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Co(II)-exchanged montmorillonite with ethylenediamine, trimethyl- and tetramethyl-ethylenediamine and their thermal decomposition

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Abstract

The influence of different steric properties of ethylenediamine (EDA), trimethylenediamine (TrMeEDA) and tetraethylenediamine (TeMeEDA) on the type of interactions with Co(II)-exchanged montmorillonite and thermal decomposition of these materials were studied. The results of X-ray diffraction (XRD), thermogravimetry (TG), derivative thermogravimetry (DTG) and spectral analysis shows that the studied ethylenediamines are intercalated into the interlayer space of montmorillonite. Thermal decomposition at 20–500 °C of studied samples with EDA proceeds in three steps (the release of chemosorbed amines, coordinated EDA and dehydroxylation) while the sample with TrMeEDA and TeMeEDA in five steps (also release the protonated forms). The effect of different steric properties of individual diamines is evident.

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Acknowledgements

We wish to thank the Slovak Grant Agency (AV 4/2014/08) for the financial support.

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Authors and Affiliations

  1. Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, SK-02032, Púchov, Slovakia

    S. Šnircová, E. Jóna, R. Janík, Ľ. Lajdová, S. Lendvayová, M. Loduhová, V. Šutinská & S. C. Mojumdar

  2. Slovak Institute of Metrology, Karloveská 63, Bratislava, Slovakia

    R. Durný

  3. Department of Industrial Design, Faculty of Industrial Technologies, Trencin University of A. Dubcek, Trencin, Slovakia

    P. Lizák

  4. University of New Brunswick, Fredericton, NB, E3B 5A3, Canada

    S. C. Mojumdar

  5. Department of Chemical and Biochemical Engineering, The University of Western Ontario, London, ON, N6A 5B9, Canada

    S. C. Mojumdar

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  1. S. Šnircová
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  2. E. Jóna
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Correspondence to S. C. Mojumdar.

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Šnircová, S., Jóna, E., Janík, R. et al. Co(II)-exchanged montmorillonite with ethylenediamine, trimethyl- and tetramethyl-ethylenediamine and their thermal decomposition. J Therm Anal Calorim 104, 937–941 (2011). https://doi.org/10.1007/s10973-011-1318-y

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