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Influence of H2O and SO2 on the activity of deposited cobalt oxide catalysts in the processes of reduction of nitrogen(I), (II) oxides with carbon monoxide and C3-C4 alkanes

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Theoretical and Experimental Chemistry Aims and scope

It is shown that palladium–cobalt oxide–cerium catalyst deposited on cordierite catalyzes the reduction of nitrogen(II) oxide with carbon monoxide, and cobalt–iron catalysts in simultaneous reduction of NO + N2O with C3-C4 alkanes retained high activity in the presence of water vapor and sulfur dioxide. The Pd-Co3O4/cordierite catalyst exceeds the Pt-Co3O4/codierite catalyst in the conversion of NO and CO in the reaction mixture CO + NO + O2 + H2O + SO2. Modification of the Pd-Co3O4/cordierite with cerium oxide considerably increases its sulfur resistance.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    P. I. Kirienko, T. M. Boichuk, S. N. Orlik & S. A. Solov’ev

Authors
  1. P. I. Kirienko
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  2. T. M. Boichuk
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  3. S. N. Orlik
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  4. S. A. Solov’ev
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Correspondence to S. N. Orlik.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 47, No. 6, pp. 370-375, November-December, 2011.

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Kirienko, P.I., Boichuk, T.M., Orlik, S.N. et al. Influence of H2O and SO2 on the activity of deposited cobalt oxide catalysts in the processes of reduction of nitrogen(I), (II) oxides with carbon monoxide and C3-C4 alkanes. Theor Exp Chem 47, 384–389 (2012). https://doi.org/10.1007/s11237-012-9231-4

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  • DOI: https://doi.org/10.1007/s11237-012-9231-4

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