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Skarn mineralogy and its geological significance for the Tayuan (Cu–Mo)–Pb–Zn deposit, northern Daxinganling metallogenic belt

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Abstract

The Tayuan (Cu–Mo)–Pb–Zn deposit is located in the northern part of Daxinganling, NE China. Lenticular ore body occurs in the skarn zone. The skarn minerals mainly include garnet, pyroxene, epidote and wollastonite. Electron microprobe analysis shows that the end member of garnet is mainly andradite (Ad62–97Gr11–45), the pyroxene is mainly diopside, and epidote is mainly clinozoisite. These characteristics indicate that the Tayuan polymetallic skarn deposit is mainly calcareous skarn. Sometimes the content zonation can be observed in garnets. With one garnet crystal, content is shifty from the core to the rim. In general, the iron content in the core is higher than in the edge. The content in the garnet shows that the garnet in the Tayuan deposit formed from weak oxidation in alkaline environment with the oxygen fugacity increasing, suggesting that the hydrothermal fluid evolved from an acidic to a slight alkaline state. In the Tayuan polymetallic deposit, the ratio of Mn/Fe in pyroxene is about 1.3, and of Mg/Fe, it is about 2. The components of garnet in the Tayuan deposit plot in the field of the typical skarn Zn, Cu, Mo deposits in the world.

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References

  • Chang YF, Liu XP, Wu YC (1991) The copper-iron metallogenic belt in the lower Yangtze region. Geology Publishing House, Beijing, pp 1–56

    Google Scholar 

  • Cheng YQ, Zhao YM (1994) China iron deposit. Geology Publishing House, Beijing, pp 386–479

    Google Scholar 

  • Crowe DE, Reciputi LR, Bezenek S, Ignatiev A (2001) Oxygen isotope and trace element zoning in hydrothermal garnets: windows into large-scale fluid flow behavior. Geology 29:479–482

    Article  Google Scholar 

  • Einaudi MT, Burt DM (1982) A special issue devoted to skarn deposits introduction erminology, classification and composition skarn deposits. Econ Geol 77(4):745–754

    Article  Google Scholar 

  • Einaudi MT, Meinert LD, Newberry RJ (1981) Skarn deposits. Econ Geol 75:317–391

    Google Scholar 

  • Gao X, Deng J, Meng JY, Yan H, Li JX (2014) Characteristics of garnets in Hongniu skarn type copper deposit. Acta Petrologica Sinica 9:2695–2708

    Google Scholar 

  • Ge WC, Wu FY, Zhou CY, Zhang JH (2005) Zircon U-Pb ages and its significance of the Mesozoic granites in the Wulanhaote region, central Da Hinggan Mountain. Acta Petrologica Sinica 3(21):749–762

    Google Scholar 

  • Ge WC, Wu FY, Zhou CY, Zhang JH (2007) The metallogenic epoch and geodynamic implication of porphyry-type Cu–Mo deposit in the eastern Xing-meng orogenic belt. Chin Sci Bull 52(20):2407–2417

    Google Scholar 

  • Holten T, Jamtveit B, Meakin P (2000) Noise and oscillatory zoning of minerals. Geochimica at Cosmochimica Acta 64:1893–1904

    Article  Google Scholar 

  • Huang JL, Zhao DP (2006) High-resolution mantle tomography of China and surrounding regions. J Geophys Res 10:1029–2005

    Google Scholar 

  • Isozaki Y (1997) Jurassic accretion tectonics of Japan. Island Arc 6:25–51

    Article  Google Scholar 

  • Jamtveit B, Wogelius RA, Fraser DC (1993) Zonation patterns of skarn garnets: records of hydrothermal system evolution. Geology 21(2):113–116

    Article  Google Scholar 

  • Kojima S (1987) Mesozoic terrane accretion in northeast China, Sikhote-Alin and Japan regions. Palaeogeogr Palaeoclimatol Palaeoecol 69:216–232

    Google Scholar 

  • Li ZZ, Qin KZ, Li GM, Ishihara Shunso, Jin LY (2014) Formation of giant Chalukou Porphy Mo deposit in northern great Xing’an Range, NE China: partial melting of the juvenile lower crust in intra-plate extensional environment. Lithos 202–203:138–141

