Skip to main content
Log in

Assessment of Contamination by Metals in Coastal Sediments from South East Coast of Tamil Nadu, India with Statistical Approach

  • Research Paper
  • Published:
Iranian Journal of Science and Technology, Transactions A: Science Aims and scope Submit manuscript

Abstract

This study was initiated to investigate the heavy metal contamination in coastal sediments from Pattipulam to Devanampattinam along the South East Coast of Tamil Nadu, India using EDXRF technique with statistical approach. The mean concentration of heavy metals in sediments is found to be in the sequence of Al > Ca > K > Fe > Mg > Ti > Ba > Mn > Zn > V > Cr > Ni > La > Pb > As > Cd > Co. The highest metal concentrations in sediments are found in Devaneri (DVN) and Thenpattinam (TPM) sites. The degree of contamination by heavy metals in sediments was assessed using enrichment factor (EF), geo-accumulation index (I geo), contamination factor (CF), and pollution load index (PLI). The results of contamination indices in heavy metals indicate that sediment is not polluted from anthropogenic activities. The natural or anthropogenic sources of heavy metals were determined using multivariate statistical techniques. The results of multivariate data analysis indicate that heavy metals in the sediments are natural origin. This study provides a better understanding of identification of metal pollution sources in the sediment samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Asante KA (2005) Distribution of trace elements in the environment. Case study in the East China Sea and Ghana. Doctoral dissertation, M.Sc Thesis, Graduate School of Agriculture, Ehime University, Matsuyama

  • Balls PW, Hull S, Miller BS, Pirie JM, Proctor W (1997) Trace metal in Scottish estuarine and coastal sediments. Mar Pollut Bull 34:42–50. doi:10.1016/S0025-326X(96)00056-2

    Article  Google Scholar 

  • Basaran AK, Aksu M, Egemen O (2009) Impacts of the fish farms on the water column nutrient concentrations and accumulation of heavy metals in the sediments in the eastern Aegean Sea (Turkey). Environ Monit Assess 162:439–451. doi:10.1007/s10661-009-0808-x

    Article  Google Scholar 

  • Bettinetti R, Giarei C, Provini A (2003) Chemical analysis and sediment toxicity bioassays to assess the contamination of the River Lambro (Northen Italy). Arch Environ Contam Toxicol 45:72–80. doi:10.1007/s00244-002-0126-6

    Article  Google Scholar 

  • Bogen J, Fergus T, Walling DE (2003) Erosion and sediment transport measurement in rivers: technological and methodological advances IAHS 283. IAHS Press, Wallingford, p 238. doi:10.1111/j.1365-2389.2004.0694h.x

    Article  Google Scholar 

  • Caeiro S, Costa MH, Ramos TB, Fernandes F, Silveira N, Coimbra A, Medeiros G, Painho M (2005) Assessing heavy metal contamination in Sado Estuary sediment: an index analysis approach. Ecol Indic 5:151–169. doi:10.1016/j.ecolind.2005.02.001

    Article  Google Scholar 

  • Chandramohan J, Chandrasekaran A, Senthilkumar G, ElangoG Ravisankar R (2016) Heavy metal assessment in sediment samples collected from Pattipulam to Dhevanampattinam along the East Coast of Tamil Nadu using EDXRF technique. J Heavy metal Toxic Dis 1:1–9

    Google Scholar 

  • Chandrasekaran A, Ravisankar R, HarikrishnanN SatapathyKK, Prasad MVR, Kanagasabapathy KV (2015) Multivariate statistical analysis of heavy metal concentration in soils of Yelagiri Hills, Tamil Nadu, India—spectroscopical approach. Spectrochim Acta Part A 137:589–600. doi:10.1016/j.saa.2014.08.093

    Article  Google Scholar 

  • Chapman PM (2000) The sediment quality triad: then, now and tomorrow. Int J Environ Pollut 13:351–356. doi:10.1504/IJEP.2000.002324

    Article  Google Scholar 

  • Chapman PM, Wang F, Janssen C, Persoone G, Allen HE (1998) Ecotoxicology of metals in aquatic sediments: binding and release, bioavailability, risk assessment, and remediation. Can J Fish Aquat Sci 55:2221–2243. doi:10.1139/cjfas-55-10-2221

