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Optimization of Processing Parameters for WC-11Co Cemented Carbide Doped with Nano-Crystalline CeO2

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Abstract

Nine types of trace nano-CeO2-doped WC-11Co cemented carbides designed by orthogonal method were prepared. The variance analysis results show that the relative density increases with increasing sintering temperature in the range of 1400-1450 °C; the hardness is highly dependent on grain size of WC which is closely related to the particle size of the initial WC powder and grain refinement produced by nano-CeO2; the bending strength of WC-11Co cemented carbide with less than 0.15 wt.% of nano-CeO2 is effectively improved because of its effect on the decreasing of porosity and inhibiting the grain growth of WC and martensitic phase transformation of Co; the fracture toughness rises at the beginning then drops later if the particle size of initial WC powder is in the range of 3-11 μm.

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References

  1. M. Mahmoodan, H. Aliakbarzadeh, and R. Gholamipour, Microstructural and Mechanical Characterization of High Energy Ball Milled and Sintered WC-10 wt.%Co-xTaC Nano Powders, Int. J. Refract. Met. Hard Mater., 2009, 27, p 801–805

    Article  CAS  Google Scholar 

  2. F.A. Costa, F.F.P. Medeiros, A.G.P. Silva, U.U. Gomes, M. Filgueira, and C.P. Souza, Structure and Hardness of a Hard Metal Alloy Prepared with a WC Powder Synthesized at Low Temperature, Mater. Sci. Eng. A, 2008, 485, p 638–642

    Article  Google Scholar 

  3. S.X. Zhao, X.Y. Song, J.X. Zhang, and X.M. Liu, Effects of Scale Combination and Contact Condition of Raw Powders on SPS Sintered Near-Nanocrystalline WC-Co Alloy, Mater. Sci. Eng. A, 2008, 473, p 323–329

    Article  Google Scholar 

  4. Z.Z. Fang, X. Wang, T. Ryu, K.S. Hwang, and H.Y. Sohn, Synthesis, Sintering, and Mechanical Properties of Nanocrystalline Cemented Tungsten Carbide—A Review, Int. J. Refract. Met. Hard Mater., 2009, 27, p 288–299

    Article  CAS  Google Scholar 

  5. S.I. Cha, Hong SH, Ha G H, Kim B K. Microstructure and Mechanical Properties of Nanocrystalline WC-10Co Cemented Carbides, Scr. Mater., 2001, 44, p 1535–1539

    Article  CAS  Google Scholar 

  6. W.B. Liu, X.Y. Song, J.X. Zhang, F.X. Yin, and G.Z. Zhang, A Novel Route to Prepare Ultrafine-Grained WC-Co Cemented Carbides, J. Alloys Compd., 2008, 458, p 366–371

    Article  CAS  Google Scholar 

  7. D.D. Gu, Y.F. Shen, L. Zhao, J. Xiao, P. Wu, and Y.B. Zhu, Effect of Rare Earth Oxide Addition on Microstructures of Ultra-Fine WC-Co Particulate Reinforced Cu Matrix Composites Prepared by Direct Laser Sintering, Mater. Sci. Eng. A, 2007, 445-446, p 316–332

    Article  Google Scholar 

  8. D.H. Xiao, Y.H. He, W.H. Luo, and M. Song, Effect of VC and NbC Additions on Microstructure and Properties of Ultrafine WC-10Co Cemented Carbides, Trans. Nonferrous Met. Soc. China, 2009, 19, p 1520–1525

    Article  CAS  Google Scholar 

  9. L. Sha, Study on Rare-Earth Doped Cemented Carbides in China, Int. J. Refract. Met. Hard Mater., 2009, 27, p 528–534

    Article  CAS  Google Scholar 

  10. C.G. Lin, Action of New Rare Earth Additions in Cemented Carbide, J. Mater. Sci. Technol., 1993, 9(3), p 177–184

    CAS  Google Scholar 

  11. J. Xiong, J.G. Yang, and X.H. Guo, Application of Rare Earth Elements in Cemented Carbide Inserts, Drawing Dies and Mining Tools, Mater. Sci. Eng. A, 1996, 209(1-2), p 287–293

    Article  Google Scholar 

  12. Z. Yao, J.J. Stiglich, and T.S. Sudarshan, Nanosized WC-Co Holds Promise for the Future, Met. Powder Rep., 1998, 53(3), p 26–33

    Article  Google Scholar 

  13. S. Liu, Z.L. Huang, G. Liu, and G.B. Yang, Preparing Nano-Crystalline Rare Earth Doped WC-Co Powder by High Energy Ball Milling, Int. J. Refract. Met. Hard Mater., 2006, 24, p 461–464

