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Average and core silver content of ancient-debased coins via neutron diffraction and specific gravity

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Abstract

The measurement of the fineness of debased ancient silver coins has proven to be a very difficult issue, which has been studied for a long time. In this paper, this subject is analysed, and the various consequences of the silver surface enrichment (SSE) are discussed exploiting the most recent investigations. A new model is proposed for the complex object that is an ancient-debased silver coin, based on the silver profiles measured on some sectioned specimens. The model is applied to a sample of 43 coins, mainly Roman victoriati, Cisalpine and Illyrian drachms (from late III to I century B.C.). The coins are investigated in two different ways: neutron diffraction (ND) and specific gravity (SG). The results of the two measurements are combined via the proposed model to provide a more complete numismatic information of the original fineness of the monetary alloy. As a result, a relation between SSE thickness and SG is derived, which, for these coinages, allows to estimate the original alloy silver content from a simple SG measurement; the same method can be used to study other debased coinages, provided that all the procedure (ND and SG) is applied.

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References

  • Ager FJ, Moreno-Suárez AI, Scrivano S, Ortega-Feliu I, Gómez-Tubío B, Respaldiza MA (2013) Silver surface enrichment in ancient coins studied by micro-pixe. Nucl Inst Methods Phys Res B 306:241–244

    Article  Google Scholar 

  • Angelini I, Barello F, Barzagli E, Corsi J, Debernardi P, Lo Giudice A (2013) Monetazione preromana dell’Italia settentrionale e vittoriati: Analisi per diffrazione neutronica. Quaderni della Soprintendenza archeologica del Piemonte 28:331–333

    Google Scholar 

  • Arles A, Téreygeol F. (2011) Études des structures et des objets liés à la fabrication de la monnaie. L’atelier monétaire royal de La Rochelle (eds P. Mille & F. Téreygeol), pp. 83–141. Rennes

  • Beck L, Bosonnet S, Réveillon S, Eliot D, Pilon F (2004) Silver surface enrichment of silver–copper alloys: a limitation for the analysis of ancient silver coins by surface techniques. Nucl Inst Methods Phys Res B 226:153–162

    Article  Google Scholar 

  • Blet-Lemarquand M, Sarah G, Gratuze B, Barrandon JN (2009) Nuclear methods and Laser Ablation Inductively Coupled Plasma Mass Spectrometry: how can these methods contribute to the study of ancient coinage? Cercetări Numismatice, XV, 43–56

  • Breda M, Canovaro C, Pérez AFM, Calliari I (2012) From coin to medal: a metallurgical study of the brazing drop on a nineteenth century scudo. Journal of the Minerals, Metals & Materials Society 64:1350–1355

    Article  Google Scholar 

  • Bugoi R, Constantinescu B, Constantin F, Catana D, Plostinaru D, Sasianu A (1999) Archaeometrical studies of Greek and roman silver coins. J Radioanal Nucl Chem 242(3):777–781

    Article  Google Scholar 

  • Butcher K, Ponting M (2015) The metallurgy of roman silver coinage: from the reform of Nero to the reform of Trajan. Cambridge University Press, Cambridge

    Google Scholar 

  • Caley ER (1949) Validity of the specific gravity method for the determination of the fineness of gold objects. The Ohio Journal of Science 49(2):73–81

    Google Scholar 

  • Caley ER (1950) Notes on the chemical composition of Parthian coins with special reference to the drachms of Orodes I. The Ohio Journal of Science 50(3):107–120

    Google Scholar 

  • Calliari I, Canovaro C, Asolati M, Saccocci A, Grazzi F, Scherillo A (2013) Orio Malipiero’s and Enrico Dandolo’s denarii: surface and bulk characterization. Applied Physics A 113:1081–1087

    Article  Google Scholar 

  • Canovaro C, Calliari I, Asolati M, Grazzi F, Scherillo A (2013) Characterization of bronze roman coins of the fifth century called nummi through different analytical techniques. Applied Physics A 113:1019–1028

    Article  Google Scholar 

  • Condamin J, Picon M (1972) Changes suffered by coins in the course of time and the influence of these on the results of a different methods of analysis. In : Methods of chemical and metallurgical investigation of ancient coinage - a symposium held by the Royal Numismatic Society in London on 9–11 December 1970. Royal Numismatic Society, London

  • Cope LH (1972) Surface-silvered ancient coins. Methods of Chemical and Metallurgical Investigation of Ancient Coinage (London, 9–11 December 1970) (eds E.T. Hall & D.M. Metcalf), pp. 261–278. London

  • Corsi J (2015) Multi-technique study of coins circulating in northern Italy between 4th and first century B.C., PhD thesis in Scienza e Alta Tecnologia, Università di Torino, ciclo XXVII, January 2015

