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Removal Processes for Tributyltin During Municipal Wastewater Treatment

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Abstract

The fate and behaviour of tributyltin (TBT) at two wastewater treatment works was examined. Both sites had two inlet streams, and each utilised high rate biological filters (biofilters) on one the streams, before treatment of the combined flows on trickling filters, with one having additional tertiary processes, installed to remove ammonia and solids. The study was designed to determine if these processes enhanced the removal of TBT. Degradation of TBT was observed in one of the biofilters, possibly as a result of temperature and hydraulic loading. At the treatment works with tertiary processes, the mass flux showed the overall removal of TBT was 68 %, predominantly due to removal with solids in the primary settlement processes. However, overall removal of 95 % was observed in the conventional trickling filter works with 94 % of this due to biodegradation in the trickling filter. The two works both removed TBT, but at different treatment stages and by different processes. Differences in the form (solubility) of TBT in the influent may have attributed to this, although further understanding of factors controlling degradation would allow for a more complete assessment of the potential of biological processes to remove hazardous compounds from wastewaters.

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Acknowledgements

The authors are grateful to United Utilities PLC for funding the work and for the permission to publish the results.

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Authors and Affiliations

  1. Institute for the Environment, Brunel University, Middlesex, UB8 3PH, UK

    M. D. Scrimshaw, D. Hala & A. E. Okiemute

  2. Cranfield Water Science Institute, School of Applied Sciences, Cranfield University, Bedfordshire, MK43 0AL, UK

    E. Cartmell & J. N. Lester

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  1. M. D. Scrimshaw
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  2. D. Hala
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  3. A. E. Okiemute
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  4. E. Cartmell
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  5. J. N. Lester
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Correspondence to M. D. Scrimshaw.

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Scrimshaw, M.D., Hala, D., Okiemute, A.E. et al. Removal Processes for Tributyltin During Municipal Wastewater Treatment. Water Air Soil Pollut 224, 1400 (2013). https://doi.org/10.1007/s11270-012-1400-5

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  • DOI: https://doi.org/10.1007/s11270-012-1400-5

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