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Complex salts trans-[Rh(β-Pic)4Cl2]X (X = Cl−, ReO −4 , and ClO −4 ): Synthesis, crystal structures, and thermal properties

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Abstract

Three novel complex salts containing the cation trans-[Rh(β-Pic)4Cl2]+ with the anions Cl− (I), ReO −4 (II), and ClO −4 (III) were obtained and characterized by elemental analysis, X-ray diffraction, NMR spectroscopy, and IR spectroscopy. The complex trans-[Rh(β-Pic)4Cl2]ReO4 crystallizes from DMF as a solvate in which solvent molecules fill the channels formed by the cations and anions. The thermal properties of complexes I, II, and II · DMF were examined by DTA. Final and some intermediate products of the thermolysis were isolated and characterized by physicochemical methods.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    D. B. Vasil’chenko, E. Yu. Filatov, I. A. Baidina, P. E. Plyusnin & S. V. Korenev

  2. Novosibirsk State University, Novosibirsk, Russia

    E. Yu. Filatov, P. E. Plyusnin & S. V. Korenev

Authors
  1. D. B. Vasil’chenko
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  2. E. Yu. Filatov
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  3. I. A. Baidina
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  4. P. E. Plyusnin
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  5. S. V. Korenev
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Correspondence to D. B. Vasil’chenko.

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Original Russian Text © D.B. Vasil’chenko, E.Yu. Filatov, I.A. Baidina, P.E. Plyusnin, S.V. Korenev, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 5, pp. 347–352.

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Vasil’chenko, D.B., Filatov, E.Y., Baidina, I.A. et al. Complex salts trans-[Rh(β-Pic)4Cl2]X (X = Cl−, ReO −4 , and ClO −4 ): Synthesis, crystal structures, and thermal properties. Russ J Coord Chem 36, 347–352 (2010). https://doi.org/10.1134/S1070328410050052

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  • DOI: https://doi.org/10.1134/S1070328410050052

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