Abstract
Bristow and Watson1 have recently described the determination of the cohesive energy densities of polymers by swelling and viscosity measurements. This communication summarizes the results of viscosity measurements on polystyrene solutions directed towards a similar end. The measurements cover a slightly different range of solvents from that of Bristow and Watson, and in some solvents a range of molecular weights has been investigated.
Similar content being viewed by others
References
Bristow, G. M., and Watson, W. F., Trans. Farad. Soc., 54, 1567, 1731, 1742 (1958).
Flory, P. J., and Fox, T. G., J. Amer. Chem. Soc., 73, 1904 (1951).
Streeter, D. J., and Boyer, R. F., Indust. Eng. Chem., 43, 1790 (1951).
Schick, A. F., quoted in Boundy, R. H., and Boyer, R. F., “Styrene, its Polymers, Copolymers and Derivatives”, 390 (Reinhold, New York, 1952).
Bawn, C. E. H., Freeman, R. F. J., and Kamaliddin, A. R., Trans. Farad. Soc., 46, 677 (1950). Bawn, C. E. H., and Wajid, M. A., ibid., 52, 1458 (1956).
Flory, P. J., “Principles of Polymer Chemistry”, 602 (Cornell, New York, 1953).
Bawn, C. E. H., Freeman, R. F. J., and Kamaliddin, A. R., Trans. Farad. Soc., 46, 1107 (1950).
Huggins, M. L., J. Chem. Phys., 9, 440 (1951).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
GREEN, J. Cohesive Energy Density of Polystyrene. Nature 183, 818–819 (1959). https://doi.org/10.1038/183818a0
Issue Date:
DOI: https://doi.org/10.1038/183818a0
- Springer Nature Limited
This article is cited by
-
Problems of adhesive contact. A review
Polymer Mechanics (1972)
-
Role of diffusion in the formation of adhesion bonds between polymers
Polymer Mechanics (1971)