Abstract
The hydrochemistry of a perennial river has been investigated with multivariate cluster analysis (CA) and principal component analysis/factor analysis (PCA/FA). The aim was to investigate parameters responsible for spatial and temporal variations of river water quality. Water quality was monitored along the river basin at 20 different sites over a period of 1 year from July, 2008 to June, 2009. Multivariate statistics revealed that Ca2+, Mg2+, Na+, K+, HCO3 −, Cl−, H4SiO4, SO4 2−, NO2 −, and PO4 3− were influenced by seasonal and spatial variations and that water quality was in the first place determined more by natural weathering processes than by anthropogenic activities. We could prove by (a) Box and Whisker plot, (b) matrix scatter score mean plot, (c) ternary plot, and (d) Gibbs plot that the chemistry of river water is controlled by lithogenic weathering processes. The higher concentration of dissolved silica during summer and the pre-monsoon season is explained by natural and tropical climatic conditions of the environment.
Similar content being viewed by others
References
Akbal F, Gurel L, Bahadır T, Guler I, Bakan G, Buyugungor H (2011) Water and sediment quality assessment in the mid-Black Sea coast of Turkey using multivariate statistical techniques. Environ Earth Sci 64:1387–1395
Anderberg MR (1973) Cluster analysis for applications. Academic Press, New York
APHA (2005) Standard methods for the examination of water and wastewater, 21st edn. APHA, Washington, DC
Arunkumar RX, Giridharan L, Shyamala J, Velmurugan PM, Jayaprakash M (2012) Geochemical assessment of ground water quality in Cuddalore, Tamil Nadu, southeast coast of India. World Appl Sci J 17(8):1033–1039
Balasubramanian A, Sharma KK, Sastri JCV (1985) Geological and hydrogeochemical evolution of coastal aquifers of Tamiraparani basin, Tamil Nadu. Geophysic Res Bull 23:203–206
Berner EK, Berner RA (1987) The global water cycle: geochemistry and environment. Prentice Hall, Englewood Cliffs, p 397
Berner EK, Berner RA (1996) Global environment: water, air and geochemical cycles. Prentice Hall, Englewood Cliffs
Bluth GJS, Kump LR (1994) Lithologic and climatologic controls of river chemistry. Geochim Cosmochim Acta 58(10):2341–2359
Bureau of Indian Standards (2004) Indian standard drinking water specification, IS10500, second revision, DOC:CHD 13 (1183)F, ICS No. 13.060.20
Chakrapani GJ, Subramanian V (1990) Preliminary studies on the geochemistry of the Mahanadi river basin, India. Chem Geol 81:241–253
Chatterjee SK, Bhattacharjee I, Chandra G (2010) Water quality assessment near an industrial site of Damodar river, India. Environ Monitor Assess 161:177–189
Datta DK, Subramanian V (1998) Distribution and fractionation of heavy metals in the surface sediments of the Ganges–Brahmaputra–Meghna river system in the Bengal basin. Environ Geol 36:93–102
Drever JI (1988) The Geochemistry of natural waters, 2nd edn. Prentice Hall, Englewood Cliffs
Everitt B (1993) Cluster analysis, 3rd edn. Halsted Press, Division of Wiley, New York
Gaillardet J, Dupré B, Allègre CJ, Négrel P (1997) Chemical and physical denudation in the Amazon river basin. Chem Geol 142:141–173
Garrels RM, Mackenzie FT (1971) Gregor’s denudation of the continents. Nature 231(5302):382–383
Garrels RM, Mackenzie FT, Hunt C (1975) Chemical cycle and the global environment. William Kaufman, New York
Gaur VK, Gupta SK, Pandey SD, Gopal K, Misra V (2005) Distribution of heavy metals in sediment and water of river Gomti. Environ Monitor Assess 102:1–3
Gibbs RJ (1970) Mechanism controlling world water chemistry. Science 17:1088–1090
Guler C, Thyne G, McCray JE, Turner AK (2002) Evaluation and graphical and multivariate statistical methods for classification of water chemistry data. Hydrogeol J 10:455–474
