Abstract
Poly(3-hexylthiophene) (P3HT) is one of the most used semiconducting polymers for organic photovoltaics because it has potential for commercialization due to its easy synthesis and stability. Although the rapid development of the small molecular non-fullerene acceptors (NFAs) have largely improved the power conversion efficiency (PCE) of organic solar cells (OSCs) based on other complicated p-type polymers, the PCE of P3HT-based OSCs is still low. In addition, the design principle and structure-properties correlation for the NFAs matching well with P3HT are still unclear and need to be investigated in depth. Here we designed a series of NFAs comprised of acceptor (A) and donor (D) units with an A2-A1-D-A1-A2 configuration. These NFAs are abbreviated as Qx3, Qx3b and Qx3c, where indaceno[1,2-b:5,6-b′]dithiophene (IDT), quinoxaline (Qx) and 2-(1,1-dicyanomethylene)rhodanine serve as the middle D, bridged A1 and the end group A2, respectively. By subtracting the phenyl side groups appended on both IDT and Qx skeletons, the absorption spectra, energy levels and crystallinity could be regularly modulated. When paired with P3HT, three NFAs show totally different photovoltaic performance with PCEs of 3.37% (Qx3), 6.37% (Qx3b) and 0.03% (Qx3c), respectively. From Qx3 to Qx3b, the removing of phenyl side chain in the middle IDT unit results in the increase of crystallinity and electron mobility. However, after subtracting all the grafted phenyl side groups on both IDT and Qx units, the final molecule Qx3c exhibits the lowest PCE of only 0.03%, which is mainly attributed to the serious phase-separation of the blend film. These results demonstrate that optimizing the substituted position of phenyl side groups for A2-A1-D-A1-A2 type NFAs is vital to regulate the optoelectronic property of molecule and morphological property of active layer for high performance P3HT-based OSCs.
Similar content being viewed by others
References
Yu G Gao J Hummelen JC Wudl F Heeger AJ. Science, 1995, 270: 1789–1791
Yan C Barlow S Wang Z Yan H Jen AKY Marder SR Zhan X. Nat Rev Mater, 2018, 3: 18003
Tang A Zhan C Yao J Zhou E. Adv Mater, 2017, 29: 1600013
Geng Y Tang A Tajima K Zeng Q Zhou E. J Mater Chem A, 2019, 7: 64–96
Yang J Xiao B Tang A Li J Wang X Zhou E. Adv Mater, 2018, 4: 1804699
Li G Shrotriya V Huang J Yao Y Moriarty T Emery K Yang Y. Nat Mater, 2005, 4: 864–868
Fan B Zhang D Li M Zhong W Zeng Z Ying L Huang F Cao Y. Sci China Chem, 2019, 62: 746–752
Hildner R Köhler A Müller-Buschbaum P Panzer F Thelakkat M. Adv Energy Mater, 2017, 7: 1700314
Po R Bernardi A Calabrese A Carbonera C Corso G Pellegrino A. Energy Environ Sci, 2014, 7: 925–943
Liu Y Summers MA Edder C Fréchet JMJ McGehee MD. Adv Mater, 2005, 17: 2960–2964
Guo X Cui C Zhang M Huo L Huang Y Hou J Li Y. Energy Environ Sci, 2012, 5: 7943
Zhai W Tang A Xiao B Wang X Chen F Zhou E. Sci Bull, 2018, 63: 845–852
Mahmood A Yang J Hu J Wang X Tang A Geng Y Zeng Q Zhou E. J Phys Chem C, 2018, 122: 29122–29128
Yang L Gu W Lv L Chen Y Yang Y Ye P Wu J Hong L Peng A Huang H. Angew Chem Int Ed, 2018, 57: 1096–1102
Yuan J Zhang Y Zhou L Zhang G Yip HL Lau TK Lu X Zhu C Peng H Johnson PA Leclerc M Cao Y Ulanski J Li Y Zou Y. Joule, 2019, 3: 1140–1151
Yang J Cong P Chen L Wang X Li J Tang A Zhang B Geng Y Zhou E. ACS Macro Lett, 2019, 8: 743–748
Chen Y Geng Y Tang A Wang X Sun Y Zhou E. Chem Commun, 2019, 55: 6708–6710
Winzenberg KN Kemppinen P Scholes FH Collis GE Shu Y Birendra Singh T Bilic A Forsyth CM Watkins SE. Chem Commun, 2013, 49: 6307–6309
