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Solid phase extraction of trace amounts of Pb(II) in opium, heroin, lipstick, plants and water samples using modified magnetite nanoparticles prior to its atomic absorption determination

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Abstract

A new, simple, fast and reliable solid-phase extraction method has been developed for separation/preconcentration of trace amounts of Pb(II) using dithizone/sodium dodecyl sulfate-immobilized on alumina-coated magnetite nanoparticles, and its determination by flame atomic absorption spectrometry (FAAS) and graphite furnace atomic absorption spectrometry (GFAAS) after eluting with 4.0 mol L−1 HNO3. Optimal experimental conditions including pH, sample volume, eluent concentration and volume, and co-existing ions have been studied and established. Under the optimal experimental conditions, the preconcentration factor, detection limit, linear range and relative standard deviation of Pb(II) using FAAS technique were 280 (for 560 mL of sample solution), 0.28 ng mL−1, 1.4–70 ng mL−1 and 4.6% (for 10 ng mL−1, n = 10), respectively. These analytical parameters using GFAAS technique were 300 (for 600 mL of sample solution), 0.002 ng mL−1, 0.006–13.2 ng mL−1 and 3.1% (for 5 ng mL−1, n = 10), respectively. The presented procedure was successfully applied for determination of Pb(II) content in opium, heroin, lipstick, plants and water samples.

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Acknowledgments

The authors would like to express their appreciations to Professor Afsaneh Safavi for her valuable discussion and useful suggestions. This research was supported by the Nanoscience and Nanotechnology Research Laboratory (NNRL) of Payame Noor University of Sirjan.

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Authors and Affiliations

  1. Payame Noor University, 19395-4697, Tehran, Iran

    Mohammad Ali Karimi, Abdolhamid Hatefi-Mehrjardi, Sayed Zia Mohammadi, Alireza Mohadesi & Asghar Askarpour Kabir

  2. Department of Chemistry and Nanoscience and Nanotechnology Research Laboratory (NNRL), Payame Noor University (PNU), Sirjan, Iran

    Mohammad Ali Karimi, Abdolhamid Hatefi-Mehrjardi & Asghar Askarpour Kabir

  3. Department of Chemistry, Payame Noor University (PNU), Kerman, Iran

    Sayed Zia Mohammadi & Alireza Mohadesi

  4. Department of Chemistry, Faculty of Sciences, Yazd University, Yazd, Iran

    Mohammad Mazloum-Ardakani

  5. Institute for Nanoscience and Nanotechnology, Sharif University of Technology, Tehran, Iran

    Mohammad Reza Hormozi Nezhad

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  1. Mohammad Ali Karimi
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Correspondence to Mohammad Ali Karimi.

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Karimi, M.A., Hatefi-Mehrjardi, A., Mohammadi, S.Z. et al. Solid phase extraction of trace amounts of Pb(II) in opium, heroin, lipstick, plants and water samples using modified magnetite nanoparticles prior to its atomic absorption determination. J IRAN CHEM SOC 9, 171–180 (2012). https://doi.org/10.1007/s13738-011-0035-6

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