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Crystal structure of the CuCl2 complex with N',N'-dimethyl-para-tert-butylbenzohydrazide [Cu(n-(t-Bu)C6H4CONHN(Me)2)]Cl2

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Abstract

The X-ray diffraction analysis of [Cu(p-(t-Bu)C6H4CONHN(Me)2)]Cl2 (I) has been performed. The complex is binuclear. Its structure represents a centrosymmetric dimer. Copper atoms are linked to each other via two bridging chlorine atoms. The copper coordination polyhedron is a distorted trigonal bipyramid. The dialkylhydrazide reagent is a bidentate (O, N(2)) ligand linked to the central atom to form a five-membered chelate ring, which has an envelope conformation with a copper atom in its “flap.” Crystals are monoclinic.

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Authors and Affiliations

  1. Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences, ul. Akademika Koroleva 3, Perm, 614013, Russia

    V. Yu. Gusev & A. V. Radushev

Authors
  1. V. Yu. Gusev
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  2. A. V. Radushev
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Correspondence to V. Yu. Gusev.

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Original Russian Text © V.Yu. Gusev, A.V. Radushev, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 8, pp. 1012–1016.

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Gusev, V.Y., Radushev, A.V. Crystal structure of the CuCl2 complex with N',N'-dimethyl-para-tert-butylbenzohydrazide [Cu(n-(t-Bu)C6H4CONHN(Me)2)]Cl2 . Russ. J. Inorg. Chem. 61, 964–968 (2016). https://doi.org/10.1134/S0036023616080106

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  • DOI: https://doi.org/10.1134/S0036023616080106

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