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Synthesis of Polystyrene Beads for Hard-Templating of Three-Dimensionally Ordered Macroporosity and Hierarchical Texture of Adsorbents and Catalysts

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Abstract

Methods of polystyrene beads producing with properties appropriate for catalyst and adsorbent synthesis have been investigated. Hierarchical silicalite-1 and Fe-silicalite-1 with zeolitic MFI structure, as well as three-dimensionally ordered titania, silica, alumina and zirconia have been prepared by hard-templating method using polystyrene beads. The materials were characterized by X-ray diffraction, scanning and transmission electron microscopies, low-temperature nitrogen adsorption technique and mercury porosimetry. Developed meso- and macroporous structure of the templated materials facilitated the supply of macromolecular reactants to the material surface and reduced the negative effect of byproduct deposition, resulting in favored advantages of the materials in a wide range of processes: hydroconversion of heavy oil, wet hydrogen peroxide oxidation of organic substrates in water, photocatalysis and gas chromatographic analysis. The obtained results of the material applications showed their potential attractiveness as catalysts and adsorbents.

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References

  1. Kresge C, Leonowicz M, Roth W, Vartuli J, Beck J (1992) Nature 359:710–712

    Article  CAS  Google Scholar 

  2. Oveisi H, Jiang X, Imura M, Nemoto Y, Sakamoto Y, Yamauchi Y (2011) Angew Chem Int Ed 50:7410–7413

    Article  CAS  Google Scholar 

  3. Yamauchi Y (2013) J Ceram Soc Jpn 121(9):831–840

    Article  CAS  Google Scholar 

  4. Wu Q, Zhang F, Yang J, Li Q, Tu B, Zhao D (2011) Microporous Mesoporous Mater 143:406–412

    Article  CAS  Google Scholar 

  5. Blin J, Leonard A, Yuan Z, Gigot L, Vantomme A, Cheetham A, Su B (2003) Angew Chem Int Ed 42:2872–2875

    Article  CAS  Google Scholar 

  6. Imhof A, Pine D (1997) Nature 389:948–951

    Article  CAS  Google Scholar 

  7. Davis S, Burkett S, Mendelson N, Mann S (1997) Nature 385:420–423

    Article  CAS  Google Scholar 

  8. Holland B, Blanford C, Stein A (1998) Science 281:538–540

    Article  CAS  Google Scholar 

  9. Yang P, Deng T, Zhao D, Feng P, Pine D, Chmelka B, Whitesides G, Stucky G (1998) Science 282:2244–2246

    Article  CAS  Google Scholar 

  10. Holland B, Abrams L, Stein A (1999) J Am Chem Soc 121:4308–4309

    Article  CAS  Google Scholar 

  11. Li S, Zheng J, Yang W, Zhao Y (2007) Mater Lett 61:4784–4786

    Article  CAS  Google Scholar 

  12. Sen T, Tiddy G, Casci J, Anderson M (2003) Angew Chem Int Ed 42:4649–4653

    Article  CAS  Google Scholar 

  13. Xia Y, Gates B, Yin Y, Lu Y (2000) Adv Mater 12(10):693–713

    Article  CAS  Google Scholar 

  14. Suzuki N, Yamauchi YJ (2010) Sol Gel Sci Technol 53:428–433

    Article  CAS  Google Scholar 

  15. Stevens S, Loiola A, Cubillas B, Silva L, Terasaki O, Anderson M (2011) Solid State Sci 13:745–749

    Article  CAS  Google Scholar 

  16. Tokudome Y, Fujita K, Nakanishi K, Miura K, Hirao K (2007) Chem Mater 19:3393–3398

    Article  CAS  Google Scholar 

  17. Han D, Li X, Zhang L, Wang Y, Yan Z, Liu Sh (2012) Microporous Mesoporous Mater 158:1–6

    Article  CAS  Google Scholar 

  18. Tang F, Fudouzi H, Sakka Y (2003) J Am Chem Soc 86(12):2050–2054

    CAS  Google Scholar 

  19. Sadakane M, Horiuchi T, Kato N, Takahashi Ch, Ueda W (2007) Chem Mater 19:5779–5785

    Article  CAS  Google Scholar 

  20. Li H, Zhang L, Dai H, He H (2009) Inorg Chem 48(10):4421–4434

    Article  CAS  Google Scholar 

  21. Sokolov S, Bell D, Stein A (2003) J Am Ceram Soc 86(9):1481–1486

    Article  CAS  Google Scholar 

  22. Yuan Z, Su B (2006) J Mater Chem 16:663–677

    Article  CAS  Google Scholar 

  23. Srinivasan M, White T (2007) Environ Sci Technol 41:4405–4409

    Article  CAS  Google Scholar 

  24. Zou D, Sun L, Aklonis J, Solovey R (1992) J Polym Sci A 30:1463–1475

    Article  CAS  Google Scholar 

  25. Parkhomchuk E, Lysikov A, Okunev A, Parunin P, Semeikina V, Ayupov A, Trunova V, Parmon V (2013) Ind Eng Chem Res 52:17117–17125