    Article  Google Scholar 

  • Chatterjee MV, Silva Filho EV, Sarkar SK, Sella SM, Bhattacharya A, Satpathy KK, Prasad MV, Chakraborty S, Bhattacharya BD (2007) Distribution and possible source of trace elements in the sediment cores of a tropical macrotidal estuary and their ecotoxicological significance. Environ Int 33:346–356. doi:10.1016/j.envint.2006.11.013

    Article  Google Scholar 

  • Cheng H, Hu Y (2010a) China needs to control mercury emissions from municipal solid waste (MSW) incineration. Environ Sci Technol 44:7994–7995. doi:10.1021/es1030917

    Article  Google Scholar 

  • Cheng H, Hu Y (2010b) Lead (Pb) isotopic fingerprinting and its applications in lead pollution studies in China: a review. Environ Pollut 158:1134–1146. doi:10.1016/j.envpol.2009.12.028

    Article  Google Scholar 

  • Dai J, Song J, Li X, Yuan H, Li N, Zheng G (2007) Environmental changes reflected by sedimentary geochemistry in recent hundred years of Jiaozhou Bay, North China. Environ Pollut 145:656–667. doi:10.1016/j.envpol.2006.10.005

    Article  Google Scholar 

  • Dassenakis M, Scoullos M, Gaitis A (1997) Trace metals transport and behaviour in the mediterranean estuary of Acheloos River. Mar Pollut Bull 34:103–111. doi:10.1016/S0025-326X(96)00062-8

    Article  Google Scholar 

  • Fedo CM, Eriksson KA, Krogstad EJ (1996) Geochemistry of shales from the Archean (~3.0 Ga) Buhwa Greenstone Belt, Zimbabwe: implications for provenance and source-area weathering. Geochim Cosmochim Acta 60:1751–1763. doi:10.1016/0016-7037(96)00058-0

    Article  Google Scholar 

  • Forstner U, Salomons W (1980) Trace metal analysis on polluted sediments: part I: assessment of sources and intensities. Environ Technol 1:494–505. doi:10.1080/09593338009384006

    Article  Google Scholar 

  • Hakanson L (1980) An ecological risk index for aquatic pollution control. A sedimentological approach. Water Res 14:975–1001. doi:10.1016/0043-1354(80)90143-8

    Article  Google Scholar 

  • Håkanson L (1988) Metal monitoring in coastal environments. In: Seeliger U, Drude de Lacerda L, Patchineelam SR (eds) Metals in coastal environments of Latin America. Springer, Berlin, Heidelberg, pp 239–257. doi:10.1007/978-3-642-71483-2_21

    Chapter  Google Scholar 

  • Harami MR, Mahboudi A, Reaisi E, Ahmadi A (2003) The study of the causes of grain size variations toward downstream and source of fine grain sediments in the Khoshk River drainage basin in Shiraz. In: Proceeding of the 21st symposium on geosciences, geological survey of Iran 2003, pp 17–19

  • Hosono T, Su CC, Delinom R, Umezawa Y, Toyota T, Kaneko S, Taniguchi M (2011) Decline in heavy metal contamination in marine sediments in Jakarta Bay, Indonesia due to increasing environmental regulations. Estuar Coast Shelf Sci 92:297–306. doi:10.1016/j.ecss.2011.01.010

    Article  Google Scholar 

  • Islam MS, Tanaka M (2004) Impacts of pollution on coastal and marine ecosystems including coastal and marine fisheries and approach for management: a review and synthesis. Mar Pollut Bull 48:624–649. doi:10.1016/j.marpolbul.2003.12.004

    Article  Google Scholar 

  • Klein J (2002) Water pollution in the Accra-Tema Metropolitan Area. Source and impacts. Doctoral dissertation, M.Sc Thesis, Eindhoven University of Technology, Eindhoven

  • Larsen B, Jensen A (1989) Evaluation of the sensitivity of sediment stations in pollution monitoring. Mar Pollut Bull 20:556–560. doi:10.1016/0025-326X(89)90356-1

