.

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Original Russian Text © L.D. Popov, S.I. Levchenkov, I.N. Shcherbakov, Z.A. Starikova, V.V. Lukov, V.A. Kogan, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 5, pp. 281–284.

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Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N. et al. Synthesis and crystal structure of the nickel(II) complex with 2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone. Russ J Coord Chem 40, 280–283 (2014). https://doi.org/10.1134/S1070328414050108

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  • DOI: https://doi.org/10.1134/S1070328414050108

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