  • Corsi J, Grazzi F, Lo Giudice A, Re A, Scherillo A, Angelici D, Allegretti S, Barello F (2016a) Compositional and microstructural characterization of Celtic silver coins from northern Italy using neutron diffraction analysis. Microchem J 126:501–508

    Article  Google Scholar 

  • Corsi J, Lo Giudice A, Re A, Agostino A, Barello F (2016b) Potentialities of X-ray fluorescence analysis in numismatics: the case study of pre-roman coins from cisalpine Gaul. Archaeol Anthropol Sci. doi:10.1007/s12520-016-0371-7

    Google Scholar 

  • Corsi J, Maróti B, Re A, Kasztovszky Z, Szentmiklósi L, Torbágyi M, Agostino A, Angelici D, Allegretti S (2015) Compositional analysis of a historical collection of cisalpine Gaul’s coins kept at the Hungarian National Museum. J Anal At Spectrom 30(3):730–737

    Article  Google Scholar 

  • Cowell MR, Ponting M (2000) British Museum Analyses. In: Metallanalytische Untersuchungen an Münzen der Römischen Republik, Berliner Numismatische Forschungen, Neue Folge Band 6, Gebr. Mann Verlag, Berlin 2000:49–54

    Google Scholar 

  • Crawford MH (1974) Roman Republican Coinage = RRC. Cambridge University Press, Cambridge

    Google Scholar 

  • Debernardi P (2008a) An investigation about the physical properties in the Roman Republican coinage: Part I– weights, The Celator, February 2008

  • Debernardi P (2008b) An investigation about the physical properties in the Roman Republican coinage: Part II– silver contents, The Celator, March 2008

  • Durisi EA, Visca L, Albertin F, Brancaccio R, Corsi J, Dughera G, Ferrarese W, Giovagnoli A, Grassi N, Grazzi F, Lo Giudice A, Mila G, Nervo M, Pastrone N, Prino F, Ramello L, Re A, Romero A, Sacchi R, Salvemini F, Scherillo A, Staiano A (2013) Characterization of a neutron imaging setup at the INES facility. Nucl Inst Methods Phys Res A 726:31–36

    Article  Google Scholar 

  • Fabretti A, Ross F, Lanzone RV (1881) Regio Museo di Torino. Monete consolari e imperiali.

  • Gore DB, Davis G (2016) Suitability of transportable EDXRF for the on-site assessment of ancient silver coins and other silver artifacts. Appl Spectrosc 70(5):840–851

    Article  Google Scholar 

  • Grazzi F, Celli M, Siano S, Zoppi M (2007) Preliminary results of the Italian neutron experimental station INES at ISIS: archaeometric applications. Il Nuovo Cimento C 30:59–65

    Google Scholar 

  • Guerra MF, Barrandon JN (1998) Ion beam activation analysis with a cyclotron. Metallurgy in Numismatics 4:15–34

    Google Scholar 

  • Imberti S, Kockelmann W, Celli M, Grazzi F, Zoppi M, Botti A, Sodo A, Leo Imperiale M, de Vries-Melein M, Visser D, Postma H (2008) Neutron diffractometer INES for quantitative phase analysis of archaeological objects. Meas Sci Technol 19:034003

    Article  Google Scholar 

  • Kasztovszky Z, Panczyk E, Fedorowicz W, Révay Z (2005) Comparative archaeometrical study of roman silver coins by prompt gamma activation analysis and SEM-EDX. J Radioanal Nucl Chem 265(2):193–199

    Article  Google Scholar 

  • Kirfel A, Kockelmann W, Yule P (2011) Non-destructive chemical analysis of old south Arabian coins, fourth century BCE to third century CE. Archaeometry 53:930–949

    Article  Google Scholar 

  • Kockelmann W, Kirfel A, Jansen E, Linke R, Schreiner M, Traum R et al. (2003) Neutron diffraction for non-destructive texture analysis of minted and cast “Taler” coins. Numismatics & Technology: questions and answers (Wien, 25–26 April 2003) pp. 113–123

  • Kockelmann W, Pantos E, Kirfel A, (2000) Neutron and synchrotron radiation studies of archaeological objects. Radiation in Art and Archeometry, 347–377. Elsevier

  • Kockelmann W, Siano S, Bartoli L, Visser D, Hallebeek P, Traum R, Linke R, Schreiner M, Kirfel A (2006) Applications of TOF neutron diffraction in archaeometry. Applied Physics A 83:175–182

    Article  Google Scholar 

  • La Niece S (1993), Silvering. Metal Plating and Patination (eds P. Craddock & S. La Niece), pp. 201–209. Butterworth

  • Linke R, Schreiner M (2000) Energy dispersive X-ray fluorescence analysis and X-ray microanalysis of medieval silver coins an analytical approach for non-destructive investigation of corroded metallic artifacts. Microchim Acta 133:165–170

