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Monomeric Ferric Laurate in Toluene

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Abstract

METAL soaps occur as two distinct types of aggregate in non-polar solvents. The majority of mono- and di-valent soaps form large complexes held together by dipole association1. The trivalent aluminium compounds which are obtained as the basic mono- or di-soaps appear, on the other hand, to have a polymeric structure joined by metal–oxygen co-ordinate links2 or by hydrogen bonds3. Solutions of the aluminium soaps exhibit characteristic visco-elastic phenomena and are believed to contain large fibrous aggregates.

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References

  1. Lawrence, A. S. C., Trans. Farad. Soc., 34, 660 (1938). Martin, E., and Pink, R. C., J. Chem. Soc., 1750 (1948).

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  2. Gray, V. R., and Alexander, A. E., J. Phys. and Colloid Chem., 53, 23 (1949).

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  3. Glazer, J., Schulman, J. H., and McRoberts, T. S., J. Chem. Soc., 2082 (1950).

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NELSON, S., PINK, R. Monomeric Ferric Laurate in Toluene. Nature 169, 620–621 (1952). https://doi.org/10.1038/169620b0

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