Guo H, Wang Y (2004) Hydrogeochemical processes in shallow quaternary aquifers from the northern part of the Datong basin, China. Appl Geochem 19:19–27
Gupta LP, Subramanian V (1994) Environmental geochemistry of Gomti river: a tributary of the Ganges river. Environ Geol 24:235–243
Helena B, Pardo R, Vega M, Barrado E, Fernandez JM, Fernandez L (2000) Temporal evolution of groundwater composition in an alluvial aquifer (Pisuerga river, Spain) by principal components analysis. Water Res 34:807–816
Horowitz AJ (1997) Some thoughts on problems associated with various sampling media used for environmental monitoring. Analyst 122:1193–1200
Ittekkot V, Subramanian V (1999) Human impact on the biogeochemistry of rivers: an introduction. In: Biogeochemistry of rivers in tropical South and South East Asia, SCOPE, Sonderband vol 82, pp 1–5
IWS (1988) Water research management studies in Tamil Nadu, final project report UND-CTD, technical report IWSIB5101. Institute for Water Studies, Public Works Department, Government of Tamil Nadu, Chennai
Jonathan MP, Roy PD, Rodrı′guez-Espinosa PF, Sarkar SK, Mun˜oz-Sevilla NP, Navarrete-Lo′pez M, Srinivasalu S, Thangadurai N (2012) Evaluation of trace element concentration (acid leachable) in sediments from River Pa′nuco and its adjacent lagoon areas, NE Me′xico. Environ Earth Sci 68:2239–2252
Kannel PR, Seockhoen L, Kanel SR, Khan SP, Lee YS (2007) Spatial–temporal variation and comparative assessment of water qualities of urban river system: a case study of the river Bagmati (Nepal). Environ Monitor Assess 129:433–459
Karaca M, Deniz A, Tayanc M (2000) Cyclone track variability over Turkey in association with regional climate. Int J Climatol 20:122–136
Koklu R, Sengorur B, Topal B (2010) Water quality assessment using multivariate statistical methods—a case study: Melen river system (Turkey). Water Resour Manage 24:959–978
Krishnaswami S, Singh SK (2005) Chemical weathering in the river basins of the Himalaya, India. Current Sci 89(5):841–849
Kumarasamy P, Govindaraj S, Vignesh S, Babu Rajendran R, Arthur James R (2012) Anthropogenic nexus on organochlorine pesticide pollution: a case study with Tamiraparani river basin, south India. Environ Monitor Assess 184:3861–3873
Meybeck M (1979) Dissolved load of world rivers. Rev Geol Dynasty Geogr Phys 21:215–246
Meybeck M (1987) Global chemical weathering of surficial rocks estimated from river dissolved load. Am J Sci 287:401–428
Naidu AS, Mowatt TC, Somayajulu BLK, Rao KS (1985) Characteristics of clay minerals in the bed loads of major rivers in India. SCOPE/UNEP, Hamburg, pp 559–569
Ohrui K, Mitchell MJ (1998) Stream water chemistry in Japanese watersheds and its variability on a small regional scale. Water Resour Res 34:1553–1561
Ramanathan AL, Vaithyanathan P, Subramanian V, Das BK (1994) Nature of solute load from Cauvery river, south India. Water Res 28:1585–1593
Ramesh R, Anbu M (1996) Chemical methods for environmental analysis. Macmillan India Ltd, Chennai, p 210
Ravichandran S (2003) Hydrological influences on the water quality trends in Tamiraparani basin, south India. Environ Monitor Assess 87:293–309
Ravichandran S, Ramanibai R, Pundarikanthan (1995) Ecoregions for describing water quality patterns in Tamiraparani basin, south India. J Hydrol 178:257–276
Ray SB, Mohanti M, Somayajulu BLK (1984) Suspended matter, major cations and dissolved silicon in the estuarine waters of the Mahanadi river, India. J Hydrol 69:183–196
Raymahasay BC (1987) A comparative study of clay minerals for pollution control. J Geol Soc India 30:408–413
Riedel GF, Tvvilliams SA, Riedel GS, Oilmour CC, Sanders JG (2000) Temporal and spatial patterns of trace elements in the Patuxent river: a whole watershed approach. Estuaries 23:521–535
Rode M, Suhr U (2007) Uncertainties in selected river water quality data. Hydrol Earth Syst Sci 11:863–874
