Skip to main content
Log in

Molecular physics and kinetics of high-temperature planetary atmospheres

  • Astrochemistry
  • Published:
Rendiconti Lincei Aims and scope Submit manuscript

Abstract

The space exploration is nowadays assisted by realistic modeling of re-entry conditions of space vehicles in planetary atmospheres, for the design of thermal protection systems. The detailed kinetic modeling relies on the accurate description of elementary process dynamics, including the role of the excitation of the internal degrees of freedom of chemical species. Efforts in the construction of a complete and consistent dynamical information are presented, focusing on hydrogen plasmas relevant to the Jupiter atmosphere. Examples of numerical experiments are given, emphasizing the relevance of the adopted state-to-state approach in reproducing the onset of non-equilibrium internal distributions governing the plasma system evolution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  • Adamson S, Astapenko V, Deminskii M, Eletskii A, Potapkin B, Sukhanov L, Zaitsevskii A (2007) Electron impact excitation of molecules: calculation of the cross section using the similarity function method and ab initio data for electronic structure. Chem Phys Lett 436(4–6):308–313

    Article  CAS  Google Scholar 

  • Borghi CA, Carraro MR, Cristofolini A, Veefkind A, Biagioni L, Fantoni G, Passaro A, Capitelli M, Colonna G (2006) Magneto-hydrodynamic interaction in the shock layer of a wedge in a hypersonic flow. IEEE Trans Plasma Phys 34(5):2450–2463

    Article  CAS  Google Scholar 

  • Bruno D, Capitelli M, Catalfamo C, Laricchiuta A (2007a) Transport of internal electronic energy in atomic hydrogen thermal plasmas. Phys Plasmas 14:072308

    Article  Google Scholar 

  • Bruno D, Laricchiuta A, Capitelli M, Catalfamo C (2007b) Effect of electronic excited states on transport in magnetized hydrogen plasma. Phys Plasmas 14:022303

    Article  Google Scholar 

  • Bruno D, Catalfamo C, Capitelli M, Colonna G, De Pascale O, Diomede P, Gorse C, Laricchiuta A, Longo S, Giordano D, Pirani F (2010) Transport properties of high-temperature Jupiter atmosphere components. Phys Plasmas 17(11):112315

    Article  Google Scholar 

  • Cacciatore M, Rutigliano M (2009) Dynamics of plasma-surface processes: E-R and L-H atom recombination reactions. Plasma Sources Sci Technol (Topical Review) 18:023002

    Article  Google Scholar 

  • Capitelli M, Gorse C (2005) Open problems in the physics of volume H/D sources. IEEE Trans Plasma Sci 33:1832

    Article  CAS  Google Scholar 

  • Capitelli M, Lamanna U (1974) Collision integrals of electronically excited states and transport coefficients of thermal plasmas. J Plasma Phys 12(01):71–79

    Article  Google Scholar 

  • Capitelli M, Gorse C, Longo S, Giordano D (2000) Collision integrals of high-temperature air species. J Thermophys Heat Transf 14(2):259–268

    Article  CAS  Google Scholar 

  • Capitelli M, Celiberto R, Gorse C, Laricchiuta A, Pagano D, Traversa P (2004) Transport properties of local thermodynamic equilibrium hydrogen plasmas including electronically excited states. Phys Rev E 69(2):026412/1–10

    Google Scholar 

  • Capitelli M, Colonna G, Giordano D, Marraffa L, Casavola A, Minelli P, Pagano D, Pietanza L, Taccogna F (2005) High-temperature thermodynamic properties of Mars-atmosphere components. J Spacecr Rockets 42(6):980–989

    Article  CAS  Google Scholar 

  • Capitelli M, Armenise I, Bruno D, Cacciatore M, Celiberto R, Colonna G, De Pascale O, Diomede P, Esposito F, Gorse C, Hassouni K, Laricchiuta A, Longo S, Pagano D, Pietanza D, Rutigliano M (2007a) Non-equilibrium plasma kinetics: a state-to-state approach. Plasma Sources Sci Technol 16:S30–S44

