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Facile and green fabrication of silver nanoparticles on a polyoxometalate for Li-ion battery

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Abstract

In the present study, we report the green and one-pot synthesis of silver nanoparticles (AgNPs) on as-prepared novel polyoxometalate {[Ni2,5(Hpen)4(PW9O34)] · 5H2O} (POM) without any reducing agent and its application as improved anode material for lithium-ion batteries (LIBs). The structure of the AgNPs involved POM (AgNPs/POM) nanocomposite was characterized by transmission electron microscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy. The synthesized POM was also characterized by elemental analysis and thermal analysis. The electrochemical performances of the POM, AgNPs, and AgNPs/POM composites were measured for charge/discharge specific capacities at different current rates in CR2032 coin-type cells. The prepared AgNPs/POM composite showed a high specific gravimetric capacity of about 1760 mAh g−1 and long-term cycle stability.

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Acknowledgments

The authors would like to thank Pamukkale University, Sinop University, Dumlupinar University, and Graduate University of Advanced Technology for supports.

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Authors and Affiliations

  1. Department of Chemical Engineering, Pamukkale University, Denizli, Turkey

    Tanju Eren & Necip Atar

  2. Department of Metallurgical and Materials Engineering, Sinop University, Sinop, Turkey

    Mehmet Lütfi Yola

  3. Department of Chemistry, Graduate University of Advanced Technology, Kerman, Iran

    Hassan Karimi-Maleh

  4. Department of Chemistry, Dumlupinar University, Kutahya, Turkey

    Alper Tolga Çolak & Asim Olgun

Authors
  1. Tanju Eren
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  2. Necip Atar
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  3. Mehmet Lütfi Yola
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  4. Hassan Karimi-Maleh
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  5. Alper Tolga Çolak
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Correspondence to Necip Atar or Hassan Karimi-Maleh.

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Eren, T., Atar, N., Yola, M.L. et al. Facile and green fabrication of silver nanoparticles on a polyoxometalate for Li-ion battery. Ionics 21, 2193–2199 (2015). https://doi.org/10.1007/s11581-015-1409-z

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  • DOI: https://doi.org/10.1007/s11581-015-1409-z

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