Abstract
In order to increase the durability of fuel cell stack, various operating technologies such as voltage cut-off and lean air operation was verified. With an application of upper voltage cut-off, cell performance loss was effectively diminished, which suggests that a formation of surface oxide layer on Pt was suppressed resulting in less irreversible catalyst deterioration such as Pt dissolution. In addition, it was found that voltage sweeping to lower reductive potential with a lean air supply was beneficial in preventing a power loss. With a simulated vehicle driving mode, it was confirmed that performance durability was 3 times improved with an application of both voltage cut-off and lean air supply which might be ascribed to the maintaining the electrochemical acive area of Pt catalyst. The suggested operating conditions based on Pt degradation mechanism will contribute the durability enhancement of fuel cell stack for FCEVs.
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Arisetty, S., Liu, Y., Gu, W. and Mathias, M. (2015). Modeling platinum oxide growth of PEMFC cathode catalysts. ECS Trans. 69, 17, 273–289.
Borup, R. L., Mukundan, R., Fairwether, J. D., Spernjak, D., Langlois, D. A., Davey, J. R., More, K. L. and Artyushkova, K. (2013). PEM fuel cell layer structure degradation during carbon corrosion. ECS Trans. 58, 1, 945–952.
Borup, R., Meyers, J., Pivovar, B., Kim, Y. S., Mukundan, R., Garland, N., Myers, D., Wilson, M., Garzon, R., Wood, D., Zeleny, P., More, K., Stroh, K., Zawodzinshi, T., Boncella, J., McGrath, J. E., Inaba, M., Miyatake, K., Hori, M., Ota, K., Ogumi, Z., Miyata, S., Nishikata, A., Siroma, Z., Uchimoto, Y., Kasuda, K., Kimijima, K. and Iwashita N. (2007). Scientific aspects of polymer electrolyte fuel cell durability and degradation. Chemical Reviews 107, 10, 3904–3951.
Casalongue, H. S., Kaya, S., Viswanathan, V., Miller, D. J., Friebel, D., Hansen, H. A., Norskov, J. K., Nilsson, A. and Ogasawara, H. (2013). Direct observation of the oxygenated species during oxygen reduction on a platinum fuel cell cathode. Nature Communications, 4, 2817–2822.
Choo, H.-S., Kinumoto, T., Jeong, S.-K., Iriyama, Y., Abe, T. and Ogumi, Z. (2007). Mechanism for electrochemical oxidation of highly oriented pyrolytic graphite in sulfuric acid solution. J. Electrochemical Society 154, 10, B1017–1023.
Choo, H.-S., Kinumoto, T., Nose, M., Miyazaki, K., Abe, T. and Ogumi, Z. (2008). Electrochemical oxidation of highly oriented pyrolytic graphite during potential cycling in sulfuric acid solution. J. Power Sources 185, 2, 740–746.
Ferreira, P. J., Ia O’, G. J., Shao-Horn, Y, Morgan, D., Makharia, R., Kocha, S. and Gasteiger, H. A. (2005). Instability of Pt/C electrocatalysts in proton exchange membrane fuel cells: A mechanistic investigation. J. Electrochemical Society 152, 11}, A2256–2271.
Inaba, M., Kinumoto, T., Kiriake, M., Umebayashi, R., Tasaka, A. and Ogumi, Z. (2006). Gas crossover and membrane degradation in polymer electrolyte fuel cells. Electrochimica Acta 51, 26, 5746–5753.
Jomori, S., Komatsubara, K., Nonoyama, N., Kato, M. and Yoshida, T. (2013). Experimental study of the activity change due to operation history in PEMFC. ECS Trans. 58, 1, 1457–1469.
Kinumoto, T., Takai, K., Iriyama, Y., Abe, T., Inaba, M. and Ogumi, Z. (2006). Stability of Pt-catalyzed highly oriented pyrolytic graphite against hydrogen peroxide in acid solution. J. Electrochemical Society 153, 1, A58–63.
Ohma, A., Shinohara, K., Iiyama, A., Yoshida, T. and Daimaru, A. (2011). Membrane and catalyst performance targets for automotive fuel cells by FCCJ membrane, catalyst, MEA WG. ECS Trans. 41, 1, 775–784.
Park, Y.-C., Kakinuma, K., Uchida, M., Uchida, H. and Watanabe, M. (2014). Deleterious effects of interim cyclic voltammetry on Pt/carbon black catalyst degradation during start-up/shutdown cycling evalution. Electrochimica Acta, 123, 84–92.
Qi, Z., Tang, H., Guo, Q. and Du, B. (2006). Investigation on “saw-tooth” behavior of PEM fuel cell performance during shutdown and restart cycles. J. Power Sources 161, 2, 864–871.
tStariha, S., Macauley, N., Sneed, B. T., Langlois, D., More, K. L., Mukundan, R. and Borup, R. L. (2018). Recent advances in catalyst accelerated stress tests for polymer electrolyte membrane fuel cells. J. Electrochemical Society 165, 7, F492–501.
Tang, H., Qi, Z., Ramani, M. and Elter, J. F. (2006). PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode. J. Power Sources 158, 2, 1306–1312.
Topalov, A. A., Cherevko, S., Zeradjanin, A. R., Meier, J. C., Katsounaros, I. and Mayrhofer, K. J. J. (2014). Toward a comprehensive understanding of platinum dissolution in acidic media. Chemical Science 5, 2, 631–638.
Xie, J., Wood III, D. L., More, K. L., Atanassov, P. and Borup, R. L. (2005a). Microstructural changes of membrane electrode assemblies during PEFC durability testing at high humidity conditions. J. Electrochemical Society 152, 5, A1011–1020.
Xie, J., Wood III, D. L., Wayne, D. M., Zawodzinski, T. A., Atanassov, P. and Borup, R. L. (2005a). Durability of PEFCs at high humidity conditions. J. Electrochemical Society 152, 1, A104–113.
Xing, L., Hossain, M. A., Tian, M., Beauchemin, D., Adjemian, K. T and Jerkiewicz, G. (2014). Platinum electro-dissolution in acdic media upon potential cycling. Electrocatalysis 5, 1, 96–112.
Zhang, X., Guo, L. and Liu, H. (2015). Recovery mechanisms in proton exchange membrane fuel cells after accelerated stress tests. J. Power Sources, 296, 327–334.
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Yang, S., Choi, S., Kim, Y. et al. Improvement of Fuel Cell Durability Performance by Avoiding High Voltage. Int.J Automot. Technol. 20, 1113–1121 (2019). https://doi.org/10.1007/s12239-019-0104-x
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DOI: https://doi.org/10.1007/s12239-019-0104-x