Ruiz F, Gomis V, Blasco P (1990) Application of factor analysis to the hydrogeochemical study of a coastal aquifer. J Hydrol 119:169–177
Sarin MM, Krishnaswamy S, Dilli K, Somayajulu BLK, Moore WS (1989) Major ion chemistry of the Ganges-Brahmaputra river system, weathering process, fluxes to the Bay of Bengal. Geochim Cosmochim Acta 53:997–1009
Shah AB, Shah VA, Mistry BC, Navik AJ (2013) Assessment of heavy metals in sediments near Hazira industrial zone at Tapti river estuary, Surat, India. Environ Earth Sci. doi:10.1007/s12665-012-2066-4
Shin JY, Artigas F, Hobble C, Lee YS (2013) Assessment of anthropogenic influences on surface water quality in urban estuary, northern New Jersey: multivariate approach. Environ Monitor Assess 185:2777–2794
Singh M, Singh AK (2007) Bibliography of environmental studies in natural characteristics and anthropogenic influences on the Ganga river. Environ Monitor Assess 129:421–432
Stallard RF, Edmond LM (1983) Geochemistry of the Amazon, 2: the influence of geology and weathering environment on the dissolved load. J Geophys Res 88:9671–9688
Subramanian V (1987) Environmental geochemistry of Indian river basins: a review. J Geol Soc India 29:205–220
Subramanian V, Biksham G, Ramesh R (1987) Environmental geology of peninsular river basin of India. J Geol Soc India 30:393–401
Varol M, Gökot B, Bekleyen A, Şen B (2012) Water quality assessment and apportionment of pollution sources of Tigris river (Turkey) using multivariate statistical techniques—a case study. River Res Appl 28:1428–1438
Vieira JS, Pires JCM, Martins FG, Vilar VJP, Boaventura RAR, Botelho CMS (2012) Surface water quality assessment of Lis river using multivariate statistical methods. Water Air Soil Pollut 223:5549–5561
Vignesh S, Muthukumar K, Santhosh Gokul M, James RA (2013) Microbial pollution indicators in the Cauvery river, southern India. In: Ramkumar M (ed) On a sustainable future of the earth’s natural resources. Springer Earth System Sciences, pp 363–376. doi:10.1007/978-3-642-32917-3
Wan J, Bu H, Zhang Y (2013) Classification of rivers based on water quality assessment using factor analysis in Taizi River basin, northeast China. Environ Earth Sci. doi:10.1007/s12665-012-1976-5
Wunderlin DA, Diaz MP, Ame MV, Pesce SF, Hued AC, Bistoni MA (2001) Pattern recognition techniques for the evolution of spatial and temporal variations in water quality. A case study: Suquia river basin (Cordoba-Argentina). Water Res 35:2881–2894
Yao W, Xu J (2013) Impact of human activity and climate change on suspended sediment load: the upper Yellow river, China. Environ Earth Sci. doi:10.1007/s12665-013-2223-4
Yerel S, Ankara H (2012) Application of multivariate statistical techniques in the assessment of water quality in Sakarya river, Turkey. J Geol Soc India 79:89–93
Yidana SM, Ophoria D, BanoengYakubob B (2008) A multivariate statistical analysis of surface water chemistry data the Ankobra basin, Ghana. J Environ Manage 86:80–87
Zhang J (1995) Geochemistry of trace metals from Chinese river/estuary systems: an overview. Estuar Coast Shelf Sci 41:631–658
Zhang J, Huang WW, Li L, Zhou Q (1990) Drainage basin weathering and major element transport in two large Chinese rivers, (Huanghe and Chanjiang). J Geophy Res 95:13277–13288
Acknowledgments
The first authors would like to thank the University Grants Commission (UGC) and Department of Science and Technology (DST) for financial assistance.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Kumarasamy, P., Arthur James, R., Dahms, HU. et al. Multivariate water quality assessment from the Tamiraparani river basin, Southern India. Environ Earth Sci 71, 2441–2451 (2014). https://doi.org/10.1007/s12665-013-2644-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12665-013-2644-0