Abstract
The cementite dissolution behavior of a hypereutectoid high carbon chromium bearing steel has been studied using the theory of local equilibrium assumption at interface. The dissolution mode was established and the process was calculated using DICTRA software. Heat treatment was performed on DIL 805 formastor, and microstructure was observed by ZEISS-SUPRA-55 SEM. Fraction and size of cementite particles were counted by ImageJ software. The results indicate that dissolution rate of cementite is fast in the beginning and then becomes slowly when holding at 840, 860 and 880 °C respectively. The simulation results are in good agreement with statistical results of SEM graphs. The fast dissolution stage is controlled by diffusion of C atoms, and the subsequent sluggish stage is governed by diffusion of Cr. Microscopically, dissolution of cementite depends upon the temporary destruction and instant recovery of local equilibrium at austenite/cementite interface. Diffusion rate of carbon is high, leading to the rapid distribution between cementite and austenite. C content in austenite increases significantly with the holding time, while little change happens to Cr content. The increase of Cr content in cementite obviously enhances its stability and reduces subsequent dissolution rate.
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References
H.K.D.K. Bhadeshia, Steels for Bearings, Prog. Mater Sci., 2012, 57, p 268
A.T.W. Barrow and P.E.J. Rivera, Nanoprecipitation in Bearing Steels, Acta Mater., 2011, 59, p 7155
L.M. Lu, H. Soda, and A. Mclean, Microstructure and Mechanical Properties of Fe-Cr-C Eutectic Composites, Mater. Sci. Eng. A, 2003, 347, p 214
C.G. Andres, F.G. Caballero, C. Capdevila et al., Modelling of Kinetics and Dilatometric Behavior of Non-isothermal Pearlite-to-Austenite Transformation in an Eutectoid Steel, Scr. Mater., 1998, 39, p 791
M. Qian, In-Situ Observations of the Dissolution of Carbides in an Fe-Cr-C Alloy, Scr. Mater., 1999, 41, p 1301
J.H. Kang and P.E.J. Rivera, Carbide Dissolution in Bearing Steels, Comput. Mater. Sci., 2013, 67, p 364
C.M. Amey, H. Huang, and P.E.J. Rivera, Distortion in 100Cr6 and Nanostructured Bainite, Mater. Des., 2012, 35, p 66
G. Miyamoto, H. Usuki, Z.D. Li et al., Effects of Mn, Si and Cr Addition on Reverse Transformation at 1073K from Spheroidized Cementite Structure in Fe-0.6mass% C Alloy, Acta Mater., 2010, 58, p 4492
Y. Xia, M. Enomoto, Z.G. Yang et al., Effects of Alloying Elements on the Kinetics of Austenitization from Pearlite in Fe-C-M Alloys, Philos. Mag., 1095, 2013, p 93
G. Purdy, J. Argen, A. Borgenstam et al., Alemi: A Ten Year History of Discussions of Alloying Element Interactions with Migrating Interfaces, Metall. Mater. Trans. A, 2011, 42A, p 3703
M. Goune, F. Danoix, J. Agren et al., Overview of the Current Issues in Austenite to Ferrite Transformation and the Role of Migrating Interfaces Therein for Low Alloyed Steels, Mater. Sci. Eng. R, 2015, 92, p 1
G.H. Zhang, J.Y. Chae, K.H. Kim et al., Effects of Mn, Si and Cr Addition on the Dissolution and Coarsening of Pearlitic Cementite During Intercritical Austenitization in Fe-1mass%C Alloy, Mater. Charact., 2013, 81, p 56-67
J. Epp, H. Surm, O. Kessler et al., In Situ X-Ray Phase Analysis and Computer Simulation of Carbide Dissolution of Ball Bearing Steel at Different Austenitizing Temperatures, Acta Mater., 2007, 55, p 5959
W.W. Song, P.P. Choi, G. Inden et al., On the Spheroidized Carbide Dissolution and Elemental Partitioning in High Carbon Bearing Steel 100Cr6, Metall. Mater. Trans. A, 2014, 45(2), p 595-606
J.Y. Chae, J.H. Jang, G.H. Zhang et al., Dilatometric Analysis of Cementite Dissolution in Hypereutectoid Steels Containing Cr, Scr. Mater., 2011, 65, p 245
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Funded by the National High-tech Research and Development Program of China (2012AA03A508) and National Natural Science Foundation of China (51101048).
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Li, H., Zhang, H., Lv, Zf. et al. Cementite Dissolution Kinetics of High Carbon Chromium Steel During Intercritical Austenitization. J. Phase Equilib. Diffus. 38, 543–551 (2017). https://doi.org/10.1007/s11669-017-0548-5
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DOI: https://doi.org/10.1007/s11669-017-0548-5