    Article  Google Scholar 

  • Lin R (1995) The relationship between characteristics and metallogenic of garnet. Chem Miner Geol 17(2):118–122

    Google Scholar 

  • Lin WW, Zhao YM, Jiang CJ (1990) Characteristics of paragenetic clinopyro-xene-garnet pairs in skarn deposits and their geological significance. Miner Depos 3(9):195–207

    Google Scholar 

  • Liu J, Mao JW, Wu G, Luo DF, Wang F, Zhou ZH, Hu YQ (2013) Zircon U-Pb dating for the magmatic rocks in the chalukou porphyry Mo deposit in the northern great Xing’an range, China, and its geological significance. Acta Geol Sinica 87(2):209–219

    Google Scholar 

  • Mao JW, Li HY, Song XX (1998) Oregeology and geochemistry for Shizhuyuan W-Sn-Mo-Bi polymetallic deposit, Hunan Province. Geology Publishing House, Beijing, pp 1–215

    Google Scholar 

  • Maruyama S, Isozaki Y, Kimura G, Terabayashi M (1997) Paleogeographic maps of the Japanese Islands: plate tectonic synthesis from 750 Ma to the present. Island Arc 6:121–142

    Article  Google Scholar 

  • Meinert LD, Hedenquist JW, Satoh H, Yet Matsuhisa (2003) Formation of anhydrous and hydrous skarn in Cu–Au ore deposits by magmatic fluids. Econ Geol 98:147–156

    Article  Google Scholar 

  • Meinert LD, Dipple GM, Nicolescu S (2005) World skarn deposits. Econ Geol 100th Anniversary Volume 299–336

  • Meng QR (2003) What drove late Mesozoic extension of the northern China–Mongolia tract. Tectonophysics 369:155–174

    Article  Google Scholar 

  • Nakano T, Yoshino T, Shimazaki H (1994) Pyroxene composition as an indicator in the classification of skarn. Econ Geol 89(7):1567–1580

    Article  Google Scholar 

  • Natalin BA (1993) History and modes of Mesozoic accretion in Southeastern Russia. Island Arc 2:15–34

    Article  Google Scholar 

  • Ren T, Zhong H, Chen JF, Zhu WG, Zhang XC (2011) Geochemical characteristics of the Langdu high intermediate-acid intrusive rocks in the Zhongdian area, northwest Yunnan Province, P. R. China. Acta Mineral Sin 31(1):46

    Google Scholar 

  • Sagong H, Kwon ST, Ree JH (2005) Mesozoic episodic magmatism in south Korea and its tectonic implication. Tectonics 10:1029–2004

    Google Scholar 

  • Smith MP, Henderson P, Jeffries TER, Long J, Williams CT (2004) The rare earth elements and uranium in garnet from the Beinn and Dubhaich aureole, Skye, Scotland, UK: constrain on processes in a dynamic hydrothermal. J Petrol 45:457–484

    Article  Google Scholar 

  • Somarin AK (2004) Carnet composition an indicator of Cu mineralization: evidence from skarn deposits of NW Iran. J Geochem Explor 81(1–3):47–57

    Article  Google Scholar 

  • Wang F, Zhou XH, Zhang LC, Ying JF, Zhang YT, Wu FY, Zhu RX (2006) Large-scale Early Cretaceous volcanic events in the northern Great Xing’ an Range, Northeastern China. Earth Planet Sci Lett 251:175–198

    Google Scholar 

  • Wu FY, Yang JH, Chinghua Lo, Wilde SA, Sun DY, Jahn BM (2007) The Jiamusi Massif: a Jurassic accretionary terrane along the Western Pacific margin of NE China. Island Arc 16:156–172

    Article  Google Scholar 

  • Wu FY, Sun DY, Ge WC, Zhang YB, Grant ML, Wilde SA, Jahn BM (2011) Geochronology of Phanerozoic granitoids in notheastern China. J Asian Earth Sci 41(1):1–30

