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An efficient, one-pot synthesis of 2-amino-4H-chromenes catalyzed by (α-Fe2O3)-MCM-41-supported dual acidic ionic liquid as a novel and recyclable magnetic nanocatalyst

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Abstract

A novel (α-Fe2O3)-MCM-41-supported dual acidic ionic liquid (DAIL) catalytic system was prepared. This catalyst was characterized by XRD, TEM, SEM, IR spectra and N2 adsorption–desorption measurements, TGA and acid–base titration. 1-Methyl-3-(4-sulfobutyl) imidazolium hydrogen sulfate as the DAIL inside the mesochannels of α-Fe2O3-MCM-41 led to preparation of a new material which was an efficient magnetic heterogeneous nanocatalyst for one-pot three-component synthesis of some new and known 2-amino-4H-chromenes in water medium conditions. This catalyst was more efficient than other reported catalysts for the synthesis of 2-amino-3-cyano-7-hydroxy-4H-chromenes. High product yields, short reaction times, use of non-corrosives, a robust and reusable magnetic nanocatalyst and water as a green solvent are the most important features of the present work.

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Acknowledgments

We gratefully acknowledge the K. N. Toosi University Research Council for partial financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, K. N. Toosi University of Technology, P. O. Box 15875 -4416, Tehran, Iran

    Shahnaz Rostamizadeh & Negar Zekri

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  1. Shahnaz Rostamizadeh
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  2. Negar Zekri
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Correspondence to Shahnaz Rostamizadeh.

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Rostamizadeh, S., Zekri, N. An efficient, one-pot synthesis of 2-amino-4H-chromenes catalyzed by (α-Fe2O3)-MCM-41-supported dual acidic ionic liquid as a novel and recyclable magnetic nanocatalyst. Res Chem Intermed 42, 2329–2341 (2016). https://doi.org/10.1007/s11164-015-2152-9

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  • DOI: https://doi.org/10.1007/s11164-015-2152-9

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