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Selective catalytic oxidation of benzyl alcohol to benzaldehyde by a mononuclear oxovanadium(V) complex of a bis(phenolate) ligand containing bulky tert-butyl substituents

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Abstract

A new mononuclear complex of vanadium(V), [V(O)(bp)(OCH3)] (1) has been synthesized, where H2bp is N,N′-bis(2-hydroxy-3,5-di-tert-butylbenzyl)-N′,N′-dimethylethylene-1,2-diamine. The complex was characterized by elemental analyses, spectroscopic methods and X-ray diffraction measurement. Single-crystal X-ray diffraction structure analysis of the complex revealed that the vanadium atom is octahedrally coordinated and that the bis(phenolate) ligand (bp2−) is N2O2-bonded to the vanadium(V) center in a tetradentate dinegative fashion.

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Acknowledgments

We acknowledge the University of Zanjan for funding this research work. R. Bikas thanks to the Ministry of Science, Research and Technology of the I.R. Iran for scholarship No. 213631.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Zanjan, 45195-313, Zanjan, Iran

    Nader Noshiranzadeh, Mina Mayeli & Rahman Bikas

  2. Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, 50-383, Wroclaw, Poland

    Rahman Bikas, Katarzyna Ślepokura & Tadeusz Lis

Authors
  1. Nader Noshiranzadeh
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  2. Mina Mayeli
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  3. Rahman Bikas
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  4. Katarzyna Ślepokura
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  5. Tadeusz Lis
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Correspondence to Nader Noshiranzadeh.

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Noshiranzadeh, N., Mayeli, M., Bikas, R. et al. Selective catalytic oxidation of benzyl alcohol to benzaldehyde by a mononuclear oxovanadium(V) complex of a bis(phenolate) ligand containing bulky tert-butyl substituents. Transition Met Chem 39, 33–39 (2014). https://doi.org/10.1007/s11243-013-9769-6

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  • DOI: https://doi.org/10.1007/s11243-013-9769-6

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