    Article  CAS  Google Scholar 

  • Capitelli M, Cappelletti D, Colonna G, Gorse C, Laricchiuta A, Liuti G, Longo S, Pirani F (2007b) On the possibility of using model potentials for collision integral calculations of interest for the planetary atmospheres. Chem Phys 338(1):62–68

    Article  CAS  Google Scholar 

  • Capitelli M, Celiberto R, Esposito F, Laricchiuta A (2009) Molecular dynamics for state-to-state kinetics of non-equilibrium molecular plasmas: state of art and perspectives. Plasma Process Polym 6:279–294

    Article  CAS  Google Scholar 

  • Catalfamo C, Bruno D, Colonna G, Laricchiuta A, Capitelli M (2009) High temperature Mars atmosphere. Part II. Transport properties. Eur Phys J D 54(3):613–621

    Article  CAS  Google Scholar 

  • Celiberto R, Lamanna U, Capitelli M (1998) Elastic, diffusion, and viscosity cross sections for collisions involving excited atomic hydrogen. Phys Rev A 58(3):2106–2114

    Article  CAS  Google Scholar 

  • Celiberto R, Janev R, Laricchiuta A, Capitelli M, Wadehra J, Atems D (2001) Cross section data for electron-impact inelastic processes of vibrationally excited molecules of hydrogen and its isotopes. Atomic Data Nucl Data Tables 77(2):161–213

    Article  CAS  Google Scholar 

  • Celiberto R, Janev R, Wadehra J, Laricchiuta A (2008) Cross sections for 11–14 eV e-H2 resonant collisions: vibrational excitation. Phys Rev A 77(1):012714/1–10

    Google Scholar 

  • Celiberto R, Janev R, Wadehra J, Laricchiuta A (2009) Cross sections for 14 eV e-H2 resonant collisions: dissociative electron attachment. Phys Rev A 80:012712

    Article  Google Scholar 

  • Colonna G, Capitelli M (2001a) The influence of atomic and molecular metastable states in high enthalpy nozzle expansion nitrogen flows. J Phys D Appl Phys 34:1812–1818

    Article  CAS  Google Scholar 

  • Colonna G, Capitelli M (2001b) Self-consistent model of chemical, vibrational, electron kinetics in nozzle expansion. J Thermophys Heat Transf 15:308–316

    Article  CAS  Google Scholar 

  • Colonna G, Capitelli M (2008) Boltzmann and master equations for mhd in weakly ionized gases. J Thermophys Heat Transf 22(3):414–423

    Article  CAS  Google Scholar 

  • Colonna G, Pietanza D, Capitelli M (2001) Coupled solution of a time-dependent collisional-radiative model and Boltzmann equation for atomic hydrogen plasmas: possible implication with libs plasmas. Spectrochim Acta B 56(6):587–598

    Article  Google Scholar 

  • Colonna G, Armenise I, Bruno D, Capitelli M (2006) Reduction of state-to-state kinetics to macroscopic models in hypersonic flows. J Thermophys Heat Transf 20(3):477–486

    Article  CAS  Google Scholar 

  • Colonna G, Pietanza LD, Capitelli M (2008) Recombination assisted nitrogen dissociation rates under nonequilibrium conditions. J Thermophys Heat Transf 22(3):399–406

    Article  CAS  Google Scholar 

  • Colonna G, D’Ammando G, Pietanza LD, Capitelli M (2011a) Radiation transfer, level and free-electron kinetics in non-equilibrium atomic hydrogen plasma. In: AIP conference proceedings of 27th international symposium on rarefied gas dynamics (in press)

  • Colonna G, Pietanza LD, D’Ammando G (2011b) Self-consistent collisional radiative models for hydrogen atoms: atom–atom interaction and radiation transport. Chem Phys (submitted)

  • Colonna G, Tuttafesta M, Capitelli M, Giordano D (1999) Non-Arrhenius NO formation rate in one-dimensional nozzle airflow. J Thermophys Heat Transf 13(3):372–375

    Article  CAS  Google Scholar 

  • Comer J, Read FH (1971) Potential curves and symmetries of some resonant states of \({\hbox{H}_2}^{-}.\)J Phys B 4(3):368

