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A Detailed Laboratory Scale Feasibility Study of Recovering Metallic Iron and Chromium from Chromium Contaminated Soils

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Abstract

One of potential technologies applicable to chromium-contaminated soils is thermal treatment, for example, the vitrification. Literature showed the reduction of hexavalent to trivalent chromium at high temperature, thus converting highly toxic and water-soluble compound into less toxic and water-insoluble compound. At high temperature, such as that of vitrification, both iron and chromium oxides can experience stepwise reduction to potentially recyclable metallic iron and chromium under reducing environment. Hence the objective of this study is to investigate the feasibility to reduce iron oxides in chromium-contaminated soils. Using solid carbon as reducing agent, the reduction to metallic iron was observable at 1200 °C. At 1400 °C, the addition of 15 % carbon by weight is required for complete reduction. The reduction is very rapid at this temperature. The information on reduction at high temperature should prove useful in providing background information in thermal treatment and also the potential recycling of metal from contaminated soils.

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References

  1. Kamolpornwijit W, Meegoda JN, Hu Z (2007) Characterization of Chromite Ore Processing Residue. Journal of Hazardous, Toxic, and Radioactive Waste Management 114:234–239

    Article  Google Scholar 

  2. Kamolpornwijit W, Meegoda JN, Batagoda JH (2014) Engineering properties of chromium contaminated soils. Geotechnical Engineering Journal of the SEAGS & AGSSEA 46(4) December 2015 ISSN 0046-5828

  3. Dermatas D, Meng X (2003) Utilization of fly ash for stabilization/solidification of heavy metal contaminated soils. Eng Geol 70:377–394

    Article  Google Scholar 

  4. Di Palma L, Gueye MT, Petrucci E (2014) Hexavalent chromium reduction in contaminated soil: a comparison between ferrous sulphate and nanoscale zero-valent iron. J Hazard Mater 281:70–76

    Article  Google Scholar 

  5. Ballesteros S, Rincón JM, Rincón-Mora B, Jordán MM (2016) Vitrification of urban soil contamination by hexavalent chromium. J Geochem Expl

  6. Pisciella P, Crisucci S, Karamanov A, Pelino M (2001) Chemical durability of glasses obtained by vitrification of industrial wastes. Waste Manag 21:1–9

    Article  Google Scholar 

  7. Colombo P, Brusatin G , Bernardo E, Scarinci G (2003) Inertization and reuse of waste materials by vitrification and fabrication of glass-based products. Curr Opin Solid State Mater Sci 7:225–239

    Article  Google Scholar 

  8. Clark RP et al (1975) Thermo-analytical Investigation of CaCrO4. Thermochem Acta 33:141–445

    Article  Google Scholar 

  9. U.S. Environmental Protection Agency (USEPA) (1992) Vitrification technologies for treatment of hazardous and radioactive waste. Handbook EPA/625/R-92/022, Washington DC

  10. Meegoda JN, Partymiller K, Richards MK, Kamolpornwijit W, Librizzi W, Tate T, Noval BA, Mueller RT, Santora S (2000) Remediation of chromium contaminated soils—a pilot scale investigation. ASCE Pract Period Hazard Toxic Radioact Waste Manag 4(1):1–11

    Article  Google Scholar 

  11. Meegoda JN, Kamolpornwijit W, Vaccari D, Ezeldin A, Noval BA, Mueller RT, Santora S (1999) Remediation of chromium contaminated soils—a bench scale investigation. ASCE Pract Period Hazard Toxic Radioact Waste Manag 3(3):124–131

    Article  Google Scholar 

  12. Meegoda JN, Kamolpornwijit W, Charleston G (2000) Construction use of vitrified chromium contaminated soils. ASCE Pract Period Hazard Toxic Radioact Waste Manag 4(3):89–99

    Article  Google Scholar 

  13. Plescia P, Maccari D (1996) Recovering metals from red mud by thermal treatment and magnetic separation. JOM. 48:25–28

