Abstract
Nickel(0) complexes coordinatively unsaturated with 2,2"-bipyridine (bpy) are more reactive in the oxidative addition to organic halides than the saturated analogs. σ-Organonickel complexes formed as intermediates of catalytic cycles were prepared in high yields using nickel complexes coordinatively unsaturated with bpy and aromatic halides containing a methyl group in the ortho-position of the ring.
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References
H. Lemkuhl, Synthesis, 1973, 377.
C. P. Andrieux and J. M. Saveant, in Investigations of Rates and Mechanisms of Reactions, Wiley, New York, 1986, 305.
S. U. Pedersen and B. Svensmark, Acta Chem. Scand., 1986, 9, 607.
P. W. Jolly and G. Wilke, The Organic Chemistry of Nickel. Part 2. Organic Synthesis, Academic Press, New York, 1975, 416 pp.
G. Shiavon, G. Bontempelli, and B. Corain, J. Chem. Soc., Dalton Trans., 1981, 5, 1074.
M. Durandetti, M. Devaud, and J. Perichon, New J. Chem., 1996, 20, 659.
C. Amatore and A. Jutand, Organometallics, 1988, 7, 2203.
C. Amatore, A. Jutand, and L. Mottier, J. Electroanal. Chem., 1991, 306, 125.
C. Amatore, A. Jutand, and L. Mottier, J. Electroanal. Chem., 1991, 306, 141.
J. Chatt and B. L. Shaw, J. Chem. Soc., 1960, 4, 1718.
W. Kaim, Coord. Chem. Rev., 1987, 76, 187.
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Yakhvarov, D.G., Samieva, E.G., Tazeev, D.I. et al. The reactivity of 2,2"-bipyridine complexes in the electrochemical reduction of organohalides. Russian Chemical Bulletin 51, 796–804 (2002). https://doi.org/10.1023/A:1016024531639
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DOI: https://doi.org/10.1023/A:1016024531639