Nano Express

Nanoscale Research Letters

, Volume 4, Issue 11, pp 1309-1314

Open Access This content is freely available online to anyone, anywhere at any time.

Study on Resistance Switching Properties of Na0.5Bi0.5TiO3 Thin Films Using Impedance Spectroscopy

  • Ting ZhangAffiliated withKey Laboratory of Photovoltaic Materials of Henan Province, School of Physics and Electronics, He’nan University
  • , Xinan ZhangAffiliated withKey Laboratory of Photovoltaic Materials of Henan Province, School of Physics and Electronics, He’nan University
  • , Linghong DingAffiliated withKey Laboratory of Photovoltaic Materials of Henan Province, School of Physics and Electronics, He’nan University
  • , Weifeng ZhangAffiliated withKey Laboratory of Photovoltaic Materials of Henan Province, School of Physics and Electronics, He’nan University Email author 

Abstract

The Na0.5Bi0.5TiO3 (NBT) thin films sandwiched between Au electrodes and fluorine-doped tin oxide (FTO) conducting glass were deposited using a sol–gel method. Based on electrochemical workstation measurements, reproducible resistance switching characteristics and negative differential resistances were obtained at room temperature. A local impedance spectroscopy measurement of Au/NBT was performed to reveal the interface-related electrical characteristics. The DC-bias-dependent impedance spectra suggested the occurrence of charge and mass transfer at the interface of the Au/NBT/FTO device. It was proposed that the first and the second ionization of oxygen vacancies are responsible for the conduction in the low- and high-resistance states, respectively. The experimental results showed high potential for nonvolatile memory applications in NBT thin films.

Keywords

Na0.5Bi0.5TiO3 (NBT) thin films Resistance switching Impedance spectroscopy Interfacial characteristics Oxygen vacancies