    Article  Google Scholar 

  • Long ER, Field LJ, MacDonald DD (1998) Predicting toxicity in marine sediments with numerical sediment quality guidelines. Environ Toxicol Chem 17:714–727. doi:10.1002/etc.5620170428

    Article  Google Scholar 

  • Macdonald DD, Carr RS, Calder FD, Long ER, Ingersoll CG (1996) Development and evaluation of sediment quality guidelines for Florida coastal waters. Ecotoxicology 5:253–278. doi:10.1007/BF00118995

    Article  Google Scholar 

  • MacDonald DD, Ingersoll CG, Berger TA (2000) Development and evaluation of consensus-based sediment quality guidelines for freshwater ecosystems. Arch Environ Contam Toxicol 39:20–31. doi:10.1007/s002440010075

    Article  Google Scholar 

  • Mendiguchia C, Moreno C, Manuel-Vez MP, Garcia-Vargas M (2006) Preliminary investigation on the enrichment of heavy metals in marine sediments originated from intensive aquaculture effluents. Aquaculture 254:317–325. doi:10.1016/j.aquaculture.2005.10.049

    Article  Google Scholar 

  • Millward GE, Moore RM (1982) The adsorption of Cu, Mn and Zn by iron oxyhydroxide in model estuarine solutions. Water Res 16:981–985. doi:10.1016/0043-1354(82)90032-X

    Article  Google Scholar 

  • Muller G (1979) Schwermetalle in den Sediment des Rheins. Veranderungen Seit 79:778–783

    Google Scholar 

  • Muohi AW, Onyari JM, Omondi JG, Mavuti KM (2003) Heavy metal distribution in surface sediments from Mtwapa and Shirazi creeks, Kenyan coast. Bull Environ Contam Toxicol 70:1220–1227. doi:10.1007/s00128-003-0112-3

    Article  Google Scholar 

  • Nath BN, Rao VP, Becker KP (1989) Geochemical evidence of terrigenous influence in deep-sea sediments up to 8°S in the Central Indian Basin. Mar Geol 87:301–313. doi:10.1016/0025-3227(89)90067-4

    Article  Google Scholar 

  • Nath BN, Kunzendorf H, Pluger WL (2000) Influence of provenance, weathering, and sedimentary processes on the elemental ratios of the fine-grained fraction of the bedload sediments from the Vembanad Lake and the adjoining continental shelf, southwest coast of India. J Sediment Petrol 70:1081–1094. doi:10.1306/100899701081

    Article  Google Scholar 

  • Nesbitt HW, Young GM, McLennan SM, Keays RR (1996) Effects of chemical weathering and sorting on the petrogenesis of siliciclastic sediments, with implications for provenance studies. J Geol 104:525–542

    Article  Google Scholar 

  • Rahman MA, Ishiga H (2012) Trace metal concentrations in tidal flat coastal sediments, Yamaguchi Prefecture, southwest Japan. Environ Monit Assess 184:5755–5771. doi:10.1007/s10661-011-2379-x

    Article  Google Scholar 

  • Ravisankar R, Chandrasekaran A, Kalaiarasi S, Eswaran P, Rajasekhar C, Vanasundari K, Athavale A (2011) Mineral analysis in beach rocks of Andaman Island, India by spectroscopic techniques. Arch Appl Sci Res 3:77–84

    Google Scholar 

  • Ravisankar R, Sivakumar S, Chandrasekaran A, Kanagasabapathy KV, Prasad MVR, Satapathy KK (2015) Statistical assessment of heavy metal pollution in sediments of east coast of Tamil Nadu using energy dispersive X-ray fluorescence spectroscopy (EDXRF). Appl Radiat Isot 102:42–47. doi:10.1016/j.apradiso.2015.03.018

    Article  Google Scholar 

  • Sakan SM, Dordevic DS, Manojlovic DD, Predrag PS (2009) Assessment of heavy metal pollutants accumulation in the Tisza river sediments. J Environ Manag 90:3382–3390. doi:10.1016/j.jenvman.2009.05.013