    Article  CAS  Google Scholar 

  14. Y.X. Li, X.Z. Zhou, Y. Wang, and X. You, Preparation of Nano-Sized CeO2 by Mechanochemical Reaction of Cerium Carbonate with Sodium Hydroxide, Mater. Lett., 2004, 58, p 245–249

    Article  CAS  Google Scholar 

  15. M.S. Tsai, Powder Synthesis of Nano Grade Cerium Oxide Via Homogenous Precipitation and Its Polishing Performance, Mater. Sci. Eng. B, 2004, 110(2), p 132–134

    Article  Google Scholar 

  16. T. Mori, Y. Wang, J. Drennan, G. Auchterlonie, J.G. Li, and T. Ikegami, Influence of Particle Morphology on Nanostructural Feature and Conducting Property in Sm-Doped CeO2 Sintered Body, Solid State Ionics, 2004, 175, p 641–649

    Article  CAS  Google Scholar 

  17. M.G. Sujana, K.K. Chattopadyay, and S. Anand, Characterization and Optical Properties of Nano-Ceria Synthesized by Surfactant-Mediated Precipitation Technique in Mixed Solvent System, Appl. Surf. Sci., 2008, 254, p 7405–7409

    Article  CAS  Google Scholar 

  18. M.A. Xueming, J.I. Gang, Z. Ling, and D. Yuanda, Structure and Properties of Bulk Nano-Structured WC-CO Alloy by Mechanical Alloying, J. Alloys Compd., 1998, 264(1-2), p 267–270

    Article  CAS  Google Scholar 

  19. S. Liu, D.Q. Yi, Y.X. Li, and D. Zou, Preparation Nano-Crystalline La Doped WC/Co Powder by High Energy Ball-Milling, Acta Metall. Sin. (Engl. Lett.), 2002, 15(5), p 448–452

    CAS  Google Scholar 

  20. H. Ngqvist and N. Axen, Abrasion of Cemented Carbides by Small Grits, Tribol. Int., 1999, 32(9), p 527–534

    Article  Google Scholar 

  21. D. Sivaprahasam, S.B. Chandrasekar, and R. Sundaresan, Microstructure and Mechanical Properties of Nanocrystalline WC-12Co Consolidated by Spark Plasma Sintering, Int. J. Refract. Met. Hard Mater., 2007, 25, p 144–152

    Article  CAS  Google Scholar 

  22. K.H. Lee, J.W. Yi, and J.S. Park, An Optimization Algorithm Using Orthogonal Arrays in Discrete Design Space for Structures, Finite Elem. Anal. Des., 2003, 40, p 121–135

    Article  Google Scholar 

  23. Q.F. Pan, Effects of Rare Earth Oxides on the Properties of WC-Co Cemented Carbide, Rare Met. Mater. Eng., 1993, 22, p 40–41 ((in Chinese))

    Google Scholar 

  24. S.I. Cha, S.H. Hong, G.H. Ha, and B.K. Kim, Mechanical Properties of WC-10Co Cemented Carbides Sintered from Nanocrystalline Spray Conversion Processed Powders, Int. J. Refract. Met. Hard Mater., 2001, 19, p 397–403

    Article  CAS  Google Scholar 

  25. L. Zhang, S. Chen, X.J. Xiong, Y.H. He, B.Y. Huang, and C.F. Zhang, Phase Composition, Transition and Structure Stability of Functionally Graded Cemented Carbide with Dual Phase Structure, J. Cent. South Univ. Technol., 2007, 14, p 149–152

    Article  CAS  Google Scholar 

  26. C.H. Xu, X. Ai, and C.Z. Huang, Research and Development of Rare-Earth Cemented Carbides, Int. J. Refract. Met. Hard Mater., 2001, 19, p 159–168

    Article  CAS  Google Scholar 

  27. Z.Z. Fang, A. Griffo, B. White, G. Lockwood, D. Belnap, G. Hilmas, and J. Bitler, Fracture Resistant Super Hard Materials and Hardmetals Composite with Functionally Designed Microstructure, Int. J. Refract. Met. Hard Mater., 2001, 19, p 453–459

    Article  CAS  Google Scholar 

  28. L. Espie, B. Drevet, and N. Eustathopoulos, Experimental Study of the Influence of Interfacial Energies and Reactivity on Wetting in Metal/Oxide Systems, Metall. Mater. Trans. A, 1994, 25A, p 599–605

    Article  CAS  Google Scholar 

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Acknowledgments

This study was supported by the Program of Excellent Team at Harbin Institute of Technology.

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Correspondence to You Wang.

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Sun, X., Wang, Y., Peng, F. et al. Optimization of Processing Parameters for WC-11Co Cemented Carbide Doped with Nano-Crystalline CeO2 . J. of Materi Eng and Perform 22, 112–117 (2013). https://doi.org/10.1007/s11665-012-0236-x

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  • DOI: https://doi.org/10.1007/s11665-012-0236-x

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