    Article  CAS  Google Scholar 

  26. Sashkina K, Labko V, Rudina N, Parmon V, Parkhomchuk E (2013) J Catal 299:44–52

    Article  CAS  Google Scholar 

  27. Song Z, Poehlein G (1989) J Colloid Interface Sci 128(2):486–500

    Article  CAS  Google Scholar 

  28. Song Z, Poehlein G (1989) J Colloid Interface Sci 128(2):501–510

    Article  CAS  Google Scholar 

  29. Capek I (2002) Adv Colloid Interface Sci 99:77–162

    Article  CAS  Google Scholar 

  30. Kozlova E, Kurenkova A, Semeykina V, Parkhomchuk E, Cherepanova S, Gerasimov E, Parmon V (2015) ChemCatChem 7(24):4108–4117

    Article  CAS  Google Scholar 

  31. Semeykina V, Parkhomchuk E, Polukhin A, Parunin P, Lysikov A, Ayupov A, Cherepanova S, Kanazhevskii V, Kaichev V, Glazneva T, Zvereva V (2016) Ind Eng Chem Res 55:3535–3545

    Article  CAS  Google Scholar 

  32. Okunev A, Parkhomchuk E, Lysikov A, Parunin P, Semeykina V, Parmon V (2015) Russ Chem Rev 84(9):981–999

    Article  CAS  Google Scholar 

  33. Zheivot V, Parkhomchuk E, Sashkina K, Melgunova E, Zaikovskii V, Moroz E (2015) Microporous Mesoporous Mater 202:57–67

    Article  CAS  Google Scholar 

  34. Sashkina K, Rudina N, Lysikov A, Ayupov A, Parkhomchuk E (2014) J Mater Chem A 2:16061–16070

    Article  CAS  Google Scholar 

  35. Sashkina K, Polukhin A, Labko V, Ayupov A, Lysikov A, Parkhomchuk E (2016) Appl Catal B 185:353–361

    Article  CAS  Google Scholar 

  36. Parkhomchuk E, Sashkina K, Semeykina V RU patent 2570510, priority 30.04.2014

  37. Parkhomchuk E, Okunev A, Sashkina K RU patent 2560066, priority 29.05.2014

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Acknowledgments

The authors thank N.A. Rudina, S.V. Bogdanov, E.Yu. Gerasimov, A.B. Aupov, O.A. Bulavchenko for their help in catalyst characterization. The works of zeolite synthesis and macroporous oxides were financed by RSFC Grant 14-13-01155.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis SB RAS, Lavrentieva ave. 5, Novosibirsk, Russia, 630090

    Ekaterina V. Parkhomchuk, Ksenia A. Sashkina, Alexey G. Okunev, Anton I. Lysikov & Valentin N. Parmon

  2. Novosibirsk State University, Pirogova st. 2, Novosibirsk, Russia, 630090

    Ekaterina V. Parkhomchuk, Victoria S. Semeykina, Alexey G. Okunev, Anton I. Lysikov & Valentin N. Parmon

Authors
  1. Ekaterina V. Parkhomchuk
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  2. Victoria S. Semeykina
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  3. Ksenia A. Sashkina
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  4. Alexey G. Okunev
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  5. Anton I. Lysikov
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  6. Valentin N. Parmon
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Correspondence to Ekaterina V. Parkhomchuk.

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Parkhomchuk, E.V., Semeykina, V.S., Sashkina, K.A. et al. Synthesis of Polystyrene Beads for Hard-Templating of Three-Dimensionally Ordered Macroporosity and Hierarchical Texture of Adsorbents and Catalysts. Top Catal 60, 178–189 (2017). https://doi.org/10.1007/s11244-016-0719-3

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  • DOI: https://doi.org/10.1007/s11244-016-0719-3

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