    Article  CAS  Google Scholar 

  • D’Ammando G, Pietanza L, Colonna G, Longo S, Capitelli M (2010) Modelling spectral properties of non-equilibrium atomic hydrogen plasma. Spectrochim Acta B 65:120–129

    Article  Google Scholar 

  • D’Angola A, Colonna G, Gorse C, Capitelli M (2008) Thermodynamic and transport properties in equilibrium air plasmas in a wide pressure and temperature range. Eur Phys J D 46(1):129–150

    Article  Google Scholar 

  • de Oliveira EM, Lima MAP, do N Varella MT (2008) Comparative study of electron and positron scattering by H2: the role of the \({{}^{2}\Upsigma}_{g}^{+}\) Feshbach resonance. Phys Rev A 78(4):042704

    Article  Google Scholar 

  • Esposito F, Capitelli M (2009) Selective vibrational pumping of molecular hydrogen via gas phase atomic recombination. J Phys Chem A 113(52):15307–15314

    Article  CAS  Google Scholar 

  • Esposito F, Gorse C, Capitelli M (1999) Quasi-classical dynamics calculations and state-selected rate coefficients for H + H2(v,j) → 3H processes: application to the global dissociation rate under thermal conditions. Chem Phys Lett 303:636–640

    Article  CAS  Google Scholar 

  • Ferziger JH, Kaper HG (1972) Mathematical theory of transport processes in gases. North-Holland, Amsterdam

    Google Scholar 

  • Josyula E, Bailey WF (2002) Vibrational relaxation and population depletion of nitrogen in hypersonic flows. AIAA 2002-0200

  • Laricchiuta A, Celiberto R, Esposito F, Capitelli M (2006) State-to-state cross sections for H2 and its isotopic variants. Plasma Sources Sci Technol 15(2):S62–S66

    Article  Google Scholar 

  • Laricchiuta A, Colonna G, Gorse C, Celiberto R, Pirani F, Capitelli M (2007) Classical transport collision integrals for a Lennard Jones like phenomenological model potential. Chem Phys Lett 445(4–6):133–139

    Article  CAS  Google Scholar 

  • Laricchiuta A, Bruno D, Capitelli M, Catalfamo C, Celiberto R, Colonna G, Diomede P, Giordano D, Gorse C, Longo S, Pagano D, Pirani F (2009a) High temperature Mars atmosphere. Part I: Transport cross sections. Eur Phys J D 54(3):607–612

    Article  CAS  Google Scholar 

  • Laricchiuta A, Pirani F, Colonna G, Bruno D, Gorse C, Celiberto R, Capitelli M (2009b) Collision integrals for interactions involving atoms in electronically excited states. J Phys Chem A 113(52):15250–15256

    Article  CAS  Google Scholar 

  • Pagano D, Gorse C, Capitelli M (2007) Modeling multicusp negative ion sources. IEEE Trans Plasma Sci 35:1247

    Article  CAS  Google Scholar 

  • Pagano D, Casavola A, Pietanza L, Colonna G, Giordano D, Capitelli M (2008) Thermodynamic properties of high-temperature Jupiter-atmosphere components. J Thermophys Heat Transf 22(3):434–441

    Article  CAS  Google Scholar 

  • Yoon JS, Song MY, Han JM, Hwang SH, Chang WS, Lee B, Itikawa Y (2008) Cross sections for electron collisions with hydrogen molecules. J Phys Chem Ref Data 37:913

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The research leading to these results has received funding from the European Community’s Seventh Framework Programme (FP7/2007-2013) under grant agreement n. 242311.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mario Capitelli.

Additional information

This paper is one of those collected in this issue and presented on the occasion of the symposium “Astrochemistry: molecules in space and time” (Rome, 4–5 November 2010), sponsored by Fondazione “Guido Donegani” and the Accademia Nazionale dei Lincei. Other 11 related papers and an Introduction to the whole series of papers on this topic were published in the previous issue of Rendiconti Lincei (Vol. 22-2, June 2011).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Capitelli, M., Bruno, D., Colonna, G. et al. Molecular physics and kinetics of high-temperature planetary atmospheres. Rend. Fis. Acc. Lincei 22, 201–210 (2011). https://doi.org/10.1007/s12210-011-0132-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12210-011-0132-6

Keywords

Navigation