Holliday S Ashraf RS Nielsen CB Kirkus M Röhr JA Tan CH Collado-Fregoso E Knall AC Durrant JR Nelson J McCulloch I. J Am Chem Soc, 2015, 137: 898–904
Kim Y Song CE Moon SJ Lim E. Chem Commun, 2014, 50: 8235–8238
Lin Y Li Y Zhan X. Adv Energy Mater, 2013, 3: 724–728
Gupta A Rananaware A Srinivasa Rao P Duc La D Bilic A Xiang W Li J Evans RA Bhosale SV Bhosale SV. Mater Chem Front, 2017, 1: 1600–1606
Yan Q Zhou Y Zheng YQ Pei J Zhao D. Chem Sci, 2013, 4: 4389–4394
Liu F Zhou Z Zhang C Vergote T Fan H Liu F Zhu X. J Am Chem Soc, 2016, 138: 15523–15526
Qiu N Yang X Zhang H Wan X Li C Liu F Zhang H Russell TP Chen Y. Chem Mater, 2016, 28: 6770–6778
Baran D Ashraf RS Hanifi DA Abdelsamie M Gasparini N Röhr JA Holliday S Wadsworth A Lockett S Neophytou M Emmott CJM Nelson J Brabec CJ Amassian A Salleo A Kirchartz T Durrant JR McCulloch I. Nat Mater, 2017, 16: 363–369
Wu Y Bai H Wang Z Cheng P Zhu S Wang Y Ma W Zhan X. Energy Environ Sci, 2015, 8: 3215–3221
Holliday S Ashraf RS Wadsworth A Baran D Yousaf SA Nielsen CB Tan CH Dimitrov SD Shang Z Gasparini N Alamoudi M Laquai F Brabec CJ Salleo A Durrant JR McCulloch I. Nat Commun, 2016, 7: 11585
Xiao B Tang A Zhang J Mahmood A Wei Z Zhou E. Adv Energy Mater, 2017, 7: 1602269
Xiao B Tang A Yang J Wei Z Zhou E. ACS Macro Lett, 2017, 6: 410–414
Tang A Xiao B Wang Y Gao F Tajima K Bin H Zhang ZG Li Y Wei Z Zhou E. Adv Funct Mater, 2018, 28: 1704507
Tang A Xiao B Chen F Zhang J Wei Z Zhou E. Adv Energy Mater, 2018, 8: 1801582
Xiao B Tang A Cheng L Zhang J Wei Z Zeng Q Zhou E. Sol RRL, 2017, 1: 1700166
Xiao B Tang A Zhang Q Li G Wang X Zhou E. ACS Appl Mater Interfaces, 2018, 10: 34427–34434
Yuan J Ouyang J Cimrová V Leclerc M Najari A Zou Y. J Mater Chem C, 2017, 5: 1858–1879
Gedefaw D Prosa M Bolognesi M Seri M Andersson MR. Adv Energy Mater, 2017, 7: 1700575
Liu M Gao Y Zhang Y Liu Z Zhao L. Polym Chem, 2017, 8: 4613–4636
Xiao B Tang A Yang J Mahmood A Sun X Zhou E. ACS Appl Mater Interfaces, 2018, 10: 10254–10261
Wang T Lau TK Lu X Yuan J Feng L Jiang L Deng W Peng H Li Y Zou Y. Macromolecules, 2018, 51: 2838–2846
Zheng Z Awartani OM Gautam B Liu D Qin Y Li W Bataller A Gundogdu K Ade H Hou J. Adv Mater, 2017, 29: 1604241
Chen W Salim T Fan H James L Lam YM Zhang Q. RSC Adv, 2014, 4: 25291–25301
Qi X Lo YC Zhao Y Xuan L Ting HC Wong KT Rahaman M Chen Z Xiao L Qu B. Front Chem, 2018, 6: 260
Rivnay J Noriega R Kline RJ Salleo A Toney MF. Phys Rev B, 2011, 84: 045203
Zhu C Zhao Z Chen H Zheng L Li X Chen J Sun Y Liu F Guo Y Liu Y. J Am Chem Soc, 2017, 139: 17735–17738
Bi YG Feng J Ji JH Yi FS Li YF Liu YF Zhang XL Sun HB. Nanophotonics, 2017, 7: 60
Acknowledgements
This work was supported by the Key Research Program of Frontier Sciences, Chinese Academy of Sciences (QYZDB-SSW-SLH033), the National Key Research and Development Program of China (2017YFA0206600) and the National Natural Science Foundation of China (51673048, 21875052, 51773046, 21602040, 51873044).
Author information
Authors and Affiliations
Corresponding authors
Supporting Information
11426_2019_9618_MOESM1_ESM.docx
Side Chain Engineering of Quinoxaline-based Small Molecular Nonfullerene Acceptors for High-performance Poly(3-hexylthiophene)-based Organic Solar Cells
Rights and permissions
About this article
Cite this article
Xiao, B., Zhang, Q., Li, G. et al. Side chain engineering of quinoxaline-based small molecular nonfullerene acceptors for high-performance poly(3-hexylthiophene)-based organic solar cells. Sci. China Chem. 63, 254–264 (2020). https://doi.org/10.1007/s11426-019-9618-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11426-019-9618-7