    Article  Google Scholar 

  14. Lopez FA, Medina F, Medina J, Palacios MA (1991) Process for recovery of non-ferrous metals from steel mill dusts involving palletizing and carbothermic reduction. Ironmak Steelmak 18(4):292–296

    Google Scholar 

  15. Bogdandy LV, Engell HJ (1971) The reduction of iron oxides. Springer, New York

    Book  Google Scholar 

  16. Davies MW, Hazeldean GSF, Smith PN (1973) Physical chemistry of process metallurgy, the Richardson conference

  17. Fortini OM, Fruehan RJ (2005) Rate of reduction of ore–carbon composites: part II. Modeling of reduction in extended composites. Metall Mater Trans 6:709

    Article  Google Scholar 

  18. Otsuka K, Kunii D (1969) Reduction of ferric oxide mixed with graphite particles. J Chem Eng Jpn 2(1):46–50

    Article  Google Scholar 

  19. Abraham MC, Ghosh G (1979) Kinetics of reduction of iron oxide by carbon. Iron-mak Steelmak 6(1):14–23

    Google Scholar 

  20. Sugata M, Sugiyamaand T, Kondo S (1974) Trans Iron Steel. Inst. Jpn 14(1974):89

    Google Scholar 

  21. Baldwin BG (1955) Formation and decomposition of hercynite (FeO.Al2O3). J Iron Steel Inst 179(30):142–146

    Google Scholar 

  22. Nasr MI, Omar AA, Khadr MH, El-Geassy AA (1994) Analysis of solid-state reduction of iron ore from a couple of experimental measurements. Scand J Metall 23:119–125

    Google Scholar 

  23. Sugata M, Sugiyama T, Kondo S (1974) Reduction of iron oxide contained in molten slags with solid carbon. Trans. Iron Steel Inst Jpn 14:88–95

    Google Scholar 

  24. El-Geassy AA (1996) Gaseous reduction of MgO-doped Fe2O3 compacts with carbon monoxide at 1173–1473. ISIJ Int 36(11):1328–1337

    Article  Google Scholar 

  25. El-Geassy AA (1998) Stepwise reduction of CaO and/or MgO doped-Fe2O3 compacts (hematite–wustite–iron transformation steps). Scand J Metall 27:205–213

    Google Scholar 

  26. Wei R, Cang DG, Zhang L, Bai Y (2015) Staged reaction kinetics and characteristics of iron oxide direct reduction by carbon. Int J Miner Metall Mater 22:1025–1032

    Article  Google Scholar 

  27. Lekatou A, Walker RD (1997) Effect of SiO2 addition on solid state reduction of chromite concentrate. Ironmak Steelmak 24(2):133–143

    Google Scholar 

  28. Holt JB (1967) Role of oxygen in solid-solid reactions, sintering and related phenomena. In: Proceedings of the international conference. University of Notre Dame. June, pp 169–190

  29. Story SR, Sarma B, Fruehan RJ, Cramb AW, Belton GR (1998) Reduction of FeO in smelting slags by solid carbon: re-examination of the influence of the gas-carbon reaction. Metall Mater Trans B 29(4):929–932

    Article  Google Scholar 

  30. Hauffe K (1967) Kinetics of compound formation in the solid state, sintering and related phenomena. In: Proceedings of the international conference. University of Notre Dame. June, pp 139–167

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Authors and Affiliations

  1. New Jersey Institute of Technology, Newark, NJ, 07102-1982, USA

    Jay N. Meegoda, Wiwat Kamolpornwijit & Janitha Hewa Batagoda

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  1. Jay N. Meegoda
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  2. Wiwat Kamolpornwijit
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  3. Janitha Hewa Batagoda
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Correspondence to Jay N. Meegoda.

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Meegoda, J.N., Kamolpornwijit, W. & Batagoda, J.H. A Detailed Laboratory Scale Feasibility Study of Recovering Metallic Iron and Chromium from Chromium Contaminated Soils. Indian Geotech J 47, 437–444 (2017). https://doi.org/10.1007/s40098-016-0208-4

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  • DOI: https://doi.org/10.1007/s40098-016-0208-4

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