    Article  Google Scholar 

  • Mancini C (1984) Silver evaluation in roman republican victoriatus. Revue d’archéométrie 8:30–40

    Article  Google Scholar 

  • Mancini C (1985) Neutron and gamma ray transmission: methods and accuracy for the analysis of silver and gold alloys. The International Journal Of Applied Radiation And Isotopes 36(6):489–494

    Article  Google Scholar 

  • Moreno-Suárez AI, Ager FJ, Scrivano S, Ortega-Feliu I, Gómez-Tubío B, Respaldiza MA (2015) First attempt to obtain the bulk composition of ancient silver–copper coins by using XRF and GRT. Nucl Inst Methods Phys Res B 358:93–97

    Article  Google Scholar 

  • O’Dubhghaill C, Jones AH (2009) Japanese irogane alloys and patination. A study of production and application. Proceedings of the 23rd Santa Fe Symposium on Jewelry Manufacturing Technology (Albuquerque, May 17th–20th 2009) (ed E. Bell), pp. 289–324. Albuquerque

  • Oddy WA, Blackshaw SM (1974) The accuracy of the specific gravity method for the analysis of gold alloys. Archaeometry 16(1):81–90

    Article  Google Scholar 

  • Pautasso A (1966) Le Monete Preromane dell’Italia Settentrionale. Centro di Studi Preistorici e Archeologici di Varese, Varese

    Google Scholar 

  • Prause B (2000) Die Messung der Dichte der Silbermünzen, in Metallanalytische Untersuchungen an Muenzen der Romischen Republik, W. Hollstein ed., Berlin

  • Russo G (1996) Sulla tecnica di produzione del numerario in lega d’argento nel mondo antico e medievale. Rivista Italiana di Numismatica 47:167–181

    Google Scholar 

  • Sarah G (2008) Caractérisation de la composition et de la structure des alliages argent-cuivre par ICP-MS avec prélèvement par ablation laser. Application au monnayage carolingien. Chemical Sciences. Université d’Orléans, 2008. (https://tel.archives-ouvertes.fr/tel-00391932)

  • Sarah G, Gratuze B, Barrandon JN (2007) Application of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) for the investigation of ancient silver coins. J Anal At Spectrom 22:1163–1167

    Article  Google Scholar 

  • Serafin-Petrillo P (1976) Ripostigli monetali romano repubblicani sottoposti ad analisi per assorbimento neutronico, con strumentazione portatile. Archeologia Classica, XXVIII, 99–114

  • Walker DR (1976) The Metrology of the Roman Silver Coinage, Oxford 1976, pp. 77–78

  • Walker DR (1980) “The Silver Content of the Roman Republican Coinage”, in Metallurgy in Numismatics I, 1980, pp. 55–72

  • Willey DB, Pratt AS (2004) The minting of platinum Roubles: part III: the platinum Roubles of Johnson Matthey. Platin Met Rev 48(3):134–138

    Article  Google Scholar 

  • Woytek B, Uhlir K, Alram M, Schreiner M, Griesser M (2007) The denarius under Trajan: new metallurgical analyses. NC 167:147–163

    Google Scholar 

  • Xie Y, Lutterotti L, Wenk HR, Kovacs F (2004) Texture analysis of ancient coins with TOF neutron diffraction. J Mater Sci 39:3329–3337

    Article  Google Scholar 

  • Zwicker U, Oddy A, La Niece S (1993a) Roman techniques of manufacturing silver-plated coins. Metal Plating and Patination (eds P.T. Craddock & S. La Niece), pp. 223–246. Butterworth

  • Zwicker U (1993b) Metallographic and analytical investigation of silver and aes coinage of the Roman republic. Actes du XIe Congrès international de numismatique pp. 73–94

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Acknowledgements

The authors are grateful to the Science and Technology Facilities Council (Cooperation Agreement No. 06/20018 between CNR and STFC and INES BeamTime Application-RB1262011) for the beamtime allocation. Dr. Federico Barello is kindly acknowledged for allowing the measurements of the coins of the Museo di Antichità of Torino and for being available to carry them to the UK. P.D. thanks Dr. Ronaldo Bertozzi for donating to him the two sacrificial coins analysed both in this paper and in Moreno-Suárez et al. (2015). We thank Ana Isabel Moreno-Suárez for providing the Ag profiles of sample no. 2 and Mr. D. Hook for providing the SGs of three quadrigati of the British Museum Collection.

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Correspondence to Alessandro Re.

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Appendix

Fig. 11
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Images of the investigated coins; all details are provided in Table 1

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Debernardi, P., Corsi, J., Angelini, I. et al. Average and core silver content of ancient-debased coins via neutron diffraction and specific gravity. Archaeol Anthropol Sci 10, 1585–1602 (2018). https://doi.org/10.1007/s12520-017-0464-y

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