Abstract
A model is constructed for sorption dynamics in multicomponent ion-exchange systems with a weak-base ion exchanger. The model is based on computer-solved nonlinear material balances and internal-diffusion kinetic equations. The multicomponent equilibria involving a weak-base ion exchanger are described in terms of surface complexation theory. According to this theory, the fixed amino groups of the ion exchanger (Lewis bases) and sorbate anions form complexes with metal cations (Lewis acids). These complexes are located in different Stern layers at different distances from the surface. Sorption dynamics models are considered for the frontal ion-exchange chromatographic separation of the H+/A/B/X (A, B; = Cu2+, Zn2+, Ni2+, Cd2+; X = Cl−, SO 2−4 ) systems on the amino-containing weak-base ion exchangers Purolite A-109 and Fuji PEI-CS-07. Frontal ion-exchange chromatograms are compared for a number of multicomponent systems.
Similar content being viewed by others
REFERENCES
Klein, G. and Helfferich, F., Multicomponent Chromatography, New York: M. Dekker, 1970.
Kalinichev, A.I., Nonlinear Theory of Multicomponent Dynamics of Sorption and Chromatography, Usp. Khim., 1996, vol. 65, no. 2, p. 103.
Horst, J., Hoell, W.H., and Eberle, S., Application of the Surface Complex Formation Model to Ion Exchange Equilibria: Part I. Weak Acid Resins, React. Polym., 1990, vol. 13, p. 209.
Hoell, W.H., Horst, J., and Wernet, M., Application of the Surface Complex Formation Model to Ion Exchange Equilibria: Part II. Chelating Resins, React. Polym., 1991, vol. 14, p. 251.
Hoell, W.H., Horst, J., and Franzreb, M., Application of the Surface Complex Formation Model to Ion Exchange Equilibria: Part III. Anion Exchangers, React. Polym., 1993, vol. 19, p. 123.
Hoell, W.H., Horst, J., Franzreb, M., and Eberle, S.H., Description of Ion-Exchange Equilibria by Means of the Surface Complexation Theory, Ion Exchange and Solvent Extraction, Marinsky, J. and Marcus, Y., Eds., New York: M. Dekker, 1993, vol. 11, p. 151.
Horst, J. and Hoell, W.H., Application of the Surface Complex Formation Model to Ion Exchange Equilibria: Part IV. Amphoteric Sorption onto Aluminium Oxide, J. Colloid Interface Sci., 1997, vol. 195, p. 250.
Hoell, W.H., Description of Sorption Equilibria for Ions onto Activated Carbon Using the Surface Complexation Theory, Water Sci. Tech., 1997, vol. 35, p. 287.
Hoell, W.H. and Horst, J., Surface Complexation Theory: Multispecies Ion Exchange Equilibria, Encyclopedia of Separation Science, Wilson, I.D., Edlard, T.R., Poole, C.A., and Cooke, M., Eds., London: Academic, 2001, vol. 2, p. 1640.
Stöhr, C. and Höll, W.H., Application of the Surface Complex Formation Model to Ion Exchange Equilibria: Part V. Adsorption of Heavy Metal Salts, React. Funct. Polym., 2001, vol. 49, p. 117.
Kiefer, R. and Hoell, W., Sorption of Heavy Metals onto Selective Ion-Exchange Resins with Aminophosphonate Functional Groups, Ind. Eng. Chem. Res., 2001, vol. 40, p. 4570.
Hoell, W.H. and Horst, J., Description of Multicomponent Ion-Exchange Equilibria by Means of the Surface Complexation Theory, Sorbtsionnye i khromatograficheskie protsessy (Sorption and Chromatographic Processes), Voronezh: Voronezh. Gos. Univ., 2001, vol. 1, no. 2, p. 145.
Kalinichev, A.I., Hoell, W.H., and Kiefer, R., A Computer Description of the Dynamic Behavior of Multicomponent Nonlinear Ion-Exchange Systems Based on the Model of Formation of Surface Complexes, Zh. Fiz. Khim., 1999, vol. 73, no. 9, p. 1627.
Kalinichev, A.I. and Hoell, W.H., Description of the Dynamic Behavior of Multicomponent Nonlinear Ion-Exchange Systems on the Basis of a Model of Formation of Surface Complexes, Zh. Fiz. Khim., 2000, vol. 74, no. 3, p. 466.
Kalinichev, A.I. and Hoell, W.H., Description of the Dynamic Behavior of Multicomponent Nonlinear Ion-Exchange Systems on the Basis of a Model of Formation of Surface Complexes with Consideration of Chemical Reactions between Components in the Solution, Sorbtsionnye i khromatograficheskie protsessy (Sorption and Chromatographic Processes), Voronezh: Voronezh. Gos. Univ., 2001, vol. 1, no. 2, p. 157.
Kalinichev, A.I. and Hoell, W.H., Modeling of the Sorption Dynamics in Multicomponent Ion-Exchange Systems with Consideration of Complexation Reactions on the Basis of the Surface Complexation Theory, Teor. Osn. Khim. Tekhnol., 2003, vol. 37, no. 3, p. 226.
Rights and permissions
About this article
Cite this article
Kalinichev, A.I., Hoell, W.H. Modeling of Sorption Dynamics in Transition Metal Ion–Weak-Base Ion Exchanger Systems in Terms of Surface Complexation Theory. Theoretical Foundations of Chemical Engineering 38, 284–290 (2004). https://doi.org/10.1023/B:TFCE.0000032190.87353.be
Issue Date:
DOI: https://doi.org/10.1023/B:TFCE.0000032190.87353.be