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Immobilized Cu(II)–Schiff base complex on modified Fe3O4 nanoparticles as catalysts in the oxidation of o-phenylenediamine to 2,3-diaminophenazine

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Abstract

A heterogeneous and magnetically recoverable nanocatalyst was conveniently synthesized via covalent anchoring of Cu(II)–Schiff base complex on modified Fe3O4@SiO2 nanoparticles yielding Fe3O4@SiO2–Cu(II). The resulting material was characterized by scanning electron microscopy, energy dispersive X-ray, X-ray diffraction, Fourier transform infrared spectroscopy and elemental analysis. The resulting nanocomposites were utilized as a catalyst for oxidation of o-phenylenediamine to 2,3-diaminophenazine in the presence H2O2 in aqueous solution. The data were fitted to the Michaelis–Menten model and the parameters K m and V max were obtained.

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References

  1. Kuah E, Toh S, Yee J, Ma Q, Gao Z (2016) Chem Eur J 22:8404–8430

    Article  CAS  Google Scholar 

  2. Ragg R, Tahir MN, Tremel W (2015) Eur J Inorg Chem 1906–1915

  3. Gao L, Zhuang J, Nie L, Zhang J, Gu N, Wang T, Feng J, Yang D, Oerrett S, Yan X (2007) Nat Nanotechnol 2:577–583

    Article  CAS  Google Scholar 

  4. Yu Z, Park Y, Chen L, Zhao B, Jung YM, Cong Q (2015) ACS Appl Mater Interfaces 42:23472–23480

    Article  Google Scholar 

  5. Yuan H, Cai R, Pan Z (2003) Anal Lett 36:277–286

    Article  CAS  Google Scholar 

  6. Mu J, He Y, Wang Y (2016) Talanta 148:22–28

    Article  CAS  Google Scholar 

  7. Thawari AG, Rao CP (2016) ACS Appl Mater Interfaces 8:10392–10402

    Article  CAS  Google Scholar 

  8. Mirica LM, Ottenwaelder X, Stack TDP (2004) Chem Rev 104:1013–1046

    Article  CAS  Google Scholar 

  9. Lewis EA, Tolman WB (2004) Chem Rev 104:1047–1076

    Article  CAS  Google Scholar 

  10. Tolman WB (1997) Acc Chem Res 30:227–237

    Article  CAS  Google Scholar 

  11. Serrano-Plana J, Garcia-Bosch I, Company A, Costas M (2015) Acc Chem Res 48:2397–2406

    Article  CAS  Google Scholar 

  12. Itoh S (2015) Acc Chem Res 48:2066–2074

    Article  CAS  Google Scholar 

  13. Kakuda S, Peterson RL, Ohkubo K, Karlin KD, Fukuzumi S (2013) J Am Chem Soc 135:6513–6522

    Article  CAS  Google Scholar 

  14. Leutbecher H, Constantin M-A, Mika S, Conrad J, Beifuss U (2011) Tetrahedron Lett 52:605–608

    Article  CAS  Google Scholar 

  15. Tarcha PJ, Chu VP, Whittern D (1987) Anal Biochem 165:230–233

    Article  CAS  Google Scholar 

  16. Griess P (1871) J Prakt Chem 3:143–144

    Article  Google Scholar 

  17. Németh S, Simándi L (1982) J Mol Catal 14:87–93

    Article  Google Scholar 

  18. Németh S, Simandi LI (1983) Inorg Chem 22:3151–3155

    Article  Google Scholar 

  19. Khattar R, Yadav A, Mathur P (2015) Spectrochim Acta Mol Biomol Spectrosc 142:375–381

    Article  CAS  Google Scholar 

  20. Tyagi N, Mathur P (2012) Spectrochim Acta Mol Biomol Spectrosc 96:759–767

    Article  CAS  Google Scholar 

  21. Maynard BA, Tutson CD, Lynn KS, Pugh CW, Gorden AEV (2016) Tetrahedron Lett 57:472–475

    Article  CAS  Google Scholar 

  22. Dalui A, Pradhan B, Thupakula U, Khan AH, Kumar GS, Ghosh T, Satpatib B, Acharya S (2015) Nanoscale 7:9062–9074

    Article  CAS  Google Scholar 

  23. Kima M-C, Lee S-Y (2015) Nanoscale 7:17063–17070

    Article  Google Scholar 

  24. Bhat PB, Bhat BR (2015) New J Chem 39:4933–4938

    Article  CAS  Google Scholar 

  25. He D, Wu Y, Xu B-Q (2007) Eur Polym J 43:3703–3709

    Article  CAS  Google Scholar 

  26. Buzoglu L, Maltas E, Ozmen M, Yildiz S (2014) Colloids Surf A Physicochem Eng Aspects 442:139–145

    Article  CAS  Google Scholar 

  27. Li W, Deng Y, Wu Z, Qian X, Yang J, Wang Y, Gu D, Zhang F, Tu B, Zhao D (2011) J Am Chem Soc 133:15830–15833

    Article  CAS  Google Scholar 

  28. Moradi-Shoeili Z, Zare M, Bagherzadeh M, Özkar S, Akbayrak S (2016) J Coord Chem 69:668–677

    Article  CAS  Google Scholar 

  29. Le X, Dong Z, Jin Z, Wang Q, Ma J (2014) Catal Commun 53:47–52

    Article  CAS  Google Scholar 

  30. Moradi-Shoeili Z, Amini Z, Boghaei DM, Notash B (2013) Polyhedron 53:76–82

    Article  CAS  Google Scholar 

  31. Sun J, Yu G, Liu L, Li Z, Kan Q, Huob Q, Guan J (2014) Catal Sci Technol 4:1246–1252

    Article  CAS  Google Scholar 

  32. Lente G (2015) Deterministic kinetics in chemistry and systems biology: the dynamics of complex reaction networks. Springer, London

    Book  Google Scholar 

  33. Kemmer G, Keller S (2010) Nat Protoc 5:267–281

    Article  CAS  Google Scholar 

  34. Mu J, Wang Y, Zhao M, Zhang L (2012) Chem Commun 48:2540–2542

    Article  CAS  Google Scholar 

  35. Jia H, Yang D, Han X, Cai J, Liu H, He W (2016) Nanoscale 8:5938–5945

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are grateful to the University of Guilan for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, University of Guilan, P.O. Box 41335-1914, Rasht, Iran

    Zeinab Moradi-Shoeili

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  1. Zeinab Moradi-Shoeili
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Correspondence to Zeinab Moradi-Shoeili.

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Moradi-Shoeili, Z. Immobilized Cu(II)–Schiff base complex on modified Fe3O4 nanoparticles as catalysts in the oxidation of o-phenylenediamine to 2,3-diaminophenazine. Reac Kinet Mech Cat 120, 323–332 (2017). https://doi.org/10.1007/s11144-016-1085-7

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  • DOI: https://doi.org/10.1007/s11144-016-1085-7

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