    Article  Google Scholar 

  • Xiao WJ, Windley BF, Hao J (2003) Accretion leading to collision and the Permian Solonker suture, Inner Mongolia, China: termination of the central Asian orogenic belt. Tectonic 22:1484–1505

    Article  Google Scholar 

  • Xu G, Lin X (2000) Geology and geochemistry of the Changlongshan skarn iron deposit, Anhui Province China. Ore Geol Rev 16:91–106

    Article  Google Scholar 

  • Yongfu A, Lingnian J (1981) The study of the relationship between the mineralization and the garnet in the skarn ore deposits. Acta Scicentiarum Naturalum Universitis Pekinesis 1:83–90

    Google Scholar 

  • Yuan Q, Cao XF, Lu XB, Wang XD, Yang EL, Yg Liu (2014) LA-ICP-MS U-Pb zircon geochronology and Hf isotope, geochemistry and kinetics of the Daxigou anorthosite from Kuruqtagh block, NW China. Chin J Geochem 33:214

    Google Scholar 

  • Zhai DG, Liu JJ, Zhang HY (2013) Origin of oscillatory zoned garnets from the Xieertala Fe-Zn skarn deposits, northern China: in situ LA-ICP-MS evidence. Lithos 191:279–291

    Google Scholar 

  • Zhang JH, Ge WC, Wu FY (2008) Late Mesozoic volcanism in the Great Xing’ an Range (NE China): timing and implications for the dynamic setting of NE Asia. Lithos 102:138–157

    Article  Google Scholar 

  • Zhang JH, Gao S, Ge WC, Wu FY, Yang JH, Wilde SA, Li M (2010a) Geochronolgy of the Mesozoic volcanic rocks in the great Xing’an range, northeastern China: implications for subduction induced delamination. Chem Geol 276:144–165

    Article  Google Scholar 

  • Zhang ZY, Du YS, Zhang J (2010b) Alteration and mineralization zoning in Tongshan skarn-type copper depositin in Guichi, Anhui Province. Miner Depos 6(29):999–1016

    Google Scholar 

  • Zhang JW, Huang ZL, Luo TY, Qian ZK, Zhang Y (2013) Geochemistry and Petrogenesis of Late ladinian OIB-like basalts from Tabai, Yunnan Province, China. Chin J Geochem 32:341

    Google Scholar 

  • Zhao B (1989) China skarn and skarn deposit. Science Press, Beijing, pp 1–268

    Google Scholar 

  • Zhao YM, Zhang DQ (1997) Metallogenic regularity and evaluation of the vista of mineralization of the copper polymetallic deposit, Daxinganling and adjacent region. Seismological Press, Beijing, pp 10–318

    Google Scholar 

  • Zhao B, Li TJ, Li ZP (1983) Experimental study of physico-chemical conditions of the formation of skarns. Geochimica 3:256–267

    Google Scholar 

  • Zhao GL, Yang GL, Wang Z, Fu JF, Yang YZ (1989) Mesozoic volcanic rocks in south central Daxinganling. Science and Technology Literature Publishing House, Beijing

    Google Scholar 

  • Zhao YM, Lin WW, Bi CS (1990) China skarn type deposit. Geology Publishing House, Beijing, pp 1–347

    Google Scholar 

  • Zhu J, Lu XB, Cao XF, Mo YL, Chen C (2012) U-Pb zircon geochronology, geochemistry and kinetics of the Huaniushan A-type granite in Northwest China. Chin J Geochem 31:85–94

    Article  Google Scholar 

Download references

Acknowledgments

This study was supported by the Natural Science Foundation of China (No. 41203039). Great thanks to Daxinganling Yunye Mining Development Limited Liability Company for assistance in the field. Finally, we wish to thank our reviewers very much for their constructive comments and suggestions on our manuscript.

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Correspondence to Tao Ren.

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Li, C., Ren, T., Huang, JG. et al. Skarn mineralogy and its geological significance for the Tayuan (Cu–Mo)–Pb–Zn deposit, northern Daxinganling metallogenic belt. Acta Geochim 36, 89–101 (2017). https://doi.org/10.1007/s11631-016-0128-0

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  • DOI: https://doi.org/10.1007/s11631-016-0128-0

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