    Article  Google Scholar 

  • Santhiya G, Lakshumanan C, Jonathan MP, Roy PD, Navarrete-Lopez M, Srinivasalu S, Uma Maheswari B, Krishnakumar P (2011) Metal enrichment in beach sediments from Chennai Metropolis, SE coast of India. Mar Poll Bull 62:2537–2542. doi:10.1016/j.marpolbul.2011.08.019

    Article  Google Scholar 

  • Sinex SA, Helz GR (1981) Regional geochemistry of trace elements in Chesapeake Bay sediments. Environ Geol 3:315–323

    Article  Google Scholar 

  • Singh KP, Mohan D, Singh VK, Malik A (2005) Studies on distribution and fractionation of heavy metals in Gomti river sediments—a tributary of the Ganges, India. J Hydrol 312:14–27. doi:10.1016/j.jhydrol.2005.01.021

    Article  Google Scholar 

  • Suciu I, Cosma C, Todica M, Bolboaca SD, Jantschi L (2008) Analysis of soil heavy metal pollution and pattern in Central Transylvania. Int J Mol Sci 9:434–453. doi:10.3390/ijms9040434

    Article  Google Scholar 

  • Szefer P, Glasby GP, Pempkowiak J, Kaliszan R (1995) Extraction studies of heavy-metal pollutants in surficial sediments from the southern Baltic Sea off Poland. Chem Geol 120:111–126. doi:10.1016/0009-2541(94)00103-F

    Article  Google Scholar 

  • Tam NF, Wong YS (2000) Spatial variation of heavy metals in surface sediments of Hong Kong mangrove swamps. Environ Poll 110:195–205. doi:10.1016/S0269-7491(99)00310-3

    Article  Google Scholar 

  • Todd PA, Ong X, Chou LM (2010) Impacts of pollution on marine life in Southeast Asia. Biodivers Conserv 19:1063–1082. doi:10.1007/s10531-010-9778-0

    Article  Google Scholar 

  • Tomlinson DL, Wilson JG, Harris CR, Jeffrey DW (1980) Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index. Helgolander Meeresuntersuchungen 33:566–575. doi:10.1007/BF02414780

    Article  Google Scholar 

  • Turekian KK, Wedepohl KH (1961) Distribution of the elements in some major units of the Earth’s crust. Geol Soc Am Bull 72:175–192

    Article  Google Scholar 

  • Van de Guchte C (1992) The sediment quality triad: an integrated approach to assess contaminated sediments. In: Newman PJ, Piavaux MA, Sweeting RA (eds) River water quality, ecological assessment and control. Brussels, pp 417–423

  • Wenning RJ, Ingersoll CG (eds) (2002) Executive summary of the SETAC Pellston workshop on use of sediment quality guidelines and related tools for the assessment of contaminated sediments. Society of Environmental Toxicology and Chemistry (SETAC), Pensacola

  • Williams TM, Rees J, Kairu KK, Yobe AC (1996) Assessment of contamination by metals and selected organic compounds in coastal sediments and waters of Mombasa, Kenya. Technical Report W C-96-37, 85

Download references

Acknowledgements

We sincerely thank and show gratitude to Dr. K. K. Satpathy, Head, Environment and Safety Division, RSEG, EIRSG, Indira Gandhi Centre for Atomic Research (IGCAR), Kalpakkam-603 102 for giving permission to make use of EDXRF facility in RSEG and also our deep gratitude and thanks to Dr. M. V. R. Prasad, Head, EnSD, RSEG, IGCAR, Kalpakkam-603,102, India for his keen help and constant encouragements in EDXRF measurements. Our sincere thanks to Mr. K. V. Kanagasabapathy, Scientific Officer, RSEG, IGCAR for his technical help in EDXRF analysis.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. Ravisankar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chandramohan, J., Chandrasekaran, A., Jebakumar, J.P.P. et al. Assessment of Contamination by Metals in Coastal Sediments from South East Coast of Tamil Nadu, India with Statistical Approach. Iran J Sci Technol Trans Sci 42, 1989–2004 (2018). https://doi.org/10.1007/s40995-017-0167-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40995-017-0167-3

Keywords

Navigation