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Spectrochemical Properties of Noncubical Transition Metal Complexes in Solution. XII. Angular Overlap Studies of Salicylideneethylenediamine Cu(II) Complex in Various Solvents

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Abstract

As a part of our general interest in the UV-Vis spectroscopy of multidentate mixed-donor ligands, the (salicylideneethylenediamine)Cu(II) complex has been prepared and characterized by elemental analyses, solubility in common solvents, molar conductivities, and ultraviolet (UV), and visible (Vis) spectroscopy. The combined results of spectrophotometric measurements and EPR spectra, as well as known the X-ray structure for solids, were used to determine the structure of the investigated complex in solutions. The spectra of [Cu(salen)] (H2salen = salicylideneethylenediamine), were measured in various solvents at room temperature, resolved by Gaussian analysis, and angular overlap model (AOM) treated in C 2v symmetry. Because of overparametrization problems, the bis(salicylaldehyde)Cu(II) complex has been characterized and AOM treated. The results of this have been used for AOM studies of [Cu(salen)]. The effect of the solvents upon the σ- and π-bonding ligand abilities is discussed.

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Authors and Affiliations

  1. Department of Chemistry, University of Podlasie, PL 08-110, Siedlce, Poland

    Krzysztof Kurzak, Iwona Kuźniarska-Biernacka & Barbara Kurzak

  2. Faculty of Chemistry, University of Wrocław, PL 50-383, Wrocław, Poland

    Julia Jezierska

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  1. Krzysztof Kurzak
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  2. Iwona Kuźniarska-Biernacka
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  3. Barbara Kurzak
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  4. Julia Jezierska
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Kurzak, K., Kuźniarska-Biernacka, I., Kurzak, B. et al. Spectrochemical Properties of Noncubical Transition Metal Complexes in Solution. XII. Angular Overlap Studies of Salicylideneethylenediamine Cu(II) Complex in Various Solvents. Journal of Solution Chemistry 30, 709–731 (2001). https://doi.org/10